Abstract
Natural materials like wood are increasingly used in the construction industry, making the understanding of their ignition and burning behaviour in fires crucial. The state of the art of wood flammability is based mostly on studies at constant heating. However, accidental fires are better represented by transient heating. Here, we study the piloted ignition and burning of medium density fibreboard (MDF) under transient irradiation. Experiments are conducted in a Fire Propagation Apparatus under parabolic heat flux pulses with peak irradiation ranging from 30 to 40 kW/m2 and time-to-peak irradiation from 160 to 480 s. The experimental results reveal that the critical conditions for ignition of fibreboard vary over wide ranges: mass flux between 4.9 to 7.4 g/m2-s, surface temperature between 276 to 298°C, and heat flux between 29 to 40 kW/m2. Flameout conditions are studied as well, with observations of when it leads either to extinction or to smouldering combustion. We explored the experiments further with a one-dimensional pyrolysis model in Gpyro and show that predictions are accurate. Assuming a non-uniform density profile (a realistic assumption) improves the predictions in comparison to a uniform density profile by increasing the mass loss rate by 12%, decreasing the temperatures by 45%, and increasing the ignition time by 20 s. These results further support previous findings that a single critical condition for igntion or flameout established under constant irradiation does not hold under transient irradiation which indicates that ignition and extinction theories need improvements.
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1 Introduction
Fiberboard is an engineered wood product that is widely used in the built environment, furniture applications, and as insulation material [1]. It is manufactured by binding wood fibers with wax or resin under high temperature and pressure conditions [2]. Its thermal properties and fire behavior differ from the ones of natural wood and timber, which warrants the separate investigation of fiberboard. Accidental fires are a major risk for all natural materials making it essential to have a good understanding of their behaviour in a fire.
The ignition and burning of wood has been studied previously both experimentally and numerically. Emmons and Atreya [3] were the first to collect and summarize previous works on ignition in an attempt to move the focus away from empirical correlations and into understanding the physical processes that occur when wood is exposed to fire. That work was later extend to study the flame spread over wood [4]. Atreya and Abu-Zaid [5] studied experimentally the effect of environmental variables on the piloted ignition of wood. They found that ignition time is proportional to the moisture content and air velocity, and inversely proportional to irradiation and oxygen concentration. Only at low irradiation, does moisture content not influence piloted ignition. Boonmee and Quintiere studied the smouldering ignition of wood [6, 7] in a cone heater and found that smouldering ignition occurs at lower heat fluxes than flaming ignition. Numerical models include Spearpoint and Quintiere’ [8] as well as Park et al. [9] who developed one-dimensional models of smouldering and pyrolysis of wood respectively. The former focused on the burning rate and found that it is influenced by the species of wood, while the latter looked at kinetics and proposed a chemical reaction scheme that is able to predict the experimental measurements. Recently, Richter et al. [10] showed that the variability in the burning rate of wood stems from the natural variation in the material properties rather than the chemical composition of wood. In other words, previous studies have largely focused on studying ignition to identify a single ignition criteria (temperature, mass loss rate, or heat flux). The extinction of wood has been treated in a similar manner to identify either a critical heat flux [11] or a critical mass loss rate [12].
The behaviour of fibreboard has been less studied than natural wood. Wasan et al. [13, 14] reported temperature profiles and mass loss rate of medium density fiberboard (MDF) of different moisture contents. They confirmed for fibreboard that moisture delays ignition as previously found for wood. Li and co-workers have a number of publications dealing with the thermo-physical and kinetic parameters of MDF. In [15], they measured the specific heat capacity, thermal conductivity and density of MDF and its char, while in [16], the kinetic parameters and heat of pyrolysis were investigated using TGA and DSC experiments. The kinetic scheme was optimized via a genetic algorithm in [17] to obtain a set of kinetic parameters, and the flame irradiation was measured in [18]. Huang et al. [19] numerically investigated the influence of kinetic scheme complexity, shrinkage, transient flame irradiation and vertical density profile on mass loss rate. Zhao et al. [20] combined numerical and experimental results to suggest the need to account for in-depth absorption in the modelling of the pyrolysis of MDF, which is in contrast to previous experimental measurements for wood that show the insignificance of in-depth absorption [21]. Further work is required on this topic; however, the present authors consider the experimental work of Girods et al. [21] as compelling evidence for the lack of influence of in-depth radiation on the mass loss rate of wood and fibreboard.
