Abstract
The results of surface snow monitoring in Vecherny Oasis, Thala Hills, East Antarctica, for evaluation of Belarusian Antarctic Station environmental impact are presented. Snow samples from the depth up to 15–20 cm were collected during 4–5th and 7–10th seasonal Belarusian Antarctic expeditions in the period from 2012 to 2018. Chemical-analytical study and determination of Ag, Al, As, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Na, Mg, Mn, Mo, Ni, Pb, Sb, Se, Th, Tl, V, U, and Zn content were performed using ISP-MS method. Altogether 85 snow samples were analyzed. High spatial variability of trace elements content in the surface snow and differences between human impacted and non-impacted areas are shown. The elevated average content of trace elements in surface snow within the human impacted areas in comparison with ice sheet has been revealed. Based on the concentration of elements and EFc, the anthropogenic origin of Sb, Se, As, Cd, Zn, Cr, Cu, Mo, V, and Pb in the surface snow were suggested. Contribution of local sources of trace elements is considered to be more important for Vecherny Oasis than their regional or transboundary transfers. The development of guidelines for unified procedure of snow sampling for the goal of local impact monitoring in Antarctica would be useful for data comparison across Antarctic.
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References
Bargagli, R. (2000). Trace metals in Antarctica related to climate change and increasing human impact. Reviews of Environmental Contamination and Toxicology, 166, 129–173.
Becagli, S., Proposito, M., Benassai, S., Flora, O., Genoni, L., Gragnani, R., Largiuni, O., Pili, S. L., Severi, M., Stenni, B., Traversi, R., Udisti, R., & Frezzotti, M. (2004). Chemical and isotopic snow variability in East Antarctica along the 2001/02 ITASE traverse. Annals of Glaciology, 39, 473–782.
Bertler, N., Mayewski, P. A., Aristarain, A., Barrett, P., Becagli, S., Bernardo, R., Bo, S., Cunde, X., Curran, M., Dahe, Q., Dixon, D., Ferron, F., Fisher, H., Frey, M., Frezzotti, M., Fundel, F., Genthon, C., Gragnani, R., Hamilton, G., Handley, M., Hong, S., Isaksson, E., Kang, J., Ren, J., Kamiyama, K., Kanamori, S., Karkas, E., Karlof, L., Kaspari, S., Kreutz, K., Kurbatov, A., Meyerson, E., Ming, Y., Zhang, M., Motoyama, H., Mulvaney, R., Oerter, H., Osterberg, E., Proposito, M., Pyne, A., Ruth, U., Simoes, J., Smith, B., Sneed, S., Teinilä, K., Traufetter, F., Uditsi, R., Virkkula, A., Watanabe, O., Williamson, B., Winthen, J.-G., Li, Y., Wolff, E. W., Li, Z., & Zielinski, A. (2005). Snow chemistry across Antarctica. Annals of Glaciology, 41, 167–179. https://doi.org/10.3189/172756405781813320.
Boutron, C. F. (1982). Atmospheric trace metals in the snow layers deposited at the South Pole from 1928 to 1977. Atmospheric Environment, 16(10), 2451–2459.
Boutron, C., & Lorius, C. (1975). Trace element content in East Antarctica snow samples (p.164–171). Mode of access: http://hydrologie.org/redbooks/a118/iahs_118_0164.pdf. Accessed 7 Feb 2020.
Boutron, C. F., & Patterson, C. C. (1987). Relative levels of natural and anthropogenic lead in recent Antarctic snow. Journal of Geophysical Research, 92, 8454–8464.
Boutron, C., Leclerc, M., & Risler, N. (1984). Atmospheric trace elements in Antarctic prehistoric ice collected at a coastal ablation area. Atmospheric Environment, 18(9), 1947–1953.
Dick, A. L., & Peel, D. A. (1985). Trace elements in Antarctic air and snowfall. Annals of Glaciology, 7, 12–19.
Dixon, D. A., Mayewski, P. A., Korotkikh, E., Sneed, S. B., Handley, M. J., Introne, D. S., & Scambos, T. A. (2013). Variations in snow and firn chemistry along US ITASE traverses and the effect of surface glazing. The Cryosphere, 7(2), 515–535.
Fortner, S. K. (2008) The geochemistry of glacier snow and melt: The Oregon cascades and the Taylor Valley, Antarctica. Dissertation, The Ohio State University; at: https://www.researchgate.net/publication/267996904. Accessed 5 Feb 2020
Grotti, M., Soggia, F., Ardini, F., & Magi, E. (2011). Major and trace element partitioning between dissolved and particulate phases in Antarctic surface snow. Journal of Environmental Monitoring, 13(9), 2511–2520.
Hong, S., Boutron, C. F., Edwards, R., & Morgan, V. I. (1998). Heavy metals in Antarctic ice from law dome: Initial results. Environmental Research, 78(2), 94–103. https://doi.org/10.1006/enrs.1998.3849.
Hong, S., Lluberas, A., Lee, G., & Park, J. K. (2002). Natural and anthropogenic heavy metal deposition to the snow in King George Island, Antarctic Peninsula. Ocean and Polar Research, 24(3), 279–287. https://doi.org/10.4217/OPR.2002.24.3.279.
