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Test case for perspectivism: incompatible models in quantum chemistry

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Abstract

The incompatibility within the context of modeling cannot be established simpliciter. The fact that modeling is understood as an activity whose representational power can only be partially established, may minimize the supposed existence of incompatible models. Indeed, it is argued from perspectivism that incompatibility can be dissolved, meaning that it becomes trivial or simply false due to the inherently pragmatic and partial nature of the act of representation and modeling. From this perspective, incompatibility can only be a consequence of a misunderstanding of the very nature of modeling and representation In this sense, in order to tackle this strategy at its root from perspectivism, we will first need to outline the maximal perspectivism thesis, attempting to identify the possible escape routes that perspectivism could find in order to explain incompatibility as an illusory incompatibility. Then, we will analyze Valence Bond Model and Molecular Model of covalent bonds, and we will conclude that the dissuasive strategies used to minimize and/or disregard incompatibility prove to be fruitless.

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Notes

  1. Surely, this seems to be almost a political and philosophical cleavage – based on community rules of play, and this could imply that a scientific community can change. What is clear is that the ties that identify a scientific community depend on these aspects. For the arguments presented in this work, what is relevant is to recognize that there is no single way to configure a scientific community.

  2. We thank the editor for pointing out that the topic of this paper may have an argumentative confluence with the article in this volume “Why do prima facie intuitive theories work in organic chemistry” written by Hirofumi Ochiai.

References

  • Bailer-Jones, D.M.: When scientific models represent. Int. Stud. Philos. Sci. 17(1), 59–74 (2003)

    Article  Google Scholar 

  • da Costa, N., French, S.: Models, theories, and structures: thirty years on. Philos. Sci. 67, 116–127 (2000)

    Article  Google Scholar 

  • Chakravartty, A.: Perspectivism, inconsistent models, and contrastive explanation. Stud. Hist. Philos. Sci. 41, 405–412 (2010)

    Article  Google Scholar 

  • Frigg, R.: Models and Theories. Routledge, New York (2022)

    Book  Google Scholar 

  • Frisch, M.: Models and scientific representation or: who is afraid of inconsistency? Synthese 191, 3027–3040 (2014)

    Article  Google Scholar 

  • Gavroglu, K. y Simoes, A. The Americans, the Germans, and the beginnings of quantum chemistry: The confluence of diverging traditions, Historical Stud Phys. Biol. Sci. 25 (1), 47–110 (2012a)

    Article  Google Scholar 

  • Gavroglu, K.y Simoes, A.: Neither Physics Nor Chemistry. The MIT Press, Boston (2012b)

    Google Scholar 

  • Giere, R.: Scientific Perspectivism. University of Chicago Press, Chicago (2006a)

    Book  Google Scholar 

  • Giere, R.: Perspectival pluralism, In: Waters C.K. (ed.), Scientific Pluralism. London: University of Minnesota Press, pp. 26–41 (2006b)

  • Heitler, W., London, F.: Wechselwirkung neutraler Atome und homöopolare Bindung nach der Quantenmechanik. Z. Phys. 44, 455–472 (1927)

    Article  Google Scholar 

  • Hendry, R.F.: Two conceptions of the chemical bond. Philosophy of Science 75, 909–920 (2006)

    Article  Google Scholar 

  • Hettema, H.: The union of chemistry and physics. Springer (2017)

    Book  Google Scholar 

  • Hoffmann, R., Shaik, S., Hiberty, P.: A conversation on VB vs MO theory: A never-ending rivalry? Acc. Chem. Res. 36(10), 750–756 (2003)

    Article  Google Scholar 

  • Lennard-Jones, J.E.: The electronic structure of some diatomic molecules. Trans. Faraday Soc. 25, 668–686 (1929)

    Article  Google Scholar 

  • Massimi, M.: Perspectival Realism. Oxford University Press, Oxford (2022)