All previous studies used a constant irradiation boundary condition for simplicity. While this simplicity is convenient, its case is singular and does not reflect a scenario of an accidental fire. Transient irradiation is a more comprehensive and realistic case for accidental fire, as nonlinear heat transfer effects challenge the general validity of findings and criteria from studies under constant irradiation. In other words, transient irradiation is a generalised version of constant irradiation, making it essential to study ignition under both constant and transient irradiation. Currently, there is only one study on fibreboard under transient irradiation [22], and even for wood there are only two [23, 24]. Agarwal et al. [22] used transient irradiation in different forms (constant irradiation, step-change in irradiation, linearly increasing irradiation) to propose a set of material and kinetic properties for fibreboard obtained through inverse modelling, but did not study the effect of these conditions on ignition or extinction. A few works [25,25,26,27,28,29] have investigated synthetic polymers under transient conditions and the applicability of ignition criteria to them. They generally disagree on the outcome with some favouring the applicability of a single ignition criteria (e.g., [25]) while others favour multiple ignition criteria (e.g., [29]).
Here we aim to investigate the effect of density on the ignition behaviour of MDF under transient irradiation at two moisture contents and test the applicability of a single ignition criteria to our study. There is growing evidence of the importance of the density profile in MDF [13,14,15,16,17,19, 22] but its significance remains unknown. Furthermore, it has not been explored for transient irradiation. At the same time, several studies (e.g., [4, 5, 30] have shown the influence of moisture content on ignition under constant irradiation, and we will test computationally here if our findings hold across different moisture contents. In other words, This paper will show whether the theoretical framework of natural wood also holds for fibreboard. To this end, we will use a model previously described and validated in a work-in-progress publication [31] and apply it to unravel the effect of density on ignition.
2 Experimental Methods
The experiments used in this work were conducted in the FM Global Fire Propagation Apparatus (FPA). These experiments were previously described in [31]. 18-mm thick MDF samples were placed onto aluminium plates of 25 mm thickness for well-defined heat losses [32]. The back-side of the aluminium plate and the sides of the sample were covered with Cotronics insulation to minimize the lateral heat losses. The surface temperature was read using an infrared pyrometer and the mass loss was recorded using a load cell. Details regarding the pyrometer measurements and their validation can be found elsewhere [33, 34]. A wireless thermocouple was inserted in the aluminium plate to measure its temperature and determine a heat loss boundary condition [32]. The use of a wireless thermocouple is novel and allows for the simultaneous measurement of mass loss (unachievable with wired thermocouples) and temperature. The samples had a measured bulk density of 605 kg/m3 and a moisture content of 7%. This moisture content was achieved by drying the samples and then conditioning them for 24 h at 50% RH, which yields an estimated moisture content of 6% to 7% as described in [35]. An ethylene–air pilot was placed 10 mm above the sample surface and 10 mm away from the perimeter of the specimen. Each experiment was repeated three times.
Parabolic irradiation curves imitate both the growth and the decay of irradiation in a fire. Seven different parabolas are used, as shown in Fig. 1, with the addition of a constant irradiation scenario of 20 kW/m2, which was carried out to validate the setup and to provide a link to literature. The curves were verified experimentally in [31]. The two varying parameters of the parabolic curves are the peak irradiation and the time to reach this peak. Four times-to-peak were used in the investigation, ranging from 160 s to 480 s and the peak irradiations are 30 kW/m2, 35 kW/m2 and 40 kW/m2. These curves are chosen to represent a wide range of heating scenarios from slow to fast heating and from low to high intensity heating. The peak value of each irradiation curve exceeds that of the critical irradiation for smouldering ignition (10 kW/m2) [7]. Details about the peak irradiation and time to peak, which characterize the parabolas, are summarized in Table S1 of the Supplementary Material. Time to ignition was observed visually and it varies from 161 s in Scenario 4 s to 408 s in Scenario 0 (constant irradiation), with an error of roughly 1 s based on previous in-house experience. As this error is below 1%, no error bars for ignition and flame-out time are given in the graphs. The errors in the experimental measurement are estimated to be around 5 K for the temperatures [33] and an error of 1 g/m2-s in the mass loss rate based on in-house experiments with the same experimental set-up which is close to the errors calculated by [36].
