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Transparent Glass-Ceramic Materials Based on Lead Fluoroborate Glasses Co-Activated by Eu/Gd

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Transparent glass-ceramic materials co-activated by Eu3+/Gd3+ were obtained by heat treatment of the initial lead fluoroborate glasses. It was found that the rare-earth ions in the obtained transparent samples are located in nanoparticles of lead fluoride cubic crystals, distributed in the bulk of the glass. It was shown that Eu3+ ions are situated in a highly symmetric local environment and that the introduction of a second activator increases the nanocrystalline phase fraction.

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References

  1. P. P. Fedorov, A. A. Luginina, and A. I. Popov, “Transparent oxyfluoride glass ceramics,” J. Fluorine Chem., 172, 22 – 50 (2015).

    Article  CAS  Google Scholar 

  2. P. A. Loiko, G. E. Rachkovskaya, N. A. Skoptsov, et al., “Mechanisms of upconversion luminescence in glass-ceramics containing Er:PbF2 nanocrystals,” Zh. Prikl. Spektrosk., 84(1), 172 – 180 (2017).

    Google Scholar 

  3. F. Zeng, G. Ren, X. Qiu, et al., “The effect of PbF2 content on the microstructure and upconversion luminescence of Er3+-doped SiO2–PbF2 –PbO glass ceramics,” J. Non-Cryst. Solids, 354, 3428 – 3432 (2008).

    Article  CAS  Google Scholar 

  4. Yu. V. Orlovskii, T. T. Basiev, K. K. Pukhov, et al., “Multiphonon relaxation of mid IR transitions of rare-earth ions in fluorite type crystals,” in: Proceedings Volume of the Advanced Solid-State Photonics 2004, Gregory Quarles, Optical Society of America, Washington (2004), Vol. 94, pp. 440 – 445.

  5. I. Richman, “Longitudinal optical phonons in CaF2, SrF2 and BaF2 ,” J. Chem. Phys., 41(9), 2836 – 2837 (1964).

    Article  CAS  Google Scholar 

  6. V. A. Aseev, E. V. Kolobkova, K. S. Moskaleva, et al., “Luminescent properties of ytterbium-erbium nanostructured lead fluoride silicate glass-ceramics at low temperatures,” Opt. Spectroscopy, 114(5), 751 – 755 (2013) [Opt. Spektrosk., 114(5), 818 – 823 (2013)].

  7. O. B. Petrova and A. V. Khomyakov, “Lead fluorosilicate glass ceramics doped with Nd3+, Er3+, and Yb3+,” Opt. Spectroscopy, 114(6), 876 – 879 (2013) [Opt. Spektrosk., 114(6), 962 – 966 (2013)].

  8. O. B. Petrova, A. V. Popov, V. E. Shukshin, et al., “Lead borate oxyfluoride glasses doped with Nd3+ ions and transparent glass-crystal materials based on them,” J. Opt. Technol., 78(10), 659 – 663 (2011) [Opt. Spektrosk., 78(10), 30 – 35 (2011)].

  9. J. Pisarska, W. Ryba-Romanowski, and G Dominiak-Dzik, “Nd-doped oxyfluoroborate glasses and glass-ceramics for NIR laser applications,” J. Alloys Compounds, 451, 223 – 225 (2008).

    Article  CAS  Google Scholar 

  10. O. Petrova, T. Sevostjanova, A. Khomyakov, et al., “Luminescent glass-ceramics based on nanoparticles of BaxRE1–xF2+x and PbxRE1–xF2+x solid solutions into fluoroborate,” Phys. Status Solidi A, 1700446 (2018).

  11. T. S. Sevostjanova, A. V. Khomyakov, O. B. Petrova, et al., “Luminescent properties of solid solutions in the PbF2–EuF3 system and lead fluoroborate glass ceramics doped with Eu3+ ions,” Opt. Spectroscopy, 123(5), 733 – 742 (2017) [Opt. Spektrosk., 123(5), 734 – 744 (2017)].

  12. O. B. Petrova, D. A. Velichkina, M. P. Zykova, et al., “Nd/La, Nd/Lu-co-doped transparent lead fluoroborate glass-ceramics,” J. Non-Cryst. Solids, 531, 119,858 – 119,864 (2020).

    Article  CAS  Google Scholar 

  13. A. K. Tyagi, S. J. Patwe, and S. N. Achary, “Phase relation studies in Pb1–x MxF2+x systems (0.0 ≤ x ≤ 1.0; M = Nd3+, Eu3+ and Er3+,” J. Solid State Chem., 177, 1746 – 1757 (2004).

  14. B. P. Sobolev, The Rare Earth Trifluorides, Institute of Crystallography, Moscow, Russia; Institut d’Estudis Catalans, Barcelona, Spain (2000).

  15. I. E. Kolesnikov, D. V. Tolstikova, A. V. Kurochkin, et al., “Concentration effect on photoluminescence of Eu3+-doped nanocrystalline YVO4 ,” J. Lumin., 158, 469 – 474 (2015).

    Article  CAS  Google Scholar 

  16. D. R. Foster, F. S. Richardson, L. M. Vallarino, et al., “Magnetic circularly polarized luminescence spectra of Eu (beta.-diketonate) 3X2 complexes in nonaqueous solution,” Inorg. Chem. ACS Publ., 22(26), 4002 – 4009 (1983).

    Article  CAS  Google Scholar 

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This work was supported by the Ministry of Science and Higher Education of the Russian Federation, grant FSSM-2020-0003.

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Correspondence to K. I. Runina.

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Translated from Steklo i Keramika, No. 1, pp. 16 – 20, January, 2021.

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Velichkina, D.A., Runina, K.I., Zykova, M.P. et al. Transparent Glass-Ceramic Materials Based on Lead Fluoroborate Glasses Co-Activated by Eu/Gd. Glass Ceram 78, 14–17 (2021). https://doi.org/10.1007/s10717-021-00340-w

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  • DOI: https://doi.org/10.1007/s10717-021-00340-w

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