Skip to main content
SpringerLink
Log in

Temperature Evolution of the Intra-Ion Absorption Spectra of Cobalt in (NH2(CH3)2)2CoCl4 Crystals

  • Published:
Journal of Applied Spectroscopy Aims and scope

On the basis of spectroscopic studies of (NH 2 (CH 3 ) 2 ) 2 CoCl 4 crystals the absorption bands corresponding to the internal electronic transitions in the Co 2+ ion were identified. The values of Dq and Racah crystal field parameters at room temperature were calculated. Patterns of changes in these parameters upon isomorphous cation and anion substitution were defined for the A 2 CoCl 4 family of crystals, where А = NH 2 (CH 3 ) 2 + , NH 2 (C 2 H 5 ) 2 + , N(CH 3 ) 4 + , N(C 2 H 5 ) 4 + . Evolution of the absorption spectra of (NH 2 (CH 3 ) 2 ) 2 CoCl 4 crystals in the region of their phase transitions at 238 and 263 K was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. D. Williams, P. W. Brown, and N. J. Taylor, Acta Crystallogr., С48, 263–266 (1992).

    Google Scholar 

  2. Z. Czapla and S. Dacko, Ferroelectrics, 125, 17–22 (1992).

    Article  Google Scholar 

  3. K. Hasebe, H. Mashiyama, and S. Tanisaki, J. Phys. Soc. Jpn., 49, 92–94 (1986).

    Google Scholar 

  4. Z. Cummins, Phys. Rep., 185, 211–411 (1990).

    Article  ADS  Google Scholar 

  5. O. Caetano, M. Lopez, A. Mahoui, J. Lapasset, J. Moret, T. Assih, and P. Saint-Gregoire, Ferroelectrics Lett. Sect., 19, 69–74 (1995).

    Article  Google Scholar 

  6. Z. A. Bobrova and V. M. Varikash, Dokl. Akad. Nauk BSSR, 30, 510–512 (1986).

    Google Scholar 

  7. N. Izumi, Bull. Fac. Educ. Kanazawa Univ., 38, 1–5 (1989).

    Google Scholar 

  8. O. G. Vlokh, I. I. Polovinko, and S. A. Sveleba, Fiz. Tverd. Tela, 31, 277–280 (1989).

    Google Scholar 

  9. O. G. Vlokh, M. O. Olkhova, I. I. Polovinko, S. A. Sveleba, and T. M. Sosnowski, Ukr. Fiz. Zh., 35, 1330–1332 (1990).

    Google Scholar 

  10. O. G. Vlokh, I. I. Polovinko, and S. A. Sveleba, Ukr. Fiz. Zh., 34, 673–677 (1989).

    Google Scholar 

  11. O. G. Vlokh, M. I. Bublyk, I. I. Polovinko, M. O. Olkhova, S. A. Sveleba, and T. M. Sosnowski, Pisma Zh. Tekh. Fiz., 16, 23–26 (1990).

    Google Scholar 

  12. О. G. Vlokh, V. В. Kapustianyk, I. I. Polovinko, S. A. Sveleba, Z. A. Bobrova, and V. М. Varikash, Ferroelectrics, 125, 183–189 (1992).

    Article  Google Scholar 

  13. V. В. Kapustianyk, Yu. M. Korchak, S. A. Sveleba, and V. I. Mokryi, Zh. Prikl. Spektrosk., 67, No. 1, 91–95 (2000).

    Google Scholar 

  14. V. Rudyk, I. Kityk, V. Kapustianyk, and K. Ozga, Ferroelectrics, 330, 19–24 (2006).

    Article  Google Scholar 

  15. V. Kapustianyk, V. Rudyk, M. Partyka, I. Kityk, and S. Tkaczyk, J. Phys.: Conf. Ser., 79, 1–8 (2007).

    Google Scholar 

  16. V. Kapustianyk, Ya. Shchur, I. Kityk, V. Rudyk, G. Lach, L. Laskowski, S. Tkaczyk, J. Swiatek, and V. Davydov, J. Phys.: Condens. Matter, 20, 365215 (2008).

  17. G. Lakshminarayana, V. Kapustianyk, K. Ozga, V. Rudyk, I. V. Kityk, M. G. Brik, J. Berdowski, and Z. Tylczynski, Appl. Phys. A, 104, 721–726 (2011).

    Article  ADS  Google Scholar 

  18. A. Lever, Inorganic Electronic Spectroscopy [Russian translation], Mir, Moscow (1987).

    Google Scholar 

  19. V. B. Kapustianyk, V. V. Bazhan, and Yu. M. Korchak. Phys. Status Solidi (b), 234, 674–688 (2002).

    Article  ADS  Google Scholar 

  20. G. A. Kiosse, A. J. Oleshuk, Z. A. Bobrov, L. A. Shuvalov, and T. I. Malinowski, Kristallografiya, 5, 1146–1149 (1989).

    Google Scholar 

  21. V. B. Kapustianyk, Physics of Crystalline Ferroics with an Organic Cation [in Russian], Ed. Center of LNU, Lviv, (2006).

    Google Scholar 

  22. V. B. Kapustianyk, Phys. Status Solidi (b), 207, 509–520 (1997).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivan Franko National University of Lviv, 50 Dragomanov Str., Lviv, 79005, Ukraine

    V. B. Kapustianyk & P. K. Yonak

  2. Scientific-Technical and Educational Center of Low Temperature Studies of Ivan Franko National University of Lviv, Lviv, Ukraine

    V. B. Kapustianyk & V. P. Rudyk

Authors
  1. V. B. Kapustianyk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. K. Yonak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Rudyk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. K. Yonak.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 82, No. 4, pp. 557–563, July–August, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kapustianyk, V.B., Yonak, P.K. & Rudyk, V.P. Temperature Evolution of the Intra-Ion Absorption Spectra of Cobalt in (NH2(CH3)2)2CoCl4 Crystals. J Appl Spectrosc 82, 591–597 (2015). https://doi.org/10.1007/s10812-015-0150-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-015-0150-8

Keywords

Search

Navigation