Abstract
The health and environmental effects of chemical processes can be assessed during the initial stage of their production. In this paper, the Chemical Screening Tool for Exposure and Environmental Release (ChemSTEER) software was used to compare the health and environmental risks of spray pyrolysis and wet chemical techniques for the fabrication of nanostructured metal oxide on a semi-industrial scale with a capacity of 300 kg/day in Iran. The pollution sources identified in each production process were pairwise compared in Expert Choice software using indicators including respiratory damage, skin damage, and environmental damages including air, water, and soil pollution. The synthesis of nanostructured zinc oxide using the wet chemical technique (with 0.523 wt%) leads to lower health and environmental risks compared to when spray pyrolysis is used (with 0.477 wt%). The health and environmental risk assessment of nanomaterial production processes can help select safer processes, modify the operation conditions, and select or modify raw materials that can help eliminate the risks.
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References
Abdullah, L., & Yong Pang, J. (2016). Application of analytic hierarchy process for assessing sustainable development among underprivileged communities. Sustainable Development, 9(5), 70–82. https://doi.org/10.5539/jsd.v9n5p70.
California Council. (2010). Nanotechnology in California. http://www.ccst.us/publications/2010/2010Nano.pdf.
EPA. (2014). Predictive model and tools for assessing chemical under the toxic substances control act. http://www.epa.gov/tsca-screening-tools/chemsteer-chemical-screening-tool-exposures-and-environmental-releases.
Fu, L., Liu, Z., Liu, Y., Han, B., Hu, P., Cao, L., & Zhu, D. (2005). Beaded cobalt oxide nano particles along carbon nanotubes: Towards more highly integrated electronic devices. Advanced Materials, 17(2), 217–221. https://doi.org/10.1002/adma.200400833.
Gentile, M., Rogers, W. J., & Mannan, M. S. (2003). Development of fuzzy logic-based inherent safety index. Process Safety and Environmental Protection, 81(6), 444–456. https://doi.org/10.1205/095758203770866610.
Ghaffarian, H. R., Saiedi, M., Sayyadnejad, M. A., & Rashidi, A. M. (2011). Synthesis of ZnO nanoparticles by spray pyrolysis method. Chemistry Chemical. Engineering, 30, 1–6.
Gupta, J. P., & Edwards, D. W. (2003). A simple graphical method for measuring inherent safety. Hazardous Materials, 104(1-3), 15–30. https://doi.org/10.1016/S0304-3894(03)00231-0.
Harbawi, M. E.l., Mustapha, S., Choong, T. S. Y., Abdul Rashid, S., Kadir, S. A. S. A., & Abdul Rashid, Z. (2008). Rapid analysis of risk assessment using developed simulation of chemical industrial accidents software package. Engineering Science and Technology, 5, 53–64.
Hassim, M. H., & Edwards, D. W. (2006). Development of a methodology for assessing inherent occupational health hazards. Process Safety and Environmental Protection, 84(5), 378–390. https://doi.org/10.1205/psep.04412.
Hassim, M. H., & Hurme, M. (2010a). Inherent occupational health assessment during process research and development stage. Journal of Loss Prevention in the Process Industries, 23(1), 127–138. https://doi.org/10.1016/j.jlp.2009.06.009.
Hassim, M. H., & Hurme, M. (2010b). Inherent occupational health assessment during preliminary design stage. Journal of Loss Prevention in the Process Industries, 23(3), 476–482. https://doi.org/10.1016/j.jlp.2009.12.004.
Hassim, M. H., & Hurme, M. (2010c). Inherent occupational health assessment during basic engineering stage. Journal of Loss Prevention in the Process Industries, 23(2), 260–268. https://doi.org/10.1016/j.jlp.2009.10.006.
Ishizaka, A., & Labib, A. (2011). Review of the main developments in the analytic hierarchy process. Expert Systems with Applications, 38, 14336–14345.
Kim, D., Kim, J., & Moon, I. (2006). Integration of accident scenario generation and multi objective optimization for safety-cost decision making in chemical processes. Journal of Loss Prevention in the Process Industries, 19(6), 705–713. https://doi.org/10.1016/j.jlp.2006.04.002.
Kim, J., Kim, D., Lee, Y., Lim, W., & Moon, I. (2009). Application of TRIZ creativity intensification approach to chemical process safety. Journal of Loss Prevention in the Process Industries, 22(6), 1039–1043. https://doi.org/10.1016/j.jlp.2009.06.015.
Kweku Adu, I., Sugiyama, H., Fischer, U., & Hungerbuhler, K. (2008). Comparison of methods for assessing environmental, health and safety (EHS) hazards in early phases of chemical process design. Process Safety and Environmental Protection, 86, 77–93.
Madler, L. (2004). Liquid-fed aerosol reactors for one step synthesis of nano structured particle. Kona Powder and Particle Journal, 22, 107–120.
Makhluf, S., Dror, R., Nitzan, Y., Abramovich, Y., Jelnek, R., & Gedanken, A. (2005). Microwave-assisted synthesis of nanocrystalline MgO and its use as a bacteriocide. Advanced Functional Materials, 15(10), 1708–1715. https://doi.org/10.1002/adfm.200500029.