3 Computational Model
We previously described and preliminarily validated the computational model in [31] and details for the validation can be found there.The setup and sample were modelled using the open-source pyrolysis code Gpyro [37]. The governing equations are listed as follows: condensed-phase mass conservation (Eq. 1), species conservation (Eq. 2) and the energy equation (Eq. 3). Thermal equilibrium between the condensed-phase and the gas-phase is assumed. The shrinkage of the sample was taken into account following [19], with further information therein and the validation of the shrinkage formulation found in [37]. As shown in the literature [21, 34, 38], in-depth radiation is not important for wood and, therefore, in-depth radiation was not taken into account. The reaction rate is expressed by the Arrhenius equation (Eq. 4).
were \(\rho\) is the density, t is time, and \({\dot{\omega }}'''_{fg}\) is rate of formation of gases. The overbar represents the respective mass or volume avarage of quantity, for details see [37].
where \(Y_i\) is the mass fraction of species i, and \({\dot{\omega }}'''_{di}\) the destruction rate of species i.
where h is the enthalpy, z the spatial dimension (depth), k the thermal conductivity, T the temperature and \(\varDelta H_s\) is the heat of pyrolysis.
where A is the pre-exponential factor, E the activation energy, and R the universal gas constant. Furthermore, the rate of formation of gases is defined as
The domain for the one-dimensional model of the experiments is shown in Fig. 2 and resembles the experiment with a free top surface at \(z=0\), an adiabatic bottom surface at \(z = L\) (Eq. 7), and no heat losses to the sides. The top surface (\(z = 0\)) is exposed to the irradiation and has convective and radiative losses (Eq. 6). The convection coefficient was taken as 20 W/m2-K [24]. Keeping a balance between accuracy and simulation time, the final values of the domain parameters are a cell size of 0.01 mm and a time step of 0.1 s based on the grid independence study of a similar model by [29].
where \(\varepsilon\) is the emissivity, \({\dot{q}}^{''}_e\) the external heat flux, \(h_c\) the convective heat transfer coefficient, \(T_\infty\) the initial temperature and \(\sigma\) the Stefan–Boltzman constant. The external heat flux is temperature dependent as shown in Fig. 1. The emissivity and heat transfer coefficient were assumed constant as the heat transfer coefficient is only expected to vary by 20% and the sensitivity of the char depth predicted by a pyrolysis model to heat transfer coefficient is low [39], the emissivity of char is relatively constant [34], and the emissivity of wood is relatively constant up to around 600 K (prior to ignition) [34].
Atreya [4] showed that finite rate kinetics are required to capture ignition. Following him we estimate the chemical timescale to be larger (58 min) [40] than the largest timescale of the pulse (16 min). The chemical reaction scheme and parameter values were proposed by Li et al. [17] for MDF. A drying step was added here. The values of the drying step parameters were chosen from Lautenberger et al. [41]. Equation 8 only holds for the three organic components of fibreboard (cellulose, hemicellulose, lignin) while we assume that the resin does not undergo drying. The values for the pre-exponential factor, activation energy, heat of pyrolysis, reaction order, and solid yields are summarized in Table 1.
The thermal properties used in the simulations are listed in Table 2 for MDF and Table 3 for the aluminium block [42]. The bulk density of MDF was measured prior to the experiment. All other parameters were taken from the literature. No parameter fittings were used. After ignition, a constant radiative flux of 30 kW/m2 was applied to represent the flame irradiation following the work of Huang et al. [19].
As mentioned previously, MDF does not have a homogeneous density profile because of the pressing process through which it is obtained. Therefore, a non-uniform density (NUD) profile was calculated using Eq. 13, taken from Agarwal et al. [22] (Fig. 3).
where \({\overline{\rho }}\) is the bulk (i.e., mean) density (605 kg/m\(^3\) in this case), and \(\xi\) is the ratio of the maximum density (occurring at the surface) to the minimum density (occurring at \(z=\frac{L_0}{2}\)) and has a value of \(\xi =1.61\) [22]. \(L_0\) is the fibreboard’s thickness (i.e. 18 mm)
The density of char was assumed to be uniform and independent of temperature based on the results in [18]. A sensitivity analysis was run in order to find the appropriate discretization of the density profile—as Gpyro required discretization of the curve—with results discussed in Sect. 4 below. Thus going from coarse to fine, we implemented four levels of discretization (Fig. 3): (1) 3 layers of 9 mm, (2) 6 layers of 3 mm, (3) 9 layers of 2 mm, and (4) 18 layers of 1 mm.
