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Determination of the personal, indoor and outdoor exposure levels of inorganic gaseous pollutants in different microenvironments in an industrial city

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Abstract

We measured SO2, NO2 and O3 concentrations during the summer and winter in Kocaeli, Turkey. The sampling was carried out indoors and outdoors at homes, schools and offices. Personal samplers were also used to determine personal exposures to these pollutants. High NO2 and SO2 concentrations were observed in outdoor samples collected close to locations characterized by heavy urban traffic. Concentrations of O3, on the other hand, were higher in rural areas around the city due to ozone distillation. For both sampling periods, the concentrations of outdoor SO2 and O3 were higher than for indoor and personal samples; however, the NO2 concentrations were higher in indoor and personal samples, indicating that outdoor sources significantly contribute to indoor SO2 and O3 levels and that indoor NO2 concentrations are primarily modulated by sources within buildings. Seasonal variations in pollutant concentrations showed statistically significant differences. Indoor and outdoor concentrations of NO2 and SO2 measured in the winter were higher than the levels measured in the summer; O3 concentrations, on the other hand, exhibited the opposite trend. Active-to-passive concentration ratios for NO2, SO2 and O3 were 0.99, 1.08 and 1.16, respectively; the corresponding outdoor ratios were 0.95, 0.99 and 1.00.

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References

  • Baek, S. O., Kim, Y. S., & Perry, R. (1997). Indoor air quality in homes, offices and restaurants in Korean urban areas indoor/outdoor relationships. Atmospheric Environment, 31, 529–544.

    Article  CAS  Google Scholar 

  • Barraza, F., Jorquera, H., Valdivia, G., & Montoya, L. D. (2014). Indoor PM2.5 in Santiago, Chile, spring 2012: source apportionment and outdoor contributions. Atmospheric Environment, 94, 692–700.

    Article  CAS  Google Scholar 

  • Bracho, L. R., Suh, H. H., Oyola, P., & Koutrakis, P. (2002). Measurements of children’s exposures to particles and nitrogen dioxide in Santiago, Chile. The Science of the Total Environment, 287, 249–264.

    Article  Google Scholar 

  • Breysse, P. N., Buckley, T. J., Williams, D., Beck, C. M., Jo, S. J., Merriman, B., Kanchanaraksa, S., Swartz, L. J., Callahan, K. A., Butz, A. M., Rand, C. S., Diette, G. B., Krishnan, J. A., Moseley, A. M., Curtin-Brosnan, J., Durkin, N. B., & Eggleston, P. A. (2005). Indoor exposures to air pollutants and allergens in the homes of asthmatic children in inner-city Baltimore. Environmental Research, 98, 167–176.

    Article  CAS  Google Scholar 

  • Brunekreef, B., & Holgate, S. T. (2002). Air pollution and health. Lancet, 360, 1233–1242.

    Article  CAS  Google Scholar 

  • Castellano, M., Franco, A., Cartelle, D., Febrero, M., & Roca, E. (2009). Identification of NOx and ozone episodes and estimation of ozone by statistical analysis. Water, Air, and Soil Pollution, 198, 95–110.

    Article  CAS  Google Scholar 

  • Challoner, A., & Gill, L. (2014). Indoor/outdoor air pollution relationships in ten commercial buildings: PM2.5 and NO2. Building and Environment, 80, 159–173.

    Article  Google Scholar 

  • Chameides, W., & Walker, J. C. G. (1973). A photochemical theory of tropospheric ozone. Journal of Geophysical Research, 78, 8751–8760.

    Article  CAS  Google Scholar 

  • Chao, C. Y. H. (2001). Comparison between indoor and outdoor air contaminant levels in residential buildings from passive sampler study. Building and Environment, 36, 999–1007.

    Article  Google Scholar 

  • Crutzen, P. J. (1973). A discussion of the chemistry of some minor constituents in the stratosphere and troposphere. Pure and Applied Geophysics, 106, 1385–1399.

    Article  Google Scholar 

  • Demirel, G., Özden, Ö., Döğeroğlu, T., & Gaga, E. O. (2014). Personal exposure of primary school children to BTEX, NO2 and ozone in Eskişehir, Turkey: relationship with indoor/outdoor concentrations and risk assessment. Science of the Total Environment, 473–474, 537–548.

    Article  Google Scholar 

  • Genç, D., Yeşilyurt, C., & Tuncel, G. (2010). Air pollution forecasting in Ankara, Turkey using air pollution index and its relation to assimilative capacity of the atmosphere. Environmental Monitoring and Assessment, 166, 11–27.

    Article  Google Scholar 

  • Helaleh, M. I. H., Ngudiwaluyo, S., Korenaga, T., & Tanaka, K. (2002). Development of passive sampler technique for ozone monitoring. Estimation of indoor and outdoor ozone concentration. Talanta, 58, 649–659.

    Article  CAS  Google Scholar 

  • Jones, A. P. (1999). Indoor air quality and health. Atmospheric Environment, 33, 4535–4564.

    Article  CAS  Google Scholar 

  • Jovanovic, M., Vucicevic, B., Turanjanin, V., Zivkovi, M., & Spasojevic, V. (2014). Investigation of indoor and outdoor air quality of the classrooms at a school in Serbia. Energy, 77, 42–48.

    Article  CAS  Google Scholar 

  • Langer, S., & Bekö, G. (2013). Indoor air quality in the Swedish housing stock and its dependence on building characteristics. Building and Environment, 69, 44–54.

