Abstract
A laser-based apparatus for determining the hydrogen diffusion constant in gas mixtures is described. The main units of the apparatus are a diffusion chamber and a computer-based laser system for the selective diagnostics of hydrogen in gas mixtures by coherent anti-Stokes Raman scattering (CARS) in combination with biharmonic pumping based on stimulated Raman scattering. The diffusion constant is estimated by approximating the experimental data that describe changes in the hydrogen concentration with time at a fixed point in the diffusion chamber and comparing them to the exact solution to the diffusion equation for the chosen one-dimensional experimental geometry.
Similar content being viewed by others
REFERENCES
Suetin, P.E., Shchegolev, G.T., and Klestov, R.A., Zh. Tekh. Fiz., 1959, vol. 29, no.8, p. 1058 [Tech. Phys. (Engl. Transl.), 1959, vol. 4, no. 8, p. 964].
Al'zhanov, K.Z., Inzh.-Fiz. Zh., 1998, vol. 71, no.4, p. 710.
Mikheev, G.M., Mogileva, T.N., Popov, A.Yu., and Kalyuzhnyi, D.G., Prib. Tekh. Eksp.,, 2003, no. 2, p. 101 [Instrum. Exp. Tech. (Engl. Transl.), 2003, vol. 46, no. 2, p. 233].
Regnier, P.R. and Taran, J.P.E., Appl. Phys. Lett., 1973, vol. 23, no.5, p. 240.
Akhmanov, S.A. and Koroteev, N.I., Metody nelineinoi optiki v spektroskopii rasseyaniya sveta (Methods of Nonlinear Optics in Spectroscopy of Light Scattering), Moscow: Nauka, 1981.
Mikheev, G.M. and Mogileva, T.N., Kvantovaya Electron. (Moscow), 1996, vol. 23, no.10, p. 943 [Quantum Electron. (Engl. Transl.), 1996, vol. 26, no. 10. p. 919].
Mikheev, G.M. and Mogileva, T.N., Int. J. Hydrogen Energy, 1999, vol. 24, no.9, p. 833.
Mikheev, G.M., Kalyuzhnyi, D.G., Popov, A.Yu., and Mogileva, T.N., Zh. Tekh. Fiz., 2005, vol. 75, no.2, p. 82 [Tech. Phys. (Engl. Transl.), 2005, vol. 50, no. 2, p. 220].
Matveev, A.N., Molekulyarnaya fizika (Molecular Physics), Moscow: Vysshaya Shkola, 1981.
Fizicheskie velichiny: Spravochnik (Physical Quantities: A Handbook), Grigor'ev, I.S. and Meilikhov, E.Z., Eds., Moscow: Energoatomizdat, 1991.
Author information
Authors and Affiliations
Additional information
__________
Translated from Pribory i Tekhnika Eksperimenta, No. 5, 2005, pp. 119–123.
Original Russian Text Copyright © 2005 by Mikheev, Popov, Mogileva.
Rights and permissions
About this article
Cite this article
Mikheev, G.M., Popov, A.Y. & Mogileva, T.N. A Laser-Based Apparatus for Estimating the Hydrogen Diffusion Constant in Gas Mixtures. Instrum Exp Tech 48, 671–674 (2005). https://doi.org/10.1007/s10786-005-0120-0
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10786-005-0120-0