4 Results and Discussion
4.1 Experimental results for the Ignition and Extinction of MDF
This section considers pilot ignition and flameout as a function of the irradiation curve, and suggests that ignition criteria under transient irradiation are similar to those under constant irradiation. Figure 4 summarizes the values of mass loss rate (MLR) and surface temperature at ignition for all 8 scenarios. In the experiments, MLR at ignition ranges between 5 g/m2-s and 8 g/m2-s. The MLR is higher than the literature values of similar materials, which are around 3.4 g/m2-s for plywood [43] and 2 g/m2-s for poplar [44] under constant irradiation. Surface temperatures at ignition are close to 300°C for the majority of cases, with the exception being the parabolic flux with a time to peak of 260 s and a peak irradiation of 30 kW/m2. The literature values for ignition temperatures for wood are between 300°C and 350°C [45] under constant irradiation. This comparison would suggest that a critical mass loss rate is a sufficient ignition criteria for MDF. However, in Scenario 3, see Fig. 4, the mass loss rate exceeds the critical mass loss rate but the sample did not ignite at the 200 s mark. This experiment supports previous studies that found that one ignition criteria is insufficient to predict the ignition of wood [24] and PMMA [29]. The applicability of a multi-threshold for ignition could not be tested further in this study, as ignition occurred in all experiments.
It is interesting to see when ignition and flameout occurred under different parabolic irradiations, as shown in Fig. 5. For comparison, the time to ignition for constant irradiation is 408 s and flameout occured after 720 s. In the cases with a lowest time to peak heat flux (160 s), flameout coincides with the end of the parabolic flux, which shows that the flame is not able to sustain itself without additional heating. For the cases with times-to-peak of 260 s to 320 s, ignition occurs before the peak heat flux is reached and flameout happens before the parabolic flux ends. For the scenarios with time to peak heat flux of 480 s to peak, ignition occurs 120 s before the peak and lasts for 60 s. All cases, therefore, show that subjecting MDF to parabolic heating scenarios does not cause sustained flaming after heating is removed or insufficient heating is applied, as has previously been shown for wood [11]. At flameout, the conditions varied widely with mass loss rates between 1.4 g/m2-s and 17 g/m2-s, heat fluxes between 0 kW/m2 and 29 kW/m2, and surface temperatures between 520°C and 670°C (see Table S2 in the Supplementary Material). We observed three different flameout conditions, shown in Fig. 6: extinction, transition to unsustained smouldering, and transition to sustained smouldering. The first (extinction) is when flameout occurs close to the removal of the heat flux (Scenarios 4 and 6) and the mass loss rate rapidly decreases once flaming ceases reaching a value of zero when the heat flux is removed. The second (flaming to unsustained smouldering) is when flameout occurs earlier during the experiment. The sample then transitions from flaming to unsustained smouldering where the burning rate stays relatively constant until the heat flux is removed and the mass loss rate becomes zero (Scenario 3). The third (flaming to sustained smouldering) similarly occurs when flameout takes place early in the experiments. The sample transitions to sustained smouldering where the burning rate gradually decreases, but burning continues after the external heat flux has ceased (Scenarios 2, 3, 5, and 7). The transition of flaming to smouldering and the subsequent continuation of smouldering presents a significant risk if MDF is used in buildings as it offers the potential for re-ignition of a flaming fire.
4.2 Influence of Non-uniform Density at Two Different Moisture Contents
The significant influence of drying on the modeled temperature and MLR profiles using a uniform density distribution is shown in Fig. 7 for both constant and transient irradiation. Additional scenarios are shown in the Supplementary Material to illustrate different behaviors when varying time to peak irradiation, magnitude of peak irradiation, and discretization. For the constant irradiation scenario, the drying step reduces the predicted surface temperature by up to 56°C. For the transient scenarios drying only reduces the predicted surface temperature by a maximum of 29°C. In all cases, the model over-predicts the initial increase in surface temperature and under-predicts the peak immediately after ignition. Furthermore, the average error between experimental and predicted surface temperature is small for constant irradiation (8%), but large (44%) for transient irradiation. The reason for these discrepancies is likely the lack of oxidative reactions in the chemical kinetics, making the model unable to capture the smoldering behaviour of fibreboard [9].
Adding drying allows for better capture of the initial MLR behavior (\(\hbox {t} \le 410\) s in Fig. 7b and \(t \le 280\) s in Fig. 7d) during which moisture evaporates. Drying decreases the peak MLR for constant irradiation (16% in Fig. 7b as well as Figs. S2 and S3) and increases it for transient irradiation (10% in Fig. 7d). In spite of this, the model underpredicts the peak MLR by 14 g/m2-s compared to the experimental measurement. Likely, the quantitative disagreement in this paper stems from an insufficient representation of the gas-phase combustion, as the model predicts the mass loss rate prior to ignition and after flameout with an average error of roughly 1 g/m2-s. Here, we simplified the heat transfer from the gas-phase combustion to the solid as a constant heat flux, while in reality it will vary depending on the flame and its position. As a result, we can consider drying to be an important mechanism to model when assuming a homogeneous density throughout the sample as it changes temperatures and mass loss rates by roughly 10% to 15% as argued above.
