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Synthesis of polyphosphate glasses

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Multicomponent spatially cross-linked polymers based on ultraphosphates with vitrification temperature 123 – 302°C have been synthesized. Their hydraulic stability (rate of mass loss when boiled in water) was measured and equals 0.0075 – 0.123 g/min. It is shown that there is a correlation between the vitrification temperature of polymers and their water resistance. Aquantitative relation was obtained for the flow temperature and the vitrification temperature of the polymers: t f = t v + (25 – 35)°C. It is shown that in principle it is possible to obtain on the basis of ultraphosphates high-temperature inorganic thermoplastics with flow temperature varying over wide limits.

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Authors and Affiliations

  1. Glass Institute JSC, Moscow, Russia

    T. K. Pavlushkina & I. V. Morozova

Authors
  1. T. K. Pavlushkina
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  2. I. V. Morozova
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Correspondence to T. K. Pavlushkina.

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Translated from Steklo i Keramika, No. 10, pp. 18 – 21, October, 2010.

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Pavlushkina, T.K., Morozova, I.V. Synthesis of polyphosphate glasses. Glass Ceram 67, 312–315 (2011). https://doi.org/10.1007/s10717-011-9286-z

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