Abstract
The phase compatibility diagram of the Pb-Tm-Te system is constructed, and the pseudobinary joins in the Pb-TmTe-Te system at 850°C are identified. A partial phase diagram of the PbTe-Tm2Te3 join is mapped out using x-ray diffraction and differential thermal analysis data. The lattice parameter of PbTe〈Tm〉 solid solutions is determined as a function of thulium content at the Pb- and Te-rich phase boundaries of lead telluride.
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REFERENCES
Akimov, B.A., Zlomanov, V.P., Ryabova, L.I., et al., Promising IR Optoelectronic Materials Based on IV–VI Compounds, Vysokochist. Veshchestva, 1991, no. 6, pp. 22–35.
Rustamov, P.G., Abilov, Ch.I., and Mamedov, M.R., PbTe-TmTe System: Phase Diagram and Properties of Phases, Neorg. Mater., 1999, vol. 35, no.2, pp. 164–165 [Inorg. Mater. (Engl. Transl.), vol. 35, no. 2, pp. 113–114].
Dorofeev, S.G., Volodin, V.D., Tyurin, A.V., et al., Synthesis and Properties of PbTe-Tm2Te3 Solid Solutions, Neorg. Mater., 1999, vol. 35, no.8, pp. 934–936 [Inorg. Mater. (Engl. Transl.), vol. 35, no. 8, pp. 789-791].
Abrikosov, N.Kh. and Shelimova, L.E., Poluprovodnikovye materialy na osnove soedinenii A IV B VI (IV–VI Semiconductor Materials), Moscow: Nauka, 1975.
Petzel, T., Ludwigs, J., and Greis, O., Thermodynamics of Sublimation and Crystal Chemistry of Tm0.77Te, J. Less-Common Met., 1989, vol. 154, pp. 317–328.
Mills, K.C., Thermodynamic Data for Inorganic Sulphides, Selenides, and Tellurides, London: Butterworths, 1974.
Dorofeev, S.G., Lebedev, A.I., Nikitenko, S.G., et al., Charge State of Thulium in PbTe by XANES, III Natsional’naya konferentsiya po primeneniyu rentgenovskogo, sinkhrotronnogo izluchenii, neitronov i elektronov dlya issledovaniya materialov (III Natl. Conf. on the Application of X-rays, Synchrotron Radiation, Neutrons, and Electrons in Materials Characterization), Moscow, 2001, p. 98.
Palenzona, A. and Cirefici, S., Dynamic Differential Calorimetry of Intermetallic Compounds: II. Heat of Formation, Heat and Entropies of Fusion of Rare-Earth-Lead (RePb3) Compounds, Thermochim. Acta, 1973, vol. 6, no.4, pp. 455–460.
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Translated from Neorganicheskie Materialy, Vol. 41, No. 6, 2005, pp. 662–666.
Original Russian Text Copyright © 2005 by Dorofeev, Vinokurov, Tananaeva, Zlomanov, Kuznetsova.
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Dorofeev, S.G., Vinokurov, A.A., Tananaeva, O.I. et al. Phase Relations in the Pb-Tm-Te System. Inorg Mater 41, 570–575 (2005). https://doi.org/10.1007/s10789-005-0171-4
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DOI: https://doi.org/10.1007/s10789-005-0171-4