Spectroscopic studies of the surface laser plasma formed by the action of sequential high-power double laser pulses close to a porous body containing microquantities of ammonium polyuranates showed that the intensities of uranium spectral lines that are proportional to the elemental content in the plasma depend significantly on the physicochemical properties of the uranium compounds. The line intensities increase by several times with almost the same increase in the formation enthalpy of the compounds.
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Z. R. Ismagilov, S. V. Kuntsevich, V. V. Kuznetsov, N. V. Shikina, M. A. Kerzhentsev, V. A. Rogov, and V. A. Ushakov, Kinet. Katal., 48, No. 4, 544–553 (2007).
G. J. Hutchings and S. H. Taylor, Catal. Today, 49, 105–113 (1999).
G. J. Hutchings, C. S. Heneghan, I. D. Hudson, and S. H. Taylor, Nature, 384, 341–343 (1996).
R. K. Grasselli and J. L. Callahan, J. Catal., 14, 93–103 (1969).
V. C. Corberan, G. Kremenic, and G. Tejuca, React. Kinet. Catal. Lett., 36, 235–240 (1988).
L. G. Gordeeva, Yu. I. Aristov, E. M. Moroz, N. A. Rudina, V. I. Zaikovskii, Yu. Yu. Tanashev, and V. N. Parmon, J. Nucl. Mater., 218, 202–209 (1995).
R. V. Selyanin, V. N. Brendakov, and V. P. Pishchulin, in: Proceedings of the Branch Scientific-Technical Conference "Technology and Automation of Atomic Energy" [in Russian], Seversk, May 17–20, 2005, SGTI, Seversk (2005).
I. S. Kurina, V. V. Popov, and V. N. Rumyantsev, At. Energ., 101, No. 5, 347–351 (2006).
J. J. Katz, G. T. Seaborg, and L. R. Morss (eds.), The Chemistry of the Actinide Elements, 2nd ed., Chapman and Hall, London and New York (1986).
V. B. Shevchenko and B. N. Sudarikov, Technology of Uranium [in Russian], Gosatomizdat, Moscow (1961), pp. 250–253.
E. A. Ippolitova, N. I. Pechurova, and E. N. Gribennik, in: Research in Uranium Chemistry [in Russian], MGU, Moscow (1961), pp. 96–107.
I. D. Abdelrazek, W. I. Zidan, H. A. Farag, and M. F. Barakat, Nukleonika, 50, No. 2, 57–60 (2005).
B. Ayaz and A. N. Bilge, J. Nucl. Mater., 280, 45–50 (2000).
A. Deptula, Nukleonika, 7, 265–274 (1962).
B. N. Murty, P. Balakrishna, R. B. Yadav, and C. Ganguly, Powder Technol., 115, 167–183 (2001).
S. Rajagopal, T. P. S. Asari, and C. S. P. Iyer, J. Nucl. Mater., 227, 300–303 (1996).
W. I. Stuart and T. L. Whateley, J. Inorg. Nucl. Chem., 31, 1639–1647 (1969).
C. N. Turcanu and R. Deju, Nucl. Technol., 45, 188–192 (1979).
R. Vuillemey, "Controbution to the Chemical and Technological Study of Ammonium Diuranate Precipitation," Report CEA 2004, Saclay Nuclear Study Center, France (1962).
V. N. Brendakov, Yu. N. Dement?ev, S. N. Kladiev, and V. P. Pishchulin, Izv. Tomsk. Politekhn. Univ., 308, No. 6, 95–98 (2005).
D. C. Fee, I. Jonson, S. A. Davis, W. A. Shinn, G. E. Staahl, and C. E. Jonson, "The Cs–U–O Phase Diagram and its Application to Uranium-Plutonium Oxide Fast Reactor Fuel Pins," Report ANL-76-126 (1977).
C. Fanrong, R. C. Ewing, and S. B. Clark, Am. Mineral., 84, 650–664 (1999).
E. H. P. Cordfunke and P. A. G. O’Hare, The Chemical Thermodynamics of Actinide Elements and Compounds, Part 3, International Atomic Energy Agency, Vienna (1978).
E. A. Medina, E. V. Suleimanov, A. V. Golubev, and O. A. Egorova, Vestn. Nizhegorodsk. Gos. Univ., No. 4, 72–74 (2007).
I. T. Goronovskii, Yu. P. Nazarenko, and E. F. Nekryach, Brief Handbook of Chemistry [in Russian], Naukova Dumka, Kiev (1987).
B. H. Parks and N. W. Hille, "Reoxidation of Partially Oxidizable Powders," US Pat. No. 4,751,098, Westinghouse Electric Corp. (1988).
R. I. Larson, R. P. Ringle, and J. L. Harmon, "Method for Passivating Uranium Oxides to Control Oxidation and the Oxidation Resisting Uranium Product," US Pat. No. 5,066,429, General Electric Company (1991).
G. G. Potoskaev, V. S. Kurskov, and N. A. Balagurov, "Method for Preparing Fuel Pellets" [in Russian], RF Pat. No. 2,456,731 (1999).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 78, No. 3, pp. 384–390, May–June, 2011.
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Zazhogin, A.P., Umreiko, D.S., Patapovich, M.P. et al. Influence of physicochemical properties of ammonium uranates on formation of uranium oxides by the action of laser radiation. J Appl Spectrosc 78, 358–364 (2011). https://doi.org/10.1007/s10812-011-9470-5
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DOI: https://doi.org/10.1007/s10812-011-9470-5