Abstract
IR spectroscopic and x-ray phase analysis established the structural specifics of glasses in the system Na2O-SiO2-TiO2-Na3AlF6, as well as the dependence on the type of crystallizing phases on the chemical composition of the glass matrix. The effect of the structure of titanium-bearing clusters on the leachability of glasses, the effect of the second coordination sphere on the coordination of the central cation (Ti4+), and the propensity of experimental glass coatings to opacification are registered.
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Translated from Steklo i Keramika, No. 11, pp. 3–6, November, 2005.
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Belyi, Y.I., Minakova, N.A. The effect of titanium dioxide on structure and properties of boron-free glasses. Glass Ceram 62, 337–340 (2005). https://doi.org/10.1007/s10717-006-0001-4
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DOI: https://doi.org/10.1007/s10717-006-0001-4