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Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors

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Abstract

Novel nanorod-like manganese-based metal–organic frameworks (Mn-MOFs) were prepared through a facile solvothermal method using 1,3,5-benzentricarboxylic acid as organic linker and applied as electroactive material for supercapacitors. The Mn-MOFs exhibited a high-specific capacitance of 371 F g−1 at 0.5 A g−1 and an excellent rate capability even if the current density was promoted to 10 A g−1. Furthermore, the designed asymmetric supercapacitors with Mn-MOFs as cathode, graphene as anode and 6 mol L−1 KOH as electrolyte delivered a specific capacitance of 89 F g−1 in the working potential range of 0 to 1.6 V and the energy density can reach 31.6 Wh kg−1. Notably, the specific capacitance of the fabricated hybrid supercapacitors retained 91.8% of the initial capacitance after successive 10,000 charge–discharge cycles at a current density of 1 A g−1. These results suggest that the as-synthesized nanorod-shaped Mn-MOFs can act as promising electrode materials for high-performance supercapacitors.

Graphical abstract

Nanorod-like Mn-MOFs were prepared and investigated as promising electroactive nanomaterials for supercapacitors, which exhibited a high-specific capacitance of 371 F g-1, excellent rate capability and long cycle life with an eminent energy density of 31.6 Wh kg-1 for the designed Mn-MOFs//graphene supercapacitor.

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Acknowledgements

We gratefully thank the National Natural Science Foundation of China (Grant Nos. 21773018 and 21573025), Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 17KJA150001), and Foundation of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology (Grant No. BM2012110) for support of this work.

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Authors and Affiliations

  1. School of Petrochemical Engineering, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, 213164, China

    Juan Xu, Yonghong Yang, Yan Wang, Jianyu Cao & Zhidong Chen

  2. Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Jiangsu Key Laboratory of Materials Surface Science and Technology, Changzhou, 213164, China

    Juan Xu, Yonghong Yang & Zhidong Chen

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  1. Juan Xu
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  2. Yonghong Yang
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  3. Yan Wang
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  4. Jianyu Cao
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  5. Zhidong Chen
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Correspondence to Jianyu Cao or Zhidong Chen.

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Xu, J., Yang, Y., Wang, Y. et al. Enhanced electrochemical properties of manganese-based metal organic framework materials for supercapacitors. J Appl Electrochem 49, 1091–1102 (2019). https://doi.org/10.1007/s10800-019-01352-9

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