Absorption bands corresponding to all types of hydroxyl associates [νas = 3476 cm–1 (OH…OH); νas = 3472 cm–1 (OH…N3); and νas = 3457 cm–1 (OH…O)] were assigned using IR spectroscopy in CH2Cl2 and n-butanol and its mixtures with various proton acceptors (THF, hexylazide, azide-containing oxetane monomers). The order of concentrations for these associates was \( {C_{{\mathrm{OH}\ldots \mathrm{O}\mathrm{H}}}}\ll {C_{{\mathrm{OH}\ldots {{\mathrm{N}}_3}}}}\ll {C_{{\mathrm{OH}\ldots \mathrm{O}}}} \). Equilibrium formation constants were estimated quantitatively. The proton-acceptor abilities of the studied additives were established.
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References
G. C. Pimental and A. L. McClellan, The Hydrogen Bond, Freeman, San Francisco and London (1960).
N. D. Sokolov (ed.), Hydrogen Bond [in Russian], Nauka, Moscow (1981), pp. 112–248.
M. J. Gorman, J. Chem. Ed., 33, 468–472 (1956).
M. Davies, Annu. Rep. Prog. Chem., 43, No. 1, 35–43 (1946).
G. A. Jeffrey and W. Saenger, Hydrogen Bonding in Biological Structures, Springer Verlag, New York (1991).
V. A. Grigor’eva, V. V. Komratova, A. I. Kuzev, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 25, No. 10, 2182–2187 (1983).
V. V. Komratova, V. A. Grigor’eva, Yu. A. Ol’khov, G. A. Gorbushina, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 25, No. 6, 1169–1172 (1983).
E. V. Stovbun, E. R. Badamshina, V. A. Grigor’eva, V. P. Lodygina, A. I. Kuzaev, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 40, No. 8, 1286–1293 (1998).
E. V. Stovbun, V. P. Lodygina, Z. S. Andrianova, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 19, No. 12, 2500–2504 (1987).
E. V. Stovbun, V. P. Lodygina, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 38, No. 7, 1104–1109 (1996).
E. V. Stovbun, V. P. Lodygina, E. R. Badamshina, V. A. Grigor’eva, I. V. Doronona, and S. M. Baturin, Heterophase Network Polymers. Synthesis, Characterization and Properties, B. A. Rozenberg and G. M. Sigalov (Eds.), Taylor & Francis, London, New York (2002), pp. 129–138.
M. A. Zaverkina, Kinetics of Reactions Occurring During Synthesis of Polyurethane Thermoelastomers Based on Oligooxetanediols [in Russian], Candidate Dissertation in Chemical Sciences, Chernogolovka (2007), pp. 53–54.
A. Weissberger and E. S. Proskauer, Organic Solvents, 2nd edn., rev. by J. A. Riddick and E. E. Toops, Jr., Inter science Pubs., Inc., New York (1955).
M. P. Gafurova, V. P. Lodygina, V. A. Grigor’eva, G. I. Chernyi, V. V. Komratova, and S. M. Baturin, Vysokomol. Soedin., Ser. A, 24, No. 4, 858–863 (1982).
O. L. I. Brown, H. E. Cary, G. S. Skinner, and E. J. Wright, J. Phys. Chem., 61, 103–105 (1957).
A. I. Kuzaev, S. I. Solomko, O. M. Ol’khova, G. A. Mirontseva, A. E. Tarasov, and M. N. Tyapkina, Zh. Prikl. Khim., 80, No. 7, 1147–1150 (2007).
M. A. Zaverkina, V. P. Lodygina, V. V. Komratova, E. V. Stovbun, and E. R. Badamshina, Vysokomol. Soedin., Ser. A, 48, No. 4, 608–613 (2006).
M. A. Zaverkina, V. P. Lodygina, E. V. Stovbun, E. R. Badamshina, and Yu. M. Mikhailov, Vysokomol. Soedin., Ser. B, 53, No. 9, 1642–1647 (2011).
U. Barbieri, T. Keicher, and G. Polacco, e-Polym., 46, 1–11 (2003).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 1, pp. 11–18, January–February, 2014.
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Zaverkina, M.A., Lodygina, V.P. & Badamshina, E.R. IR-Spectroscopic Study of Hydrogen Bonds in n-Butanol and its Mixtures with Various Proton Acceptors. J Appl Spectrosc 81, 7–14 (2014). https://doi.org/10.1007/s10812-014-9879-8
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DOI: https://doi.org/10.1007/s10812-014-9879-8