The possibility of increasing the strength of ceramic by introducing the ceramic-forming polymer polydimethylsilane into the batch is examined. Upon the introduction of polydimethylsilane into the mix a transition of polydimethylsilane into polycarbosilane is observed in the presence of the catalyst molybdenum chloride and is followed by a transition of polycarbosilane into silicon carbide. It is shown that the introduction of this additive with weight content > 4% increases strength and decreases open porosity.
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References
S. Yajima, Y. Hasegawa, K. Okamura, and T. Matsuzawa, “Development of high tensile strength silicon carbide fibre using an organosilicon polymer precursor,” Nature, 273, 525 – 527 (1978).
H. Q. Ly, R. Taylor, and J. Day, “Conversion of polycarbosilane (PCS) to SiC-based ceramic. Part I. Characterization of PCS and Curing product,” Mater. Sci., 36, 4037 – 4043 (2011).
D. Frazer, M. D. Abad, D. Krumwiede, et al., “Localized mechanical property assessment of SiC/SiC composite materials,” Composites, Pt A, Appl. Sci. Manuf., 70, 93 – 101 (2015).
T. Shimoo, I. Tsukada, M. Narisawa, et al., “Change in properties of polycarbosilane-derived SiC fibers at high temperatures,” J. Ceram. Soc. Jpn., 110, 559 – 563 (1997).
V. Yu. Chukhlanov, E. P. Sysoev, and E. N. Tereshina, “Heat-insulating materials based on ceramic-forming organosilicon binder,” Syntact Glass Ceram., Nos. 5 – 6, 145 – 147 (2005).
V. Yu. Chukhlanov, O. G. Selivanov, E. S. Pikalov, and N. V. Chukhlanova, Method of Producing Heat-Resistant High-Strength Ceramic, Patent Application for Invention No. 2017115517, May 2, 2017 [in Russian].
Z. Chun-man, Li Xiao-dong, W. Hao, and Z. Bin, “Thermal stability and curing kinetics of polycarbosilane fibers,” Trans. Nonferrous Met. Soc., No. 10, 44 – 48 (2006).
V. Yu. Chukhlanov, et al., “Enhancement of the dielectric properties of ceramic in the centimeter microwave range by structural modification of pyrogenic silicon dioxide by nanoparticles,” Steklo Keram., No. 7, 12 – 14 (2016); V. Yu. Chukhlanov, et al., “Enhancement of the dielectric properties of ceramic in the centimeter microwave range by structural modification of pyrogenic silicon dioxide by nanoparticles,” Glass Ceram., 73(7 – 8), 149 – 167 (2016).
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Translated from Steklo i Keramika, No. 9, pp. 22 – 24, September, 2017.
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Chukhlanov, V.Y., Selivanov, O.G., Chukhlanova, N.V. et al. Modification of Ceramic by Organosilicon Polymer Capable of Transitioning Into Silicon Carbide. Glass Ceram 74, 323–325 (2018). https://doi.org/10.1007/s10717-018-9986-8
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DOI: https://doi.org/10.1007/s10717-018-9986-8