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Quadrupole interactions in tetraoxoferrates (VI)

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Abstract

An applicability of the point charge approach for calculations of quadrupole splittings in Mössbauer spectra of ferrates(VI) was studied. The reasonable correlation between calculated and experimental splittings was observed for the majority of ferrates excepting K3Na(FeO4)2. The comparison of ferrates and chromates was made using calculated nucleus independent coefficient.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, Russia

    Sergey K. Dedushenko & Yurii D. Perfiliev

  2. Department of Physics, Moscow State University, Moscow, Russia

    Vyacheslav S. Rusakov & Alexei M. Gapochka

Authors
  1. Sergey K. Dedushenko
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  2. Yurii D. Perfiliev
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  3. Vyacheslav S. Rusakov
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  4. Alexei M. Gapochka
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Corresponding author

Correspondence to Sergey K. Dedushenko.

Additional information

Proceedings of the 4th Joint International Conference on Hyperfine Interactions and International Symposium on Nuclear Quadrupole Interactions (HFI/NQI 2012), Beijing, China, 10–14 September 2012.

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Dedushenko, S.K., Perfiliev, Y.D., Rusakov, V.S. et al. Quadrupole interactions in tetraoxoferrates (VI). Hyperfine Interact 222, 67–72 (2013). https://doi.org/10.1007/s10751-013-0765-1

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  • DOI: https://doi.org/10.1007/s10751-013-0765-1

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