Skip to main content
Log in

Magnetic and 57Fe Mössbauer Studies of Fe1 − xMnxSb2 system (0 ≤ x ≤ 0.2)

  • Conference Proceeding
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

A Correction to this article was published on 18 August 2023

This article has been updated

Abstract

The results of the 57Fe Mössbauer spectroscopic studies performed at 25 K are reported here for the polycrystalline Fe0.8Mn0.2Sb2 and FeSb2 systems. The spectra of Fe0.8Mn0.2Sb2 at 25 K exhibited a magnetically broadened spectral shape. The magnetic measurements for these two specimens have been performed in the temperature range 2–350 K using MPMS SQUID magnetometer and externally applied magnetic fields of 2 and 20 kOe. From the shape of the M-H curve for Fe0.8Mn0.2Sb2 it may be said that it is behaving like a weakly ferromagnetic material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

Data availability

The data that support the findings of this study are available from the corresponding author, upon reasonable request.

Change history

References

  1. L, A.K., Fan, G.H., Rosenthal, H.L., Mckinzie, A., Wold: Preparation and Properties of FeAs2 and FeSb2. J. Solid State Chem. 5, 136–143 (1972)

    Article  ADS  Google Scholar 

  2. Steger, J., Kostiner, E.: Mössbauer effect study of FeSb2. J. Solid State Chem. 5, 131–135 (1972)

    Article  ADS  Google Scholar 

  3. Petrovic, J.W., Kim, S.L., Bud’ko, I., Goldman, C., Canfield, et al.: Anisotropy and large magnetoresistance in the narrow-gap semiconductor FeSb2. Phys. Rev. B 67, 155205 (4) (2003)

  4. Yamaguchi, G., Shimada, M., Koizumi, M., Kanamaru, F.: Preparation and characterization of compounds of the system Fe(Sb1 – xTex)2 (0 ≤ x ≤ 1.0). J. Solid State Chem. 34, 241 (1980)

    Article  ADS  Google Scholar 

  5. Gonçalves da Silva, C.E.T.: Magnetic susceptibility of FeSb2: A quasi-magnetic Semiconductor. Solid State Comm. 33, 63–68 (1980)

    Article  Google Scholar 

  6. Sharma, R.K., Sharma, Y.K.: Synthesis, XRD and 57Fe Mössbauer studies of the pseudo-binary Fe1 – xMnxSb2 alloys. Ind. J. Pure & Appl. Phys. 44, 325–329 (2006)

    Google Scholar 

  7. Sharma, R.K., Thesis, P.D.: Univ. of Raj., Jaipur, India (2006)

  8. Chikina, A., Ma, J.Z., Brito, W.H., et al.: Correlated electronic structure of colossal thermopower FeSb2: An ARPES and ab inito study. Phys. Rev. Research. 2, 023190 (2020)

    Article  ADS  Google Scholar 

  9. Takahashi, H., Okazaki, R., Ishiwata, S., Taniguchi, H., Okutani, A., M.Hagiwara, and, Terasaki, I.: Colossal Seebeck effect enhanced by quasi-ballistic phonons dragging massive electrons in FeSb2. Nat. Comm. 7, 12732 (2016)

    Article  ADS  Google Scholar 

  10. Homes, C.C., Du, Q., Petrovic, C., Brito, W.H., Choi, S., Kotliar, G.: Unusual electronic and vibrational properties in the colossal thermopower material FeSb2. Sci. Rep. 8, 11692 (2018)

    Article  ADS  Google Scholar 

  11. Tomczak, J.M.: Thermoelectricity in correlated narrow-gap semiconductors. J. Phys. : Condens. Matter. 30, 183001 (2018)

    ADS  Google Scholar 

  12. Petrovic, C., Lee, Y., Vogt, T., Lazarov, N.D., Bud’ko, S.L., Canfield, P.C.: Kondo Insulator description of spin state transition in FeSb2. Phys. Rev. B 72, 045103(7) (2005)

  13. Rongwei Hu, R.P., Hermann, F., Grandjean, Y., Lee, J.B., Warren, V.F., Mitrovic, C., Petrovic: Weak ferromagnetism in Fe1 – xCoxSb2. Phys. Rev. B. 76, 224422 (2007)

    Article  ADS  Google Scholar 

Download references

Funding

Not applicable.

Author information

Authors and Affiliations

Authors

Contributions

The authors confirm contribution to the paper as follows: study conception and design: Vijay Sharma, M. P. Sharma; data collection: Vijay Sharma; analysis and interpretation of results: Vijay Sharma; draft manuscript preparation: M. P. Sharma. All authors reviewed the results and approved the final version of the manuscript.

Corresponding author

Correspondence to M. P. Sharma.

Ethics declarations

Ethical approval

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

The copyright holder for this article was incorrectly given as ‘© Springer Nature Switzerland AG 2023’ but should have been ‘© The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023’. The original paper has been corrected.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharma, V., Oudhia, A. & Sharma, M.P. Magnetic and 57Fe Mössbauer Studies of Fe1 − xMnxSb2 system (0 ≤ x ≤ 0.2). Hyperfine Interact 244, 12 (2023). https://doi.org/10.1007/s10751-023-01823-8

Download citation

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10751-023-01823-8

Keywords

Navigation