This paper reports the first attempt at the synthesis of single phosphors of europium (Eu3+) and dysprosium (Dy3+) co-doped hydroxyapatite (HA)/β-tricalcium phosphate (TCP) nanostructures providing strong red and yellow luminescence depending on annealing temperature and holding time. The morphology of the phosphors was observed to have a nanowire structure. The photoluminescence (PL) intensity of the phosphors increases with annealing temperature and time. The luminescent phosphors also showed the typical luminescence of Eu3+ centered at 610 nm and Dy3+ centered at 572 nm, which was more efficient for the annealed Eu3+/Dy3+ co-doped HA/TCP phosphors than for as-synthesized ones. These results suggest that the Eu3+ and Dy3+ co-doped HA/TCP nanostructures can find potential application in plant cultivation as environment friendly phosphors.
Similar content being viewed by others
References
Y. J. Zhang, Z. Y. Mao, D. J. Wang, and J. Zhao, Mater. Res. Bull., 67, 1–4 (2015).
L. Ma, D. J. Wang, Z. Y. Mao, Q. F. Lu, and Z. H. Yuan, Appl. Phys. Lett., 93, 144101–144101-3 (2008).
J. Chen, C. Guo, Z. Yang, T. Li, and J. Zhao, J. Am. Ceram. Soc., 99, 218–225 (2016)
A. Shimada and Y. Taniguchi, J. Photochem. Photobiol. B: Biol., 104, 399–404 (2011).
I. Vänninen, D. M. Pinto, A. I. Nissinen, N. S. Johansen, and L. Shipp, Annu. Appl. Biol., 157, 393–414 (2010).
Y. Wang and K. M. Folta, Am. J. Bot., 100, 70–78 (2013).
R. M. Klein and P. C. Edsall, Photochem. Photobiol., 6, 841–850 (1967).
U. V. Pedmale, S. C. Huang, M. Zander, B. J. Cole, J. Hetzel, K. Ljung, P. A. B. Reis, P. Sridevi, K. Nito, J. R. Nery, J. R. Ecker, and J. Chory, Cell, 164, 1–13 (2016).
A. Takemiya, S. I. Inoue, M. Doi, T. Kinoshita, and K. I. Shimazaki, The Plant Cell, 17, 1120–1127 (2005).
H. A. H. Graham and D. R. Decoteau, Sci. Horticulturae, 69, 41–49 (1997).
K. E. Gerhardt, M. A. Lampi, and B. M. Greenberg, Photochem. Photobiol., 84, 1445–1454 (2008).
G. Tamulaitis, P. Duchovskis, Z. Bliznikas, K. Breiv, R. Ulinskait, A. Brazaityt, A. Novičkovas, and A. Zukauskas, J. Phys. D: Appl. Phys., 38, 3182–3187 (2005).
S. D. Gupta, B. Jatothu, Plant Biotechnol. Rep., 7, 211–220 (2013).
N. Yeh and J. P. Chung, Renew. Sustain. Energy Rev., 13, 2175–2180 (2009).
L. Poulet, G. D. Massa, R. C. Morrow, C. M. Bourget, R. M. Wheeler, and C. A. Mitchell, Lif. Sci. Space Res., 2, 43–53 (2014).
Y. Xie, W. He, F. Li, T. S. H. Perera, L. Gan, Y. Han, X. Wang, S. Li, and H. Dai, ACS Appl. Mater. Interfaces, 27, 10212–10219 (2016).
K. Hasna, S. S. Kumar, M. Komath, M. R.Varma, M. K. Jayaraj, and K. R. Kumar, Phys. Chem. Chem. Phys., 15, 8106–8111 (2013).
A. K. S. Lafarga, F. P. P. Moisés, A. Gurinov, G. G. Ortiz, and G. G. C. Arízaga, Mater. Sci. Eng. C, 48, 541–547 (2015).
C. Rosticher, B. Viana, T. Maldiney, C. Richard, and C. Chanéac, J. Lumin., 170, 460–466 (2016).
V. H. Pham and N. N. Trung, Mater. Lett., 36, 359–361 (2014).
C. X. Thang and V. H. Pham, Mater. Sci. Eng. B, 197, 18–24 (2015).
T. C. Xuan, N. N. Trung, and V. H. Pham, Optik, 126, 5019–5021 (2015).
Y. Han, X. Wang, H. Dai, and S. Li, J. Lumin., 135, 281–287 (2013).
F. R. O. Silva, N. B. de Lima, A. H. A. Bressiani, L. C. Courrol, and L. Gomes, Opt. Mater., 47, 135–142 (2015).
S. Huang, J. Zhu, and K. Zhou, Mater. Res. Bull., 47, 24–28 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 4, p. 680, July–August, 2018
Rights and permissions
About this article
Cite this article
Van, H.N., Tam, P.D. & Pham, VH. Red and Yellow Luminescence of Eu3+/Dy3+ Co-Doped Hydroxyapatite/β-Tricalcium Phosphate Single Phosphors Synthesized Using Coprecipitation Method. J Appl Spectrosc 85, 738–742 (2018). https://doi.org/10.1007/s10812-018-0713-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-018-0713-6