Hong, S., Soyol-Erdene, T. O., Hwang, H. J., Hong, S. B., Hur, S. D., & Motoyama, H. (2012). Evidence of global-scale As, Mo, Sb, and Tl atmospheric pollution in the Antarctic snow. Environmental Science & Technology, 46(21), 11550–11557. https://doi.org/10.1021/es303086c.
Ikegawa, M., Kimura, M., Honda, K., Makita, K., Motoyama, H., Fujii, Y., & Itokawa, Y. (1997). Springtime peaks of trace metals in Antarctic snow. Environmental Health Perspectives, 105, 654–659. https://doi.org/10.1289/ehp.97105654.
Ikegawa, M., Kimura, M., Honda, K., Akabane, I., Makita, K., Motoyama, H., Fujii, Y., & Itokawa, Y. (1999). Geographical variations of major and trace elements in East Antarctica. Atmospheric Environment, 33, 1457–1467. https://doi.org/10.1016/S1352-2310(98)00243-X.
Jiang, X. X., Hou, S. G., Li, Y. S., Pang, H. X., Hua, R., Paul, M., Sharon, S., An, C. L., Michael, H., Liu, K., & Zhang, W. B. (2018). Spatial variations of Pb, As, and Cu in surface snow along the transect from the Zhongshan Station to Dome A, East Antarctica[J]. Sciences in Cold and Arid Regions, 10(3), 219–231. https://doi.org/10.3724/SP.J.1226.2018.00219.
Kakareka, S., & Salivonchyk, S. (2020). Assessment of diesel power plants air impacts in Antarctica. Advances in Polar Science, 31(1), 74–87. https://doi.org/10.13679/j.advps.2019.0029.
Kakareka, S., Kukharchyk, T., Loginov, V., & Salivonchyk, S. (2016). Construction and operation of Antarctic research stations. An experience of comprehensive environmental evaluation (278 p). Minsk: StroyMediaProekt.
Kakareka, S., Kukharchyk, T., & Kurman, P. (2019). Major and trace elements content in freshwater lakes of Vecherny Oasis, Enderby Land, East Antarctica. Environmental Pollution, 255, 113126. https://doi.org/10.1016/j.envpol.2019.113126.
Kotlyakov, V. M. (2000). Selected works in six books. Book 1. Glaciology of Antarctica. Monograph, Moscow: Nauka, 433 p. (In Russian).
Laluraj, C. M., Thamban, M., & Satheesan, K. (2013). Dust and associated trace element fluxes in a firn core from the coastal East Antarctica and its linkages with the Southern Hemisphere climate variability over the last 50 yr. Climate of the Past Discussions, 9, 1841–1867, www.clim-past-discuss.net/9/1841/2013/. https://doi.org/10.5194/cpd-9-1841-2013. Accessed 10 Feb 2020
Lee, K., Han, Y., Kang, J-H, Hong, S-B, Hwang, H., Hur, S.D., Frezzotti, M., Narcisi, B. (2017). The characteristics of atmospheric trace elements input into East Antarctica as recorded in GV7 snow pit. Geophysical Research Abstracts, 19, EGU2017–5907. EGU General Assembly 2017.
Liu, Y.-G., Zhang, Y.-H., Li, G.-Q., & Xiao, L. (1988). Analysis of trace elements in the BHQ ice core, Law Dome, Antarctica. Journal of Glaciology, 34(118), 297–300.
Marteel, A., Boutron, C. F., Barbante, C., Gabrielli, P., Cozzi, G., Gaspari, V., Cescon, P., Ferrari, C. P., Dommergue, A., Rosman, K., Hong, S., & Hur, S. D. (2008). Changes in atmospheric heavy metals and metalloids in Dome C (East Antarctica) ice back to 672.0 kyr BP (marine isotopic stages 16.2). Earth and Planetary Science Letters, 272, 579–590. https://doi.org/10.1016/j.epsl.2008.05.021.
McConnell, J., Maselli, O. J., Sigl, M., Vallelonga, P., Neumann, T., Anschutz, H., Bales, R. C., Curran, M. A. J., Das, S. B., Edwards, R., Kipfstuhl, S., Layman, L., & Thomas, E. R. (2014). Antarctic-wide array of high-resolution ice core records reveals pervasive lead pollution began in 1889 and persists today. Scientific Reports, 4, 5848.
Molodyozhnaya Station. (2017). Monthly values of meteorological parameters. Mode of access: http://www.aari.aq/data/data.asp?lang=0&station=4. Accessed 14 Dec 2017.
Pęcherzewski, K. (1987). Air pollution and natural sedimentation from the atmosphere in the region of the Admiralty Bay (South Shetland Islands). Polish Polar Research, 8(2), 145–151.
Petrov, V. N. (1975). Atmospheric nutrition of the ice sheet of Antarctica. Edited by E. S. Korotkevich. Leningrad: Hydrometeoizdat. 150 pp. (In Russian).
