Skip to main content
SpringerLink
Log in

Formation of Gaseous Negative Ions of Fluoro and Trifluoromethyl Derivatives of C60 Fullerene Studied by Knudsen-Cell Mass Spectrometry

  • Published:
Inorganic Materials Aims and scope

Abstract

Experimental procedures are described for producing negative ions of fluoro and trifluoromethyl derivatives of C60 in the vapor phase and characterizing them by Knudsen-cell mass spectrometry. Some common aspects of the formation of such ions are established, and the associated ion-molecule equilibria are investigated. Electron affinity data are presented for C60(CF3)2n molecules. It is shown that, upon ionization, the fluorofullerenes tend to loose one or several fluorine atoms.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Brink, C., Andersen, L.H., Hvelplund, P., et al., Laser Photodetachment of C −60 and C −70 Ions Cooled in a Storage Ring, Chem. Phys. Lett., 1995, vol. 233, pp. 52–56.

    Article  CAS  Google Scholar 

  2. Zhou, F., Van Berkel, G.J., and Donovan, B.T., Electron-Transfer Reactions of Fluorofullerene C60F48, J. Am. Chem. Soc., 1994, vol. 116, no.12, pp. 5485–5486.

    Article  CAS  Google Scholar 

  3. Boudon, C., Gisselbrecht, J.-P., Gross, M., et al., Electrochemistry of Mono-through Hexakis-Adducts of C60, Helv. Chim. Acta, 1995, vol. 78, pp. 1334–1344.

    Article  CAS  Google Scholar 

  4. Suzuki, T., Kikuchi, K., Oguri, F., et al., Electrochemical Properties of Fullerenolanthanides, Tetrahedron, 1996, vol. 52, no.14, pp. 4973–4982.

    Article  CAS  ISI  Google Scholar 

  5. Yamamoto, E., Tansho, M., Tomiyama, T., et al., 13C-NMR Study on the Structure of Isolated Sc2C84 Metallofullerene, J. Am. Chem. Soc., 1996, vol. 118, no.9, pp. 2293–2294.

    Article  CAS  Google Scholar 

  6. Anderson, M.R., Dorn, H.C., Stevenson, S., et al., The Electrochemistry of Sc3C82, J. Am. Chem. Soc., 1997, vol. 119, pp. 437–438.

    CAS  Google Scholar 

  7. Hettich, R.L., Ying, C., and Compton, R.N., Determination of the Electron Affinities of Fluorinated Fullerenes (C60F44.46, C70F52.54) by Fourier Transform Mass Spectrometry, Int. J. Mass Spectrom. Ion Processes, 1994, vol. 138, no.1, pp. 263–274.

    Article  CAS  Google Scholar 

  8. Sidorov, L.N., Zhuravleva, L.V., and Sorokin, I.D., High-Temperature Mass Spectrometry and Studies of Ion-Ion, Ion-Molecule, and Molecule-Molecule Equilibria, Mass Spectrom. Rev., 1986, vol. 5, no.1, pp. 73–97.

    Article  CAS  Google Scholar 

  9. Sidorov, L.N. and Boltalina, O.V., Endohedral Metallofullerenes and Exohedral Fluorofullerenes, Usp. Khim., 2002, vol. 71, no.7, pp. 609–640.

    Google Scholar 

  10. Vasil'ev, Yu.V., Boltalina, O.V., Tuktarov, R.F., et al., Resonant Free Electron Capture Spectra of C60F48, Int. J. Mass. Spectrom. Ion Processes, 1998, vol. 173, no.1/2, pp. 113–125.

    Google Scholar 

  11. Cozzolino, R., Belgacem, O., Drewello, T., et al., Laser Desorption/Ionisation of Fluorinated Fullerenes, Eur. J. Mass Spectrom., 1997, vol. 3, no.6, pp. 407–414.

    CAS  Google Scholar 

  12. Borshchevskii, A.Ya., Aleshina, V.E., Sidorov, L.N., et al., Solid-State Fluorination of C60 Fullerene: Theory and Experiment, Vestn. Mosk. Univ., Ser. 2: Khim., 2003, vol. 44, no.6, pp. 363–371.

    CAS  Google Scholar 

  13. Sidorov, L.N., Nikulin, V.V., Chilingarov, N.S., and Korobov, M.V., Enthalpy of Formation of CoF −4 , Zh. Fiz. Khim., 1987, vol. 61, no.4, pp. 1078–1080.

    CAS  Google Scholar 

  14. Nikitin, M.I., Igolkina, N.A., Skokan, E.V., et al., Enthalpy of Formation of AlF −4 , Zh. Fiz. Khim., 1986, vol. 60, no.1, pp. 39–42.

    CAS  Google Scholar 

  15. Boltalina, O.V., Dashkova, E.V., and Sidorov, L.N., Gibbs Energies of Gas-Phase Electron Transfer Reactions Involving the Larger Fullerene Anions, Chem. Phys. Lett., 1996, vol. 256, pp. 253–260.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob'evy gory 1-3, Moscow, 119992, Russia

    A. Ya. Borshchevskii, V. E. Aleshina, V. Yu. Markov, E. I. Dorozhkin & L. N. Sidorov

Authors
  1. A. Ya. Borshchevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. E. Aleshina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Yu. Markov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. I. Dorozhkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. N. Sidorov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Neorganicheskie Materialy, Vol. 41, No. 12, 2005, pp. 1493–1501.

Original Russian Text Copyright © 2005 by Borshchevskii, Aleshina, Markov, Dorozhkin, Sidorov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borshchevskii, A.Y., Aleshina, V.E., Markov, V.Y. et al. Formation of Gaseous Negative Ions of Fluoro and Trifluoromethyl Derivatives of C60 Fullerene Studied by Knudsen-Cell Mass Spectrometry. Inorg Mater 41, 1318–1326 (2005). https://doi.org/10.1007/s10789-005-0309-4

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10789-005-0309-4

Keywords

Search

Navigation