Abstract
The structure of the ternary compound Nb5Si3 − x P0.5 + x (x = 0–0.5) is determined by single-crystal x-ray diffraction: sp. gr. P63 mc, a = 1.32350(5) nm, c = 0.52954(1) nm; R F = 0.028, R w = 0.081 for 547 reflections with F hkl > 4.0σ(F hkl ). Relations between the structure of Nb5Si3 − x P5 + x , the Mn5Si3 structure type, and its derivatives are discussed.
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REFERENCES
Lomnytska, Ya.F. and Koval', L.V., Phase Relations in the Nb-Si-P and Ta-Si-P Systems, Zh. Neorg. Khim., 1996, vol. 41, no.11, pp. 1925–1927.
Aksel'rud, L.G., Grin, Yu.N., Pecharsky, V.K., and Zavalij, P.Yu., CSD97—Universal Program Package for Single Crystal and Powder Data Treatment, Version no. 7, 1997.
Emsley, J., Die Elemente, Berlin: Gruyter, 1994.
Kripyakevich, P.I., Strukturnye tipy intermetallicheskikh soedinenii (Structure Types of Intermetallic Compounds), Moscow: Nauka, 1977.
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Translated from Neorganicheskie Materialy, Vol. 41, No. 10, 2005, pp. 1212–1217.
Original Russian Text Copyright © 2005 by Lomnytska, Oryshchyn, Kuz'ma, Guerin.
An erratum to this article is available at http://dx.doi.org/10.1007/s10789-005-0315-6.
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Lomnytska, Y.F., Oryshchyn, S.V., Kuz'ma, Y.B. et al. Crystal Structure of Nb5Si3 − x P0.5 + x (x = 0–0.5). Inorg Mater 41, 1067–1072 (2005). https://doi.org/10.1007/s10789-005-0262-2
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DOI: https://doi.org/10.1007/s10789-005-0262-2