Addition of a drying step in the model lowered the predicted in-depth temperatures through the solid, as the additional drying front consumes heat (Fig. 7a, c). A lower temperature results in delayed ignition. These results, however, only hold for a uniform density profile in the solid. Once we simulate one of the four discretized cases (3–18 layers) the density at the surface of the solid rises to 800 kg/m2. The evaporation of water at a moisture content of 7% no longer lowers the temperature significantly (Fig. S1). Only deeper into the solid, where the density is low, is the temperature profile affected by the moisture content (Fig. 8). In short, the significance of moisture content reduces as the density increases. The density rises significantly near the exposed surface when accounting for the density profile of fibreboard. The degradation of fibreboard near the exposed surface controls ignition. It follows that the influence of moisture content reduces when accounting for the density profile of fibreboard to the point that the influence of moisture content can be neglected (Fig. S1 in the Supplementary Material).
The non-uniform density profile has negligible influence on the surface temperatures (Fig. 8), as the error of 45% (graph not shown) between the predictions with uniform and non-uniform density stems solely from the difference in ignition times (20 s). Away from the ignition zone, the error is less than 10%. It does have a significant effect on the peak MLR. Discretizing into 9 layers of 2 mm or 18 layers of 1 mm provides the highest increase in peak MLR, as the highest density, which is in the exterior, is captured better (Fig. 9 and Fig. S4). The mass loss rate then increases by 12% under constant irradiation when introducing 18 layers compared to a uniform density. However, there is only 0.33 g/m2-s difference between 9 and 18 layers. Nine layers is therefore considered a good representation of the density profile of MDF. The increase in mass loss rate by 9% for 9 layers and 12% for 18 layers is in good agreement with Zeinali et al. [46]. In an independent study, published during the review of this paper, they found that simulations of the heat release rate of MDF in a corner test increases by 20% when taking into account the non-uniform density. The mass loss rate and heat release rate are related by the heat of combustion, which can be considered constant, meaning that these two studies agree well. This holds in particular if one considers the different scales. These findings also agree with Agarwal et al. [22] and Huang et al. [19], who have previously stated the importance of the density profile in replicating mass loss rate curves under constant irradiation. Our analysis proves their hypothesis, expanding it to transient irradiation, and adds to their findings.
5 Conclusion
This work studied the pilot ignition and extinction of fibreboard under transient irradiation, both experimentally and computationally. Experimentally, we found the mass loss rates and surface temperature of fibreboard under transient irradiation at ignition to be of the same order of magnitude as under constant irradiation. This suggests a similar ignition behaviour between fibreboard and wood. At flameout, however, MDF was shown to either undergo either extinction, transition to unsustained smouldering, or transition to sustained smouldering. These three different mechanisms lead to large variations (one order of magnitude) in the reported mass loss rate, and a variation of 150°C in surface temperature at flameout.
Computationally, this work tested the significance of the density profile on ignition. The model uses literature and measured values for chemical and thermal parameters. We compared the predictions using a uniform density to using non-uniform density profiles. Firstly, our results showed that the influence of moisture content changes with density profile, as the value of moisture content influenced the predictions when employing a uniform density profile but less when employing non-uniform profile. From these results, we conclude that the density profile is a more significant variable than moisture content in engineered timber. Secondly, we found that the temperature profile is unaffected by the density profile away from the ignition time with an error of less than 10%. Thirdly, we found that the mass loss rate changes by up to 12% when considering a non-uniform density profile. Therefore, the predicted heat release rate and ignition behaviour based on the critical mass loss rate is affected by the density. We conclude that the non-uniform density profile of fibreboard is important to account in the modelling of ignition.
Overall, this study contributes to the literature by showing the significance of the density profile in modelling the fire behaviour of engineered wood, that the complexity of wood ignition and extinction is unlikely to be captured by a single criteria, and that flameout is a complex mechanism that can lead to either extinction or smouldering combustion. This study is therefore a step to unravel the ignition and burning behaviour of fibreboard.
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Acknowledgements
The authors thank FM Global and EPSRC (EP/M506345/1) for funding this project, and Dr. Gaurav Agarwal for his help in conducting the experiments at FM Global. Furthermore, we would like to thank Han Yuan (Imperial College London) and Prof. Nieves Fernandez-Anez (Western Norway University of Applied Science) for their helpful comments.
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Vermesi, I., Richter, F., Chaos, M. et al. Ignition and Burning of Fibreboard Exposed to Transient Irradiation. Fire Technol 57, 1095–1113 (2021). https://doi.org/10.1007/s10694-020-01017-6
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DOI: https://doi.org/10.1007/s10694-020-01017-6