Abstract
A local-scale spatially refined multimedia fate model (LSRMFM) was developed to evaluate in detail the multimedia transport of organic compounds at a spatial level. The model was derived using a combination of an advection–dispersion–reaction partial differential equation, a steady-state multimedia fugacity model, and a geographical information system. The model was applied to predicting four major volatile organic compounds that are produced as emissions (benzene, toluene, xylene, and styrene) in an urban and industrial area (the 50 × 50-km area was divided into 0.5 × 0.5-km segments) in Korea. To test the accuracy of the model, the LSRMFM was used to predict the extent of dispersion and the data compared with actual measured concentrations and the results of a generic multimedia fate model (GMFM). The results indicated that the method developed herein is appropriate for predicting long-term multimedia pollution. However, the comparison study also illustrated that the developed model has some limitations (e.g., steady-state assumption) in terms of explaining all the observed concentrations, and additional verification and study (e.g., validation using a large observed data set, integration with a more accurate runoff model) would be desirable. In comparing LSRMFM and GMFM, discrepancies between the LSRMFM and GMFM outputs were found, as the result of geographical effects, even though the environmental parameters were identical. The geographical variation for LSRMFM output indicated the existence of considerable local human and ecological risks, whereas the GMFM output indicated less average risk. These results demonstrate that the model has the potential for improving the management of pollutant levels under these refined spatial conditions.
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References
Mackay, D. (1979). Finding fugacity feasible. Environmental Science & Technology, 13(10), 1219–1223.
Mackay, D., & Diamond, M. (1989). Application of the QWASI (quantitative water air sediment interaction) fugacity model to the dynamics of organic and inorganic chemicals in lakes. Chemosphere, 18(7/8), 1343–1365.
Mackay, D., & Paterson. (1991). Evaluating the multimedia fate of organic chemicals: A level III fugacity model. Environmental Science & Technology, 25(3), 427–436.
van de Meent, D. (1993). SimpleBOX: A generic multi-media fate evaluation model. RIVM report no. 6727200001. The Netherlands: Bilthoven.
Devillers, J., & Bintein, S. (1995). CHEMFRANCE: A regional level III fugacity model applied to France. Chemosphere, 30(3), 457–476.
Mackay, D., Di Guardo, A., Paterson, S., & Cowan, C. E. (1996). Evaluating the environmental fate of a variety of types of chemicals using the EQC model. Environmental Toxicology and Chemistry, 15(9), 1627–1637.
Fenner, K., Scheringer, M., & Hungerbuhler, K. (2000). Persistence of parent compounds and transformation products in a level IV multimedia model. Environmental Science & Technology, 34(17), 3809–3817.
Cousins, I. T., & Mackay, D. (2001). Strategies for including vegetation compartments in multimedia models. Chemosphere, 44(4), 643–654.
Tao, S., Yang, Y., Cao, H. Y., Liu, W. X., Coveney, R. M., Xu, F. L., et al. (2006). Modeling the dynamic changes in concentrations of g-hexachlorocyclohexane (g-HCH) in Tianjin region from 1953 to 2020. Environmental Pollution, 139(1), 183–193.
Priemer, D. A., & Diamond, M. L. (2002). Application of the multimedia urban model to compare the fate of SOCs in an urban and forested watershed. Environmental Science & Technology, 36(5), 1004–1013.
Hollander, A., Baijens, I., Ragas, A., Huijbregts, M., & van de Meent, D. (2007). Validation of predicted exponential concentration profiles of chemicals in soils. Environmental Pollution, 147(3), 757–763.
Suzuki, N., Murasawa, K., Sakurai, T., Nansai, K., Matsuhashi, K., Moriguchi, Y., et al. (2004). Geo-referenced multimedia environmental fate model (G-CIEMS): Model formulation and comparison to the generic model and monitoring approaches. Environmental Science & Technology, 38(21), 5682–5693.
Wania, F. (1996). Spatial variability in compartmental fate modelling. linking fugacity models and GIS. Environmental Science and Pollution Research, 3(1), 39–46.
Woodfine, D., Macleod, M., & Mackay, D. (2002). A regionally segmented national scale multimedia contaminant fate model for Canada with GIS data input and display. Environmental Pollution, 119(3), 341–355.
