Skip to main content
Log in

Environmentally friendly natural polyhydroxylic compounds in electroless copper plating baths: application of xylitol, D-mannitol and D-sorbitol as copper(II) ligands

  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The possibility of using xylitol, D-mannitol and D-sorbitol as Cu(II) ligands in electroless copper baths was demonstrated. The ligands mentioned showed good chelating properties for Cu(II) ions in alkaline media (pH > 11.5), i.e. under conditions of the use of traditional formaldehyde-containing solutions. Electroless copper plating solutions containing the chelators xylitol, D-mannitol and D-sorbitol are stable and, under the optimal conditions selected, copper coatings up to 3 μm thick can be obtained in 1 h at ambient temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • M. Šalkauskas A. Vaškellis (1985) ‘Chemical Metallizing of Plastics’ Khimiya Leningrad

    Google Scholar 

  • A. Vaškelis M. Šalkauskas (1986) ‘Plastics Finishing and Decoration’ D. Satas (Eds) Van Nostrand Reinhold Company Van Nostrand Reinhold Company New York

    Google Scholar 

  • G.O. Mallory J.B. Hajdu (1990) Electroless Plating: Fundamentals and Applications American Electroplaters and Surface Finishers Society Orlando

    Google Scholar 

  • A. Vaškelis D. Satas A.A. Tracton (Eds) (2001) ‘Coating Technology Handbook’ Marcel Dekker New York 213

    Google Scholar 

  • L.G. Sillen A.E. Martell (1964) ‘Stability Constants of Metal-Ion Complexes. Special Publication No 25 Supplement No 1’ Chemical Society London

    Google Scholar 

  • E. Högfeld (1982) ‘Stability Constants of Metal-Ion Complexes. Part A: Inorganic Ligands’ Pergamon Press Oxford

    Google Scholar 

  • M.D. Tucker L.L. Barton B.M. Thompson B.M. Wagener A. Aragon (1999) Waste Manage. 19 477

    Google Scholar 

  • M. Sillanpää V. Vaičiuniené L. Niinistö M.-L. Sihvonen (1997) Chemosphere 35 2797

    Google Scholar 

  • K. Hegetschweiler (1999) Chem. Soc. Rev. 28 239

    Google Scholar 

  • K. Burger and L. Nagy, in K. Burger (Ed), ‘Bio Coordination Chemistry: Coordination Equilibria in Biologically Active Systems’, (Elis Hoorwood, Chichester, 1990), p. 236.

  • J.-F. Verchère S. Chapelle F. Xin D.C. Crans (1998) NoChapterTitle K.D. Karlin (Eds) ‘Progress in Inorganic Chemistry’ John Wiley & Sons New York 837

    Google Scholar 

  • G. Rozovskis A. Vaškelis (Eds) (1966) ‘Electroless Copper Plating’ RMTIPI Vilnius

    Google Scholar 

  • A. Vaškelis (1967) Metal Protect. 3 472

    Google Scholar 

  • A. Vaškelis G. Rozovskis J. Kulšytë (1971) Metal Protect. 7 558

    Google Scholar 

  • H. Koyano M. Kato H. Takenouchi (1992) J. Electrochem. Soc. 139 3112

    Google Scholar 

  • S. Ohno (1971) Plating 58 350

    Google Scholar 

  • I.M. Kolthoff R. Belcher V.A. Stenger G. Matsuyama (1957) Volumetric Analysis Vol. 3 Titration Methods Oxidation–Reduction Reactions New York

    Google Scholar 

  • E. Norkus, J. Vaičiuniené, T. Vuorinen, E. Gaidamauskas, J. Reklaitis, A.-S. Jääskeläinen and D.C. Crans, Carbohydr. Res. in press.

  • E. Norkus, R. Pauliukaitė, A. Vaškelis, E. Butkus, Z. Jusys and M. Krenevièienë, J. Chem. Res.(S) N6 (1998) 320.

  • E. Norkus R. Pauliukaitë (2001) J. Solution Chem. 30 55

    Google Scholar 

  • A. Vaškelis E. Norkus R. Juškënas E. Matulionis G. Stalnionis (1995) Galvanotechnik 89

    Google Scholar 

  • A. Vaškelis, Trans. Lithuanian Acad. Sci. B4 (1966) 3.

  • E. Norkus A. Vaškelis I. Stalnionienė (2000) J. Solid State Electrochem. 4 337

    Google Scholar 

  • A. Vaškelis E. Norkus I. Stalnionienė G. Stalnionis (2004) Electrochim. Acta 49 1613

    Google Scholar 

  • E. Norkus J. Vaičiuniené J. Reklaitis E. Gaidamauskas D.C. Crans (2002) Chemija (Vilnius) 13 119

    Google Scholar 

  • E. Norkus A. Vaškelis (1994) Polyhedron 13 3041

    Google Scholar 

  • E. Norkus J. Vaičiuniené J. Reklaitis E. Gaidamauskas D.C. Crans (2002) Chemija (Vilnius) 13 129

    Google Scholar 

  • F. Franks J. Dadok S. Ying R.L. Kay J.R. Grigera (1991) J. Chem. Soc Faraday Trans. 87 579

    Google Scholar 

  • R. Peat S. Shannon (1983) J. Electroanal. Chem. 159 229

    Google Scholar 

  • M.J. Sottomayor F. Silva (1994) J. Electroanal. Chem. 376 59

    Google Scholar 

  • L. Proença M.I.S. Lopes I. Fonseca A. Rodes R. Gómez A. Aldaz (1998) Electrochim. Acta 44 1163

    Google Scholar 

  • A.J. Silva L. Proença M.I.S Lopes I. Fonseca A. Rodes A. Aldaz (2001) Electrochim. Acta 46 3147

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. Norkus.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Norkus, E., Vaškelis, A., Jačiauskiene, J. et al. Environmentally friendly natural polyhydroxylic compounds in electroless copper plating baths: application of xylitol, D-mannitol and D-sorbitol as copper(II) ligands. J Appl Electrochem 35, 41–47 (2005). https://doi.org/10.1007/s10800-004-2056-7

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10800-004-2056-7

Keywords

Navigation