Mohammadi Roozbahani, M., Nassiri, P., & Jafari Shalkouhi, P. (2009). Risk assessment of workers exposed to noise pollution in a textile plant. Engineering Science and Technology, 6, 591–596.
Narkiewicz, U., Sibera, D., Kuryliszyn-Kudelska, I., Kilanski, L., Dobrowolski, W., & Romcevic, N. (2008). Synthesis by wet chemical method and characterization of nanocrystalline ZnO doped with Fe2O3. Acta Physica Polonica, 113(6), 1695–1700. https://doi.org/10.12693/APhysPolA.113.1695.
Nowack, B., & Bucheli, T. D. (2007). Occurrence, behavior and effects of nanoparticles in the environment. Environmental Pollution, 150(1), 5–22. https://doi.org/10.1016/j.envpol.2007.06.006.
Ostertag, K., & Husing, B. (2008). Identification of starting points for exposure assessment in the post-use phase of nanomaterial-containing products. Journal of Cleaner Production, 16(8-9), 938–948. https://doi.org/10.1016/j.jclepro.2007.04.019.
Rajendran, R., Balakumar, C., Hasabo, A. M. A., Jayakumar, S., Vaideki, K., & Rajesh, E. M. (2010). Use of zinc oxide nano particles for production of antimicrobial textiles. Engineering Science and Technology, 2, 202–208.
Rusli, R., & Shariff, A. M. (2010). Qualitative assessment for inherently safer design (QAISD) at preliminary design stage. Journal of Loss Prevention in the Process Industries, 23(1), 157–165. https://doi.org/10.1016/j.jlp.2009.07.005.
Saaty, T. L. (1986). Axiomatic foundation of the analytic hierarchy process. Management Science, 32(7), 841–855. https://doi.org/10.1287/mnsc.32.7.841.
Saaty, T. L. (2003). Decision-making with the AHP: Why is the principal eigenvector necessary. European Journal of Operational Research, 145(1), 85–91. https://doi.org/10.1016/S0377-2217(02)00227-8.
Saaty, T. L. (2008). Decision making with the analytic hierarchy process. International Journal of Services Sciences, 1(1), 83–98. https://doi.org/10.1504/IJSSCI.2008.017590.
Savolainen, K., Pylkkänen, L., Norppa, H., Falck, G., Lindberg, H., Tuomi, T., & Seipenbusch, M. (2010). Nanotechnologies, engineered nanomaterials and occupational health and safety—a review. Safety Science, 48(8), 957–963. https://doi.org/10.1016/j.ssci.2010.03.006.
Som, C., Wick, P., Krug, H., & Nowack, B. (2011). Environmental and health effects of nanomaterials in nanotextiles and façade coatings. Environment International, 37(6), 1131–1142. https://doi.org/10.1016/j.envint.2011.02.013.
Steffi, F., & Jurgen, S. (2007). Environmental, health and safety aspects of nanotechnology implications for the RandD in (small) companies. Science and Technology of Advanced Materials, 8, 12–18.
Sustainable Futures/P2 Framework Manual. (2012). EPA-748-B12-001 11. Estimating Workplace Exposure and Industrial Releases Using ChemSTEER. https://www.epa.gov/sites/production/files/2015-05/documents/11.pdf.
Tcai, S. C., Song, Y. L., Tsai, C. S., Yang, C. C., Chiu, W. Y., & Lin, H. M. (2004). Ultrasonic spray pyrolysis for nanoparticle synthesis. Journal of Materials Science, 39, 3647–3657.
Wang, W., Lio, Z., Lio, Y., Xu, C., Zheng, C., & Wang, G. (2003). A simple wet chemical synthesis and characterization of CuO nanorods. Applied Physics Letters, 76, 417–420.
Zhang, H., Feng, J., Wang, J., & Zhang, M. (2007). Preparation of ZnO nanorods through wet chemical method. Materials Letters, 61(30), 5202–5205. https://doi.org/10.1016/j.matlet.2007.04.030.
Zhang, L., Jiang, Y., Ding, Y., Daskalakis, N., Jeuken, L., Povey, M., et al. (2009). Mechanistic investigation into antibacterial behavior of suspensions of ZnO nanoparticles against E.coli. Journal of Nanoparticle Research, 12, 1625–1636.
Zhuravleva, N. G., and Shlyakhtin, O. A. (2011). Glossary of nanotechnology and related terms. http://eng.thesaurus.rusnano.com/wiki/article1209?sphrase_id=10219.
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This research was approved by Iran’s Research Institute of Petroleum Industry (RIPI). The authors wish to express their gratitude to the Nanotechnology Research Center of RIPI.
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Torabifard, M., Arjmandi, R., Rashidi, A. et al. Inherent health and environmental risk assessment of nanostructured metal oxide production processes. Environ Monit Assess 190, 73 (2018). https://doi.org/10.1007/s10661-017-6450-0
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DOI: https://doi.org/10.1007/s10661-017-6450-0