Planchon, F. A. M., Boutron, C. F., Barbante, C., Cozzi, G., Gaspari, V., Wolff, E. W., Ferrari, C. P., & Cescon, P. (2002). Changes in heavy metals in Antarctic snow from Coats Land since the mid-19th to the late-20th century. Earth and Planetry Science Letters, 200(1–2), 207–222. https://doi.org/10.1016/S0012-821X(02)00612-X.
Protocol on Environmental Protection to the Antarctic Treaty (1991). [Electronic Resource]. – Mode of access: www.ats.aq/documents/recatt/Att006_e.pdf. Accessed 9 Jan 2019.
RD 52.04.186–89. (1991). Guidelines for the control of air pollution (530 pp.). Leningrad: USSR State Committee for Hydrometeorology, USSR Ministry of Health (In Russian).
Rudnic, R. L., & Gao, S. (2003). Composition of the continental crust. In H. D. Holland & K. K. Turekian (Eds.), Treatise on geochemistry (Vol. 3, pp. 1–64). London: Elsevier-Pergamon.
Suttie, E. D., & Wolff, E. W. (1992). Seasonal input of heavy metals to Antarctic snow. Tellus, 44B, 351–357.
Suttie, E. D., & Wolff, E. W. (1993). The local deposition of heavy metal emissions from point sources in Antarctica. Atmospheric Environment. Part A. General Topics, 27(12), 1833–1841.
TCGP 17.13-15-2014 (02120). (2015). Technical code of good practice. Environmental protection and nature use. Analytical (laboratory) control and environmental monitoring. Procedure for the sampling of air, precipitation and snow cover to determine the concentration of pollutants and meteorological observation (20 pp.). Minsk: Ministry of Natural Resources and Environmental Protection of the Republic of Belarus (in Russian).
Thamban, M., & Thakur, R. C. (2013). Trace metal concentrations of surface snow from Ingrid Christensen coast, East Antarctica–spatial variability and possible anthropogenic contributions. Environmental Monitoring and Assessment, 185(4), 2961–2975.
Tuohy, A., Bertler, N., Neff, P., Edwards, R., Emanuelsson, D., Beers, T., & Mayewski, P. (2015). Transport and deposition of heavy metals in the Ross Sea region, Antarctica. Journal of Geophysical Research – Atmospheres, 120, 10,996–11,011. https://doi.org/10.1002/2015JD023293.
Wagenbach, D., Ducroz, F., Mulvaney, R., Keck, L., Legrand, M., Hall, J. S., & Wolff, E. W. (1998). Sea-salt aerosol in coastal Antarctic regions. Journal of Geophysical Research, 103(D9), 10,961–10,974.
Warburton, J. A., Molenar, J. V., Owens, M. S., & Anderson, A. (1980). Heavy metal enrichment in Antarctic precipitation and near surface snow. PAGEOPH, 118, 1130–1144. https://doi.org/10.1007/BF01593054.
Wedepohl, K. H. (1995). The composition of the continental crust. Geochimica et Cosmochimica Acta, 59(7), 1217–1232.
Wolff, E. W., & Suttie, E. D. (1994). Antarctic snow record of southern hemisphere lead pollution. Geophysical Research Letters, 1994, 781–784. https://doi.org/10.1029/94GL00656.
Xiao, C., Qin, D., Yao, T., Ren, J., & Li, Y. (2000). Global pollution shown by lead and cadmium contents in precipitation of polar regions and Qinghai-Tibetan Plateau. Chin.Sci.Bull., 45, 847–853. https://doi.org/10.1007/BF02887416.
Acknowledgments
Authors express sincere gratitude to the Head of Belarusian Antarctic Expeditions Alexei Haidashou, to Dr. Vladislav Myamin, Dr. Yury Giginyak, and other participants of expeditions for snow sampling and transportation.
Funding
This study has been funded in the framework of the State Program “Monitoring of the Earth Polar Regions, Creation of the Belarusian Antarctic Station and Support of the Polar Expeditions for 2016–2020.”
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Sergey Kakareka contributed to the study conception of network monitoring, programs of investigation, article design, statistic calculation, and mapping. Tamara Kukharchyk provided the analysis of data, references review, and enrichment factor calculation. The first draft article has been prepared by S. Kakareka and T. Kukharchyk. Chemical analytical work and method description were performed by Peter Kurman. All authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Highlights
- Significant spatial variability of trace elements content in the surface snow of Vecherny Oasis.
- Sb, Se, As, Cd, Zn, Cr, Cu, Mo, V, and Pb are in the list of pollutants.
- Influence of local anthropogenic sources due to past and current activities.
- Surface snow sampling is a cost-effective method to monitor human activity impact according to the Annex 1 to the Protocol on Environmental Protection to the Antarctic Treaty.
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Kakareka, S., Kukharchyk, T. & Kurman, P. Study of trace elements in the surface snow for impact monitoring in Vecherny Oasis, East Antarctica. Environ Monit Assess 192, 725 (2020). https://doi.org/10.1007/s10661-020-08682-8
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DOI: https://doi.org/10.1007/s10661-020-08682-8