Fourier-transform IR absorption, Raman, and surface-enhanced Raman scattering spectra are presented for phenylfluorone, which is widely used as an analytical reagent in the photometric determination of high-valent metals from Groups III–VI of the Periodic Table. A geometric structure and vibrational frequencies for the phenylfluorone molecule were calculated using a quantum-mechanical density-functional method. An interpretation of its vibrational spectra was proposed for the first time. Spectral effects of phenylfluorone protonation have been studied. The geometry of phenylfluorone adsorbed on the surface of nanostructured silver films was examined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. A. Nazarenko and V. P. Antonovich, Trihydroxyfluorones [in Russian], Nauka, Moscow (1973).
V. G. Amelin and O. I. Abramenkova, Zh. Anal. Khim., 63, 1217–1226 (2008).
V. G. Amelin and O. I. Abramenkova, Zh. Anal. Khim., 62, 1316–1318 (2007).
F. A. Chmilenko, O. V. Mikulenko, T. S. Chmilenko, and E. V. Matorina, Khim. Tekhnol. Vody, 29, 254–260 (2007).
R. Aroca, Surface-Enhanced Vibrational Spectroscopy, John Wiley & Sons, Chichester (2006).
G. S. Petrova, Yu. S. Ryabokobilko, A. M. Lukin, N. N. Visokova, and R. V. Poponova, Anal. Lett., 5, 695–701 (1972).
V. P. Antonovich, E. I. Shelikhina, B. V. Zhadanov, and V. A. Nazarenko, Zh. Anal. Khim., 27, 100–107 (1972).
A. Yu. Panarin, V. S. Chirvonyi, K. I. Kholostov, P.-I. Tyurpen, and S. N. Terekhov, Zh. Prikl. Spektrosk., 76, No. 2, 298–306 (2009).
D. N. Laikov, J. Chem. Phys., 281, 151–156 (1997).
D. N. Laikov, “Development of an economical approach to the calculation of molecules by the density-functional method and its application to the solution of complicated chemical problems,” Candidate Dissertation in Physical-Mathematical Sciences, Moscow (2000).
L. L. Gladkov and K. N. Solovyov, Biofizika, 42, 26–33 (1997).
S. N. Terekhov, L. L. Gladkov, O. L. Gladkova, M. V. Parkhots, I. A. Khodasevich, A. Yu. Panarin, and P.-I. Tyurpen, Opt. Spektrosk., 106, 919–927 (2009).
L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Polyatomic Molecules [in Russian], Nauka, Moscow (1970).
L. J. Bellamy, The Infrared Spectra of Complex Molecules, Methuen & Co., London (1958).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 78, No. 2, pp. 181–190, March–April, 2011.
Rights and permissions
About this article
Cite this article
Gladkova, O.L., Panarin, A.Y. & Terekhov, S.N. Vibrational spectra of phenylfluorone and their interpretation. J Appl Spectrosc 78, 165–173 (2011). https://doi.org/10.1007/s10812-011-9442-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-011-9442-9