Skip to main content
Log in

Study of the Structure of Iron-Containing Zinc Borate Glass

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

The results of the experimental study of glass of the xFe2O3–(100–x)[40ZnO. 60B2O3] composition in which the content of iron oxide varies from 0 to 10 mol % are presented. The regularities of the glass structure change in the short- and intermediate-range order structures are considered based on the data of infrared spectroscopy and Raman spectroscopy. The valence and coordination state of iron in a glass matrix is studied by Mössbauer spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kajinami, A., Harada, Y., Inoue, S., Deki, S., and Umesaki, N., The structural analysis of zinc borate glass by laboratory EXAFS and X-ray diffraction measurements, Jpn. J. Appl. Phys., 1999, vol. 38, no. 1, pp. 132–135.

    Article  Google Scholar 

  2. Moncke, D., Kamitsos, E.I., Palles, D., Limbach, R., Winterstein-Beckmann, A., Honma, T., Yao, Z., Rouxel, T., and Wondraczek, L., Transition and posttransition metal ions in borate glasses: borate ligand speciation, cluster formation, and their effect on glass transition and mechanical properties, J. Chem. Phys., 2016, vol. 145, pp. 124501-1–124501-16.

    Article  Google Scholar 

  3. Yao, Z.Y., Moncke, D., Kamitsos, E.I., Houizot, P., Celarie, F., Rouxel, T., and Wondraczek, L., Structure and mechanical properties of copper-lead and copperzinc borate glasses, J. Non-Cryst. Solids, 2016, vol. 435, pp. 55–68.

    Article  Google Scholar 

  4. Stefan, R., Pascuta, P., Popa, A., Raita, O., Indrea, E., and Culea, E., XRD and EPR structural investigation of some zinc borate glasses doped with iron ions, J. Phys. Chem. Solids, 2012, vol. 73, pp. 221–226.

    Article  Google Scholar 

  5. Scholze, H., Glass: Nature, Structure and Properties, New York: Springer, 1990.

    Google Scholar 

  6. Anavekar, R.V., Devaraj, N., Ramesh, K.P., and Ramakrishna, J., Mössbauer effect and electron paramagnetic resonance studies on zinc borate glasses containing transition metal oxides, Phys. Chem. Glasses, 1992, vol. 33, no. 4, pp. 116–121.

    Google Scholar 

  7. Pascuta, P., Borodi, G., Bosca, M., Pop, L., Rada, S., and Culea, E., Preparation and structural characterization of some Fe2O3–B2O3–ZnO glasses and glass ceramics, J. Phys.: Conf. Ser., 2009, vol. 182, pp. 012072-1–012072-4.

    Google Scholar 

  8. Harrison, D.E. and Hummel, F.A., Phase equilibria and fluorescence in the system zinc oxide–boric oxide, J. Electrochem. Soc., 1956, vol. 103, no. 9, pp. 491–498.

    Article  Google Scholar 

  9. Ehrt, D., Zinc and manganese borate glasses—phase separation, crystallization, photoluminescence and structure, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2013, vol. 54, no. 2, pp. 65–75.

    Google Scholar 

  10. Bronswijk, J.P. and Strijks, E., The Raman spectrum of vitreous and crystalline B2O3, J. Non-Cryst. Solids, 1977, vol. 24, pp. 145–147.

    Article  Google Scholar 

  11. Galeener, F.L., Lucovsky, J., and Mikkelsen, J.C., Vibrational spectra and structure of pure vitreous B2O3, Phys. Rev. B, 1980, vol. 22, no. 8, pp. 3983–3990.

    Article  Google Scholar 

  12. Pereira, A.S., Perottoni, C.A., and Jornada, J.A.H., Raman spectroscopy as a probe for in situ studies of presser-induced amorphization: some illustrative examples, J. Raman Spectrosc., 2003, vol. 34, pp. 578–586.

    Article  Google Scholar 

  13. Gautam, C., Yadav, A.K., and Singh, A.K., A review on infrared spectroscopy of borate glasses with effects of different additives, ISRN Ceram., 2012, vol. 2012, 17 p.

  14. Pascuta, P., Maniu, D., and Ardelean, I., Structural investigation of Fe2O3–B2O3–KF glasses by IR and Raman spectroscopies, Int. J. Mod. Phys. B, 2004, vol. 18, nos. 10–11, pp. 1651–1658.

    Article  Google Scholar 

  15. Doweidar, H., El-Damrawi, G., Mansour, E., and Fetouh, R.E., Structural role of MgO and PbO in MgO–PbO–B2O3 glasses as revealed by FTIR; a new approach, J. Non-Cryst. Solids, 2012, vol. 358, pp. 941–946.

    Article  Google Scholar 

  16. Doweidar, H. and Saddeek, Y.B., FTIR and ultrasonic investigations on modified bismuth borate glasses, J. Non-Cryst. Solids, 2009, vol. 355, pp. 348–354.

    Article  Google Scholar 

  17. Rao, T.R., Reddy, Ch.V., Krichna, Ch.R., Sathish, D.V., Rao, P.S., and Ravikumar, R.V.S.S.N., Spectroscopic investigations on physical properties of Mn2+ doped mixed alkali zinc borate glasses, Mater. Res. Bull., 2011, vol. 46, pp. 2222–2229.

    Article  Google Scholar 

  18. Ardelean, I., Lungu, R., and Pascuta, P., Structural changes induced by Fe2O3 addition in strontium-borate glass matrix, J. Mater. Sci.: Mater. Electron., 2007, vol. 18, no. 8, pp. 837–841.