Zhang, Q., Crittenden, J. C., Sonnard, D., & Mihelcic, J. R. (2003). Development and evaluation of an environmental multimedia fate model CHEMGL for the great lakes region. Chemosphere, 50(10), 1377–1397.
Prevedouros, K., MacLeod, M., Jones, K. C., & Sweetman, A. J. (2004). Modelling the fate of persistent organic pollutants in Europe: Parameterisation of a gridded distribution model. Environmental Pollution, 128(1), 251–261.
Luo, Y., Gao, Q., & Yang, X. (2007). Dynamic modeling of chemical fate and transport in multimedia environments at watershed scale—I: Theoretical considerations and model implementation. Journal of Environmental Management, 83(1), 44–55.
Fann, N., Hubbell, B. (2008) Performing local-scale health impact assessments with near-field air quality modeling. 7th annual CMAS conference, Chapel Hill, NC, October 6–8
Chapra, S. C. (1997). Surface water-quality modeling (2nd ed.). New York: McGraw-Hill.
Merks, R. M. H., Hoekstra, A. G., & Sloot, P. M. A. (2002). The moment propagation method for advection-diffusion in the lattice Boltzmann method: Validation and Péclet number limits. Journal of Computational Physics, 183(2), 563–576.
Mackay, D. (2001). Multimedia environmental fate model: The fugacity approach (2nd ed.). Boca Raton: Lewis.
Trapp, S., & Matthies, M. (1998). Chemodynamics and environmental modeling: An introduction (Firstth ed.). Berlin: Springer.
Kim, J. H., Kim, M.-S., Kwak, B. K., Yoo, H. S., Shin, C. B., & Yi, J. (2006). Development of national scale environmental & geographical information system for supporting exposure assessment. Journal of Korean Society of Environmental Engineering, 28(10), 1082–1089.
Kim, J. H., Kwak, B. K., Shin, C. B., Park, H.-S., Choi, K., Lee, S. M., et al. (2009). Speed-up of the disaggregation of emission inventories and increased resolution of disaggregated maps using landuse data. Korean Journal of Chemical Engineering, 26(6), 1620–1629.
Kim, J. H., Kwak, B. K., Park, H.-S., Kim, N. G., Choi, K., & Yi, J. (2010). A GIS-based national emission inventory of major VOCs and risk assessment modeling: Part I—methodology and spatial pattern of emissions. Korean Journal of Chemical Engineering, 27(1), 129–138.
Seinfeld, J. H., & Pandis, S. N. (1998). Atmospheric chemistry and physics. New York: Wiley.
Geyer, W. R., & Signell, R. P. (1992). A reassessment of the role of tidal dispersion in estuaries. Estuaries, 15(2), 97–108.
Jenson, S. K., & Domingue, J. O. (1988). Extracting topographic structure from digital elevation data for geographic information system analysis. Photogrammetric Engineering and Remote Sensing, 54(11), 1593–1600.
Maidment, D. R. (2002). ARC hydro—GIS for water resources (1st ed.). Redlands: ESRI.
Zawar-Reza, P., Kingham, S., & Pearce, J. (2005). Evaluation of a year-ling dispersion modeling of PM10 using the mesoscale model TAPM for Christchurch, New Zealand. The Science of the Total Environment, 349(1–3), 249–259.
McCay, D. P. F., Whittier, N., Ward, M., Santos, C. (2006) Spill hazard evaluation for chemicals shipped in bulk using modeling, Environ. Modelling and Software, 21(2), 156–169.
Huijbregts, M. A. J., Thissen, U., Guinee, Jager, T., Kalf, D., van de Meent, D., et al. (2000). Priority assessment of toxic substances in life cycle assessment. Part I: Calculation of toxicity potentials for 181 substances with the nested multi-media fate, exposure and effects model USES-LCA. Chemosphere, 41(4), 541–573.
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We are grateful to the ECO-Technopia-21 Project of the Ministry of Environment in Korea for financial support.
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Kim, J.H., Kwak, B.K., Shin, C.B. et al. Development of a Local-Scale Spatially Refined Multimedia Fate Model (LSRMFM) for Urban-Scale Risk Assessment: Model Formulation, GIS-Based Preprocessing, and Case Study. Environ Model Assess 16, 265–281 (2011). https://doi.org/10.1007/s10666-011-9250-x
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DOI: https://doi.org/10.1007/s10666-011-9250-x