An effective spectroscopic method for estimating the degree of filling (porosity) of polymeric materials, the average size and the size distribution of the scattering particles of the filler within the polymer matrix, their anisotropy and the degree of orientation is proposed. The obtained spectral data are in good agreement with the results of optical and electron microscopy methods.
Similar content being viewed by others
References
J. Z. Liang, J. Appl. Polym. Sci., 104, 1692–1696 (2007).
R. Haggenmueller, C. Guthy, J. R. Lukes, J. E. Fischer, and K. J. Winey, Macromolecules, 40, 2417–2421 (2007).
L. Yu, K. Dean, and L. Li, Prog. Polym. Sci., 31, 576–602 (2006).
F. E. Kesting, Synthetic Polymer Membrane, Wiley, New York (1985).
M. B. Satterfield, P. W. Majstrik, H. Ota, J. B. Benziger, and A. B. Bocarsly, J. Polym. Sci. B: Polym. Phys., 44, 2327–2345 (2006).
D. Dasgupta and A. K. Nandi, Macromolecules, 40, 2008–2018 (2007).
M. N. Malanin, S. D. Khizhnyak, and P. M. Pakhomov, Entsiklopediya Inzhenera-Khimika, No. 10, 9–20 (2008).
P. M. Pakhomov, E. V. Kruglova, and S. D. Khizhnyak, Vysokomol. Soed. B, 42, No. 6, 1081–1086 (2000).
P. M. Pakhomov, M. N. Malanin, E. V. Kruglova, and S. D. Khizhnyak, Vysokomol. Soed., B, 43, No. 4, 764–768 (2001).
P. M. Pakhomov, S. D. Khizhnyak, M. N. Malanin, and Yu. N. Mikhailova, Zavod. Lab.: Diagnostika Mater., 68, No. 5, 31–33 (2002).
P. M. Pakhomov, M. N. Malanin, and S. D. Khizhnyak, Vysokomol. Soed. B, 47, No. 6, 1066–1072 (2005).
S. D. Khizhnyak, M. N. Malanin, K.-J. Eichhorn, and P. M. Pakhomov, Polymer Sci. B, 50, Nos. 5–6, 158–164 (2008).
P. M. Pakhomov, S. D. Khizhnyak, S. Yu. Zharov, and K.-J. Eichhorn, Fibre Chem., 40, No. 3, 253–265 (2008).
V. E. Sitnikova, S. D. Khizhnyak, and P. M. Pakhomov, Europ. Res., 63, No. 11–12, 2666–2674 (2013).
Ed. Bormashenko, R. Pogreb, O. Stanevsky, Y. Bormashenko, St. Tamir, R. Cohen, M. Nunberg, V.-Zeev Gaisina, M. Gorelik, and O.V. Gendelman, Mater. Lett., 59, 2461–2464 (2005).
J. Dechant, Ultrarotspektroskopische Untrsuchungen an Polymeren, Аkademie, Berlin (1972).
G. A. Zisman and O. M. Todes, General Physics Course [in Russian], 3, Nauka, Moscow (1970).
Ya. Rabek, Experimental Methods in the Chemistry of Polymers [in Russian], Part 1, Mir, Moscow (1983).
P. M. Pakhomov, M. N. Malanin, and S. D. Khizhnyak, Vysokomol. Soed. B, 50, No. 6, 1113–1115 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 5, pp. 780–785, September–October, 2017.
Rights and permissions
About this article
Cite this article
Pakhomov, P.M., Khizhnyak, S.D. & Sitnikova, V.E. IR Spectroscopy for the Analysis of Scattering Polymeric Materials* . J Appl Spectrosc 84, 837–842 (2017). https://doi.org/10.1007/s10812-017-0553-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-017-0553-9