New bands within the ranges of 1900–2200 and 700–1000 cm–1 have been discovered in the IR absorption spectra of crystalline alkali-earth fluorides. It is found that the defects responsible for the high frequency bands facilitate the formation of color centers during crystal growth. These bands are presumably caused by valence vibrations of CO molecules. The low frequency bands are attributed to molecular complexes which contain oxygen-vacancy dipoles.
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R. Kalchgruber, H. J. Goksu, E. Hochnauser, and G. A. Wagner, Radiat. Meas., 35, 585–590 (2002).
K. Prokert and M. Sommer, Radiat. Prot. Dosim., 78, 249–257 (1998).
N. Kristianpoller, D. Weiss, and R. Chen, Radiat. Meas., 38, 719–722 (2004).
N. Kristianpoller, W. Chen, D. Weiss, D. Kuzmin, and R. Chen, Phys. Status Solidi (c), 4, 1110–1113 (2007).
N. Kristianpoller, D. Weiss, N. Khaidukov, and V. Makhov, R. Chen, Radiat. Meas., 43, 245–248 (2008).
L. O. Arantes, R. B. Ferreira, R. P. M. Carvalhaes, and A. R. Blak, Radiat. Meas., 43, 227–230 (2008).
V. Denks, A. Maaroos, V. Nagirnyi, T. Savikhina, and V. Vassiltsenko, J. Phys.: Condens. Matter, 11, 3115–3125 (1999).
Y. Shimizu, M. Minowa, W. Suganuma, and Y. Inoue, Phys. Lett. B, 633, 195–200 (2006).
J. Selling, M. D. Birowosuto, P. Dorenbos, and S. Schweizer, Phys. Status Solidi (c), 4, 976–979 (2007).
A. B. Bel’skii, M. A. Gan, I. A. Mironov, and R. P. Seisyan, Opt. Zh., 76, No. 8, 59–69 (2009).
E. Faulques, J. Wery, B. Dulieu, C. Seybert, and D. L. Perry, J. Fluores., 8, 283–287 (1998).
E. Radzabov, J. Phys.: Condens. Matter, 13, 10955–10967 (2001).
J. Laberguerie, P. Gredin, M. Mortier, G. Patriarche, and A. Kozak, Z. Anorg. Allg. Chem., 632, 1538–1543 (2006).
I. Nicoara, M. Munteanu, N. Pecingina-Garjoaba, M. Stef, E. Preda, and A. Lucaci, Phys. Status Solidi (c), 4, 1234-1237 (2007).
I. V. Stepanov and P. P. Feofilov, Dokl. AN SSSR, 108, 615–618 (1957).
D. C. Stockbarger, J. Opt. Soc. Am., 39, 731–740 (1949).
V. M. Reiterov and Z. N. Korneva, Opt. Spektrosk., 21, 583–587 (1966).
V. V. Ratnam, Phys. Status Solidi, 16, 559–567 (1966).
R. Rauch, Izv. AN SSSR, Ser. Fiz., 37, 595–598 (1973).
R. Rauch, R. Reimann, and G. Schwotzer, Phys. Status Solidi (a), 23, 69–78 (1974).
R. Rauch and G. Schwotzer, Phys. Status Solidi (a), 74, 123–132 (1982).
W. Boulmann, Phys. Status Solidi (a), 40, 49–53 (1977).
W. Boulmann, Phys. Status Solidi (a), 57, 601–607 (1980).
A. V. Arkhangel’skaya, V. M. Reiterov, and L. M. Trofimova, Zh. Prikl. Spektrosk., 32, 103–109 (1980).
A. V. Arkhangel’skaya, Spectroscopy of Crystals [in Russian], Nauka, Moscow (1970), pp. 143–153.
S. I. Kachan and Z. P. Chornii, FTT, 48, 239–242 (2006).
A. Smakula, Phys. Rev., 77, 408–409 (1950).
W. Roland, Jr. and Ure, J. Chem. Phys., 26, 1363–1373 (1957).
J. Sierro, J. Chem. Phys., 34, 2183–2184 (1961).
W. Bollmann, Kristall und Technik, 15, 359–366 (1980).
A. I. Nepomnyashchikh and P. V. Figura, Opt. Spektrosk., 65, 1395–1397 (1988).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir, Moscow (1966), pp. 125, 137, 151, 246–249.
L. Bellamy, Infrared Spectra of Molecules [Russian translation], Inonstr. Lit, Moscow (1957), pp. 145, 154–155, 393.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 77, No. 1, pp. 113–118, January–February, 2010.
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Bryukvina, L.I., Penzina, É.É. Formation of color centers during growth of alkali-earth fluoride crystals. J Appl Spectrosc 77, 104–109 (2010). https://doi.org/10.1007/s10812-010-9299-3
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DOI: https://doi.org/10.1007/s10812-010-9299-3