Skip to main content
SpringerLink
Log in

Effect of oxygen impurity on the efficiency of the formation of complexes with H-bond and aggregation of color centers in lithium fluoride

  • Impurity Centers
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The effect of impurities on the efficiency of the formation of color centers and hydrogen-bonded molecular complexes upon exposure to various radiations in lithium fluoride crystals grown in air is studied. The results of experiments for measuring optical properties, IR vibrational spectra, luminescence, and thermally stimulated luminescence are presented. The fact that the band in the range of 1800–2300 cm–1 corresponds to stretching vibrations of a complex with strong hydrogen bond is proved based on the Fermi-resonance perturbation in the region of 2080 cm–1, shaped as the Evans hole and bands A, B, and C. It is shown that the composition of these complexes includes an OH– ion and an HF molecule. The crucial role of O2‒ V + a oxygen dipoles in the aggregation efficiency and gradient distribution of color centers and radiation resistance of hydroxyl ions is revealed. It is shown that products of radiation decomposition of OH– ions stimulate, while decay of O2‒ V + a dipoles suppress, the formation of positively charged color centers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. I. Nepomnyashchikh, E. A. Radzhabov, and A. V. Egranov, Color Centers and Luminescence in LiF Crystals (Nauka, Novosibirsk, 1984) [in Russian].

    Google Scholar 

  2. H. A. Ivanov, D. V. Inshakov, I. A. Parfianovich, and V. M. Khulugurov, Sov. Tech. Phys. Lett. 12 (10), 517 (1986).

    Google Scholar 

  3. L. C. Courrol, R. E. Samad, L. Gomes, I. M. Ranieri, S. L. Baldochi, A. Z. de Freitas, and N. D. Vieira, Opt. Lett. 12, 288 (2004).

    Google Scholar 

  4. L. Bryukvina, J. Lumin. 162, 145 (2015).

    Article  Google Scholar 

  5. T. G. Stoebe, J. Phys. Chem. Solids 28, 1375 (1967).

    Article  ADS  Google Scholar 

  6. T. G. Stoebe, J. Phys. Chem. Solids 31, 1291 (1970).

    Article  ADS  Google Scholar 

  7. P. D. Alekseev and T. I. Baranov, Sov. Phys. Solid State 22 (4), 706 (1980).

    Google Scholar 

  8. L. A. Lisitsyna and V. M. Lisitsyn, Phys. Solid State 55 (11), 2297 (2013).

    Article  ADS  Google Scholar 

  9. E. Freytag, Z. Phys. 177, 206 (1964).

  10. A. Chandra, J. Chem. Phys. 51, 1499 (1969).

  11. L. I. Bryukvina, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 9, 101 (1988).

    Google Scholar 

  12. L. I. Bryukvina and V. M. Khulugurov, Sov. Phys. Solid State 30 (3), 533 (1988).

    Google Scholar 

  13. G. C. Pimentel and A. L. McClellan, The Hydrogen Bond (Freeman, San Francisco, California, 1960; Mir, Moscow, 1964).

    Google Scholar 

  14. A. Novak, Struct. Bonding (Berlin) 18, 177 (1974).

    Article  Google Scholar 

  15. N. D. Sokolov, Hydrogen Bond (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  16. L. I. Bryukvina, V. M. Khulugurov, and I. A. Parfianovich, Zh. Prikl. Spektrosk. 48, 322 (1988).

    Google Scholar 

  17. R. M. Grant and J. R. Cameron, J. Appl. Phys. 37, 3791 (1966).

    Article  ADS  Google Scholar 

  18. X. L. Yuan and S. W. S. McKeever, Phys. Status Solidi A 108, 545 (1988).

    Article  ADS  Google Scholar 

  19. W. Wachter, N. J. Vana, and H. Aiginger, Nucl. Instrum. Methods Phys. Res. 175, 21 (1980).

    Article  ADS  Google Scholar 

  20. N. Takeuchi, K. Inabe, and S. Nakamura, J. Mater. Sci. Lett. 2, 39 (1983).

    Article  Google Scholar 

  21. A. V. Egranov and E. A. Radzhabov, Spectroscopy of Oxygen and Hydrogen Impurity Centers in Alkali Halide Crystals (Nauka, Novosibirsk, 1992) [in Russian].

    Google Scholar 

  22. H. Dotsch, W. Gebhardt, and C. H. Martius, Solid State Commun. 3, 297 (1965).

    Article  ADS  Google Scholar 

  23. M. L. Meistrich, J. Phys. Chem. Solids 29, 1119 (1968).

    Article  ADS  Google Scholar 

  24. J. Nahum, Phys. Rev. 158, 814 (1967).

    Article  ADS  Google Scholar 

  25. B. D. Lobanov, V. M. Khulugurov, and I. A. Parfianovich, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 4, 81 (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Irkutsk National Research Technical University, ul. Lermontova 83, Irkutsk, 664074, Russia

    S. A. Nebogin & N. A. Ivanov

  2. Irkutsk Division of Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, ul. Lermontova 130a, Irkutsk, 664033, Russia

    L. I. Bryukvina & D. S. Glazunov

Authors
  1. S. A. Nebogin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Bryukvina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. S. Glazunov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. I. Bryukvina.

Additional information

Original Russian Text © S.A. Nebogin, L.I. Bryukvina, N.A. Ivanov, D.S. Glazunov, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 6, pp. 1118–1124.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nebogin, S.A., Bryukvina, L.I., Ivanov, N.A. et al. Effect of oxygen impurity on the efficiency of the formation of complexes with H-bond and aggregation of color centers in lithium fluoride. Phys. Solid State 59, 1139–1145 (2017). https://doi.org/10.1134/S1063783417060178

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783417060178

Search

Navigation