    Book  Google Scholar 

  • McWeeny, R.: Coulson’s Valence. Oxford University Press, Oxford/New York/Toronto (1979)

    Google Scholar 

  • Morrison, M.: One phenomenon, many models: inconsistency and complementarity. Stud. Hist. Philos. Sci. 42, 342–351 (2011)

    Article  Google Scholar 

  • Morrison, M.: Reconstructing Reality: Models, Mathematics, and Simulations. Oxford University Press, New York (2015)

    Book  Google Scholar 

  • Mulliken, R.: Electronic structures of polyatomic molecules and valence. Phys. Rev. 40, 55–62 (1932)

    Article  Google Scholar 

  • Mulliken, R.: Nobel lecture. Nobel prize.org. Nobel prize outreach AB (2024). https://www.nobelprize.org/prizes/chemistry/1966/mulliken/lecture/

  • Mulliken, R.:. Life of a Scientist—An Autobiographical Account of the Development of Molecular Orbital Theory with an Introductory Memoir by Friedrich Hund B.J. Ransil (ed.). Springer-Verlag, Berlin (1989)

  • Pauling, L.: Letter Pauling to Noyes, April 25, PP, Box 71, Noyes A. A. Correspondence, pp. 1921–1938 (1926)

  • Pauling, L.: The nature of the chemical bond. IV. The energy of single bonds and the relative electronegativity of atoms. J. Am. Chem. Soc. 54(9), 3570–3582 (1932)

    Article  Google Scholar 

  • Pauling, L.: Nobel Lecture. Nobel Prize.org. Nobel Prize Outreach AB (2024). https://www.nobelprize.org/prizes/chemistry/1954/pauling/lecture/

  • Rueger, A.: Perspectival models and theory unification. Br. J. Philos. Sci. 56, 579–594 (2005)

    Article  Google Scholar 

  • Saatsi, J.: Inconsistency and scientific realism. Synthese 191(13), 2941–2955 (2014)

    Article  Google Scholar 

  • Seifert, V. (2022). “The chemical bond is a real pattern”, Philosophy of Science, pp. 1–47 (forthcoming). Recuperado de http://philsci-archive.pitt.edu/20333/

  • Shaik, S., Hiberty, P.C.: Myth and reality in the attitude toward valence-bond (VB) theory: are its −failures× real? Helvetica Chimica Actal 86, 1063–1084 (2003)

    Article  Google Scholar 

  • Shaik, S., Danovich, D., Hiberty, P.C.: Valence bond theory—its birth, struggles with molecular orbital theory, its present state and future prospects. Molecules 26, 1624 (2021)

    Article  Google Scholar 

  • Slater, J.C.: Molecular energy levels and valence bonds. Phys. Rev. 38, 1109–1144 (1931)

    Article  Google Scholar 

  • Teller, P.: Twilight of the perfect model model. Erkenntnis 55, 393–415 (2001)

    Article  Google Scholar 

  • Teller, P.: Two models of truth. Analysis 71(3), 465–472 (2011)

    Article  Google Scholar 

  • Van Vleck, J.H., Sherman, A.: The quantum theory of valence. Rev. Mod. Phys. 7(3), 167–228 (1935)

    Article  Google Scholar 

  • Weisberg, M.: Challenges to the structural conception of chemical bonding. Proceedings of the 2006 Bienn. Meeting Philos. Sci. Assoc. Part II: Symp. 75 (5), 932-946 (2008)

  • Woody A.I.: Concept amalgamation and representation in quantum chemistry. In: Woody A.I., Hendry R.F., Needham P. (eds.), A Handbook of Philosophy of Science, vol. 6: Philosophy of Chemistry. Elsevier, Oxford, pp. 427–466 (2012)

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Correspondence to Hernan Lucas Accorinti.

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Accorinti, H.L., González, J.C.M. Test case for perspectivism: incompatible models in quantum chemistry. Found Chem (2024). https://doi.org/10.1007/s10698-024-09502-4

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