SHS-Metallurgy methods were used to obtain samples in the form of aluminum oxynitride Al5O6N ingots (AlON) using mixtures of the thermit type. The experiments were performed in SHS reactors at initial nitrogen pressure 5 MPa. The optimal conditions for the synthesis of the most stable phase of aluminum oxynitride Al5O6N were determined. Regimes were developed for comminuting the synthesized ingots into powder with definite fractions. Spark plasma sintering (SPS) was used to obtain from them experimental samples with high density, hardness, and transparency.
Similar content being viewed by others
References
X. J. Liu, F. Chen, and F. Zhang, “Hard transparent AlON ceramic for visible/IR windows,” Int. J. Refr. Met. Hard Mater., No. 39, 38 – 43 (2013).
J.W. McCauley, P. M. Chen, et al., “AlON: Abrief history of its emergence and evolution,” J. Europ. Ceram. Soc., No. 29, 223 – 236 (2009).
X. D. Wang, D. Sichen, and W. C. Seetharaman, “Kinetic studies of the oxidation of γ-aluminum oxynitride,” Metall. Mater. Trans. B, 33(2), 201 – 207 (2002).
Y. W. Li, N. Li, R. Z. Yuan, et al. Effect of raw materials on carbothermal reduction synthesis of γ-aluminum oxynitride spinel powder,” J. Mater. Sci., 34(11), 2547 – 2552 (1999).
S. Bandyopadhyay, G. Rixecker, F. Aldinger, et al., “Effect of reaction parameters on γ-AlON formation from Al2O3 and AlN,” J. Amer. Ceram. Soc., 85(4), 1010 – 1012 (2002).
F. C. Sahin, H. E. Kanbur, and B. Apak, “Preparation of AlON ceramics via reactive spark plasma sintering,” J. Europ. Ceram. Soc., 32(4), 925 – 929 (2012).
X. Yuan, X. Liu, F. Zhang, and S. Wang, “Synthesis of c-AlON powders by a combinational method of carbothermal reduction and solid-state reaction,” J. Amer. Ceram. Soc., 93(1), 22 – 24 (2010).
D. Zientara, M. Bucko, and J. Lis, “AlON-based materials prepared by SHS technique,” J. Europ. Ceram. Soc., 27(2 – 3), 775 – 779 (2007).
J. Lee, I. Lee, H. Chung, et al., “Self-propagating high-temperature synthesis for aluminum oxynitride (AlON),” Mater. Sci. Forum, 510 – 511, 662 – 665 (2006).
V. A. Gorshkov, A. G. Tarasov, and V. I. Yukhvid, “Autowave synthesis of cast aliuminum oxynitrides with high nitrogen content,” Khim. Fiz., 29(4), 51 – 55 (2010).
V. A. Gorshkov, A. A. Samboruk, and V. I. Yukhvid, “Chemical and phase compositions of the products of combustion of thermit-type mixtures based on chromium, lanthanum, and calcium oxides,” Khim. Fiz., 28(10), 48 – 51 (2009).
V. A. Gorshkov, “Advanced ceramics based on aluminum, silicon, chromium, and lanthanum oxides: preparation and applications (an overview),” Int. J. Self-Prop. High-Temp. Synth., 20(4), 273 – 276 (2011).
N. Zhang, B. Liang, X. Y. Wang, et al., “The pressureless sintering and mechanical properties of AlON ceramic,” Mater. Sci. Eng. A, 528, 6259 – 6262 (2011).
E. A. Olevskii, E. V. Aleksandrova, A. M. Il’ina, et al., “Electro-consolidation of powdered materials. I. Methods of lowvoltage and high-voltage consolidation,” Fiz. Khim. Obrab. Mater., No. 2, 53 – 64 (2013).
J. Hennicke and H. U. Kessel, Field Assisted Sintering Technology (“FAST”) for the Consolidation of Innovative Materials; cfi/Ber. DKG81 [11] (2004) E14-E16.
A. Shiryaev, “Thermodynamics of SHS processes: An advanced approach,” Int. J. SHS, 4(4), 351 – 362 (1995).
The equipment used to perform these investigations was provided by the Distribution Center for Collective Use ISMAN. This work was supported by RFFI Grant No. 16-08-00499.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Steklo i Keramika, No. 6, pp. 10 – 15, June, 2017.
Rights and permissions
About this article
Cite this article
Gorshkov, V.A., Grigor’ev, E.G., Miloserdov, P.A. et al. Compact Aluminum Oxynitride Based Ceramic Obtained by the SHS-Metallurgy Method. Glass Ceram 74, 199–203 (2017). https://doi.org/10.1007/s10717-017-9961-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10717-017-9961-9