    Google Scholar 

  19. Motke, S.G., Yawale, S.P., and Yawale, S.S., Infrared spectra of zinc doped lead borate glasses, Bull. Mater. Sci., 2002, vol. 25, no. 1, pp. 75–78.

    Article  Google Scholar 

  20. Colak, S.C., Akyuz, I., and Atay, F., On the dual role of ZnO in zinc-borate glasses, J. Non-Cryst. Solids, 2016, vol. 432, pp. 406–412.

    Article  Google Scholar 

  21. Bale, S., Rahman, S., Awasthi, A.M., and Sathe, V., Role of Bi2O3 content on physical, optical and vibrational studies in Bi2O3–ZnO–B2O3 glasses, J. Alloys Compd., 2008, vol. 460, pp. 699–703.

    Article  Google Scholar 

  22. Gaafar, M.S., Abd, El-AalN.S., Gerges, O.W., and El-Amir, G., Elastic properties and structural studies on some zinc-borate glasses derived from ultrasonic, FT-IR and X-ray techniques, J. Alloys Compd., 2008, vol. 460, pp. 699–703.

    Article  Google Scholar 

  23. Glazkova, Ya.S., Kalmykov, S.N., Presnyakov, I.A., Stefanovskaya, O.I., and Stefanovskii, S.V., The structural state of iron in multicomponent aluminum iron borosilicate glass depending on their composition and synthesis conditions, Glass Phys. Chem., 2015, vol. 41, no. 4, pp. 367–377.

    Article  Google Scholar 

  24. Ram, S. and Ram, K., IR investigation of amorphous BaO–Fe2O3–B2O3 glasses prepared using 1 mol % TiO2, Infrared Phys., 1989, vol. 29, no. 5, pp. 895–902.

    Article  Google Scholar 

  25. Ardelean, I. and Pascuta, P., Comparative vibrational study of xFe2O3(1–x)[3B2O3 · MO] (MO → CaO or CaF2) glass systems, Mater. Lett., 2004, vol. 58, pp. 3499–3502.

    Article  Google Scholar 

  26. Yiannopoulos, Y.D., Chryssikos, G.D., and Kamitsos, E.I., Structure and properties of alkaline earth borate glasses, Phys. Chem. Glasses, 2001, vol. 42, no. 3, pp. 164–172.

    Google Scholar 

  27. Osipov, A.A. and Osipova, L.M., Structure of glasses and melts in the Na2O–B2O3 system from high-temperature Raman spectroscopic data: II. Superstructural units in melts, Glass Phys. Chem., 2009, vol. 35, no. 2, pp. 132–140.

    Article  Google Scholar 

  28. Osipov, A.A., Osipova, L.M., and Bykov, V.N., Spektroskopiya i struktura shchelochnoboratnykh stekol i rasplavov (Spectroscopy and Structure of Alkali-Borate Glasses and Melts), Yekaterinburg, Miass: UrO RAN, 2009.

    Google Scholar 

  29. Osipov, A.A. and Osipova, L.M., Structure of lithium borate glasses and melts: investigation by high temperature Raman spectroscopy, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2009, vol. 50, no. 6, pp. 343–354.

    Google Scholar 

  30. Osipov, A.A. and Osipova, L.M., Raman scattering study of barium borate glasses and melts, Phys. Chem. Solids, 2013, vol. 74, pp. 971–978.

    Article  Google Scholar 

  31. Osipov, A.A. and Osipova, L.M., Structural specificity of high alkali lithium and sodium borate melts: a high temperature Raman study, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, 2013, vol. 54, no. 1, pp. 1–14.

    Google Scholar 

  32. Syono, Y., Ito, A., and Horie, O., Mössbauer study on the structural and magnetic properties of amorphous BaO–Fe2O3–B2O3 system, J. Phys. Soc. Jpn., 1979, vol. 46, no. 3, pp. 793–801.

    Article  Google Scholar 

  33. Yuanfu, H., Rongchuan, L., and Shuxin, W., A Mössbauer investigation of non-bridging oxygens in Na2O–Fe2O3–B2O3 glasses, Hyperfine Interact., 1986, vol. 27, pp. 285–288.

    Article  Google Scholar 

  34. Nagata, K. and Hayashi, M., Structure relaxation of silicate melts containing iron oxide, J. Non-Cryst. Solids, 2001, vol. 282, pp. 1–6.

    Article  Google Scholar 

  35. Syono, Y. and Ito, A., Structural and magnetic properties of amorphous BaO-Fe2O3-B2O3 system, J. Phys., 1979, vol. 40, C2-115–C2-117.

  36. Sanchez, I.P. and Friedt, J.M., Magnetic properties of the ternary oxide glasses, Li2O–B2O3–Fe2O3 from 57Fe Mössbauer spectroscopy, J. Phys., 1982, vol. 43, pp. 1707–1716.

    Google Scholar 

  37. Music, S., Furic, K., Bajs, Z., and Mohacek, V., Spectroscopic characterization of alkali borosilicate glasses containing iron ions, J. Mater. Sci., 1992, vol. 27, pp. 5269–5275.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. A. Osipov.

Additional information

Original Russian Text © A.A. Osipov, R.T. Zainullina, L.M. Osipova, M.V. Shtenberg, P.V. Khvorov, S.M. Lebedeva, 2018, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Osipov, A.A., Zainullina, R.T., Osipova, L.M. et al. Study of the Structure of Iron-Containing Zinc Borate Glass. Glass Phys Chem 44, 211–221 (2018). https://doi.org/10.1134/S1087659618030112

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659618030112

Keywords

Navigation