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Chemical compositions of snow from Mt. Yulong, southeastern Tibetan Plateau

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Abstract

The snow and ice in Mt. Yulong offer a unique opportunity to investigate changes in climate and large scale atmospheric circulations over Asia. During February and April 2012, surface snow samples were collected from the Baishui Glacier No. 1 at different altitudes along the eastern slope of Mt. Yulong. Two snowpits were also excavated from Mt. Yulong at altitudes of 4780 and 4730 m a.s.l. in February 2012. The concentrations of inorganic ions were higher at an elevation of 4506 m a.s.l. in the glacier with significant contribution of anthropogenic (mainly NH\(_{4}^{\mathrm {+}}\), SO\(_{4}^{\mathrm {2-}}\), NO\(_{3}^{\mathrm {-}})\) and crustal (mainly Ca 2+) constituents. Concentration of HCOO in surface snow exhibited large variability, ranging from 0.04 to 6.8 μeq L −1, attributed to dominant contribution from biomass burning emissions. Ion balance (ΔC) and Na +/Cl calculations indicated an excess of cations (particularly higher Ca 2+ concentrations) and Cl in snow, considering the sea-salt ratio, respectively. Monsoon season (June–September) ion concentrations in snowpit samples were generally two-fold lower than in other seasons. Principal component analysis was used to identify different sources of ions. Three main factors, accounting for more than 80% of the total variance, were related to different sources, including agricultural activities, biomass burning, and crustal aerosols.

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Acknowledgements

This work was supported by the Innovative Research Group National Natural Science Foundation of China (41121001) and Youth Talent Program of CAREERI (Y551C11001, Y451181001), CAS (KJZD-EW-G03-04), the Foundation from the State Key Laboratory of Cryospheric Sciences (05SS011201), and National Natural Science Foundation (41273010). We would like to thank two anonymous reviewers and Prof. K Krishnamoorthy for their constructive comments which substantially improved the quality of the paper. We would also like to express our appreciation to Prof. Neng-Huei (George) Lin and Dr Robbie Hart for their constructive comments.

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Niu, H., He, Y., Kang, S. et al. Chemical compositions of snow from Mt. Yulong, southeastern Tibetan Plateau. J Earth Syst Sci 125, 403–416 (2016). https://doi.org/10.1007/s12040-016-0670-5

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