    Article  Google Scholar 

  • Lawrence, A., & Fatima, N. (2014). Urban air pollution & its assessment in Lucknow City—the second largest city of North India. Science of the Total Environment, 488–489, 447–455.

    Article  Google Scholar 

  • Lee, S. C., & Chang, M. (2000). Indoor and outdoor air quality investigation at schools in Hong Kong. Chemosphere, 41, 109–113.

    Article  CAS  Google Scholar 

  • Lee, H. S., Kang, B.-W., Cheongs, J. P., & Lee, S. K. (1997). Relationships between indoor and outdoor air quality during the summer season in Korea. Atmospheric Environment, 31(11), 1689–1693.

    Article  CAS  Google Scholar 

  • Lee, K., Parkhurst, W. J., Xue, J. P., Ozkaynak, A. H., Neuberg, D., & Spengler, J. D. (2004). Outdoor/indoor/personal ozone exposures of children in Nashville, Tennessee. Journal of the Air and Waste Management Association, 54, 352–359.

    Article  CAS  Google Scholar 

  • Mavroidis, I., & Chaloulakou, A. (2011). Long-term trends of primary and secondary NO2 production in the Athens area. Variation of the NO2/NOx ratio. Atmospheric Environment, 45, 6872–6879.

    Article  CAS  Google Scholar 

  • Mavroidis, I., & Ilia, M. (2012). Trends of NOx, NO2 and O3 concentrations at three different types of air quality monitoring stations in Athens, Greece. Atmospheric Environment, 63, 135–147.

    Article  CAS  Google Scholar 

  • Mayer, H. (1999). Air pollution in cities. Atmospheric Environment, 33, 4029–4037.

    Article  CAS  Google Scholar 

  • Meng, Q., Williams, R., & Pinto, J. P. (2012). Determinants of the associations between ambient concentrations and personal exposures to ambient PM2.5, NO2, and O3 during DEARS. Atmospheric Environment, 63, 109–116.

    Article  CAS  Google Scholar 

  • Menteşe, S., Mirici, N.A. Otkun, M.T., Bakar, C., Palaz, E., Taşdibi, D., Cevizci, S., Cotuker, O. (2015). Association between respiratory health and indoor air pollution exposure in Canakkale, Turkey. Building and Environment, 93(1), 72–83.

  • Mraihi, R., Harizi, R., Mraihi, T., & Bouzidi, M. T. (2015). Urban air pollution and urban daily mobility in large Tunisia’s cities. Renewable and Sustainable Energy Reviews, 43, 315–320.

    Article  CAS  Google Scholar 

  • Nopmongcol, U., Emery, C., Sakulyanontvittaya, T., Jung, J., Knipping, E., & Yarwood, G. (2014). A modeling analysis of alternative primary and secondary US ozone standards in urban and rural areas. Atmospheric Environment, 99, 266–276.

    Article  CAS  Google Scholar 

  • Norhidayah, A., Chia-Kuang, L., Azharb, M. K., & Nurulwahida, S. (2013). Indoor air quality and sick building syndrome in three selected buildings. Procedia Engineering, 53, 93–98.

    Article  CAS  Google Scholar 

  • Notario, A., Bravo, I., Adame, J. A., Díaz-de-Mera, Y., Aranda, A., Rodríguez, A., & Rodríguez, D. (2013). Variability of oxidants (OX = O3 + NO2), and preliminary study on ambient levels of ultrafine particles and VOCs, in an important ecological area in Spain. Atmospheric Research, 128, 35–45.

    Article  CAS  Google Scholar 

  • Pekey, B., & Özaslan, Ü. (2013). Spatial distribution of SO2, NO2, and O3 concentrations in an industrial City of Turkey using a passive sampling method. Clean: Soil, Air, Water, 41, 423–428.

    CAS  Google Scholar 

  • Radiello the radial diffusive sampler, Italy. Available at http://www.radiello.com. Accessed on 15 Feb 2015.

  • Rivas, I., Viana, M., Moreno, T., Bouso, L., Pandolfi, M., Alvarez-Pedrerol, M., Forns, J., Alastuey, A., Sunyer, J., & Querol, X. (2015). Outdoor infiltration and indoor contribution of UFP and BC, OC, secondary inorganic ions and metals in PM2.5 in schools. Atmospheric Environment, 106, 129–138.

    Article  CAS  Google Scholar 

  • Schindler, M., & Caruso, G. (2014). Urban compactness and the trade-off between air pollution emission and exposure: lessons from a spatially explicit theoretical model. Computers, Environment and Urban Systems, 45, 13–23.

    Article  Google Scholar 

  • Stranger, M., Potgieter-Vermaak, S. S., & Van Grieken, R. (2007). Comparative overview of indoor air quality in Antwerp, Belgium. Environment International, 33, 789–797.

    Article  CAS  Google Scholar 

  • Stranger, M., Krata, A., Kontozova-Deutsch, V., Bencs, L., Deutsch, F., Worobiec, A., Naveau, I., Roekens, E., & Grieken, R. V. (2008). Monitoring of NO2 in the ambient air with passive samplers before and after a road reconstruction event. Microchemical Journal, 90, 93–98.

    Article  CAS  Google Scholar 

  • Sudalma, S., Purwanto, P., & Santoso, L. W. (2015). The effect of SO2 and NO2 from transportation and stationary emissions sources to SO4 2−and NO3 in rain water in Semarang. Procedia Environmental Sciences, 23, 247–252.

    Article  CAS  Google Scholar 

  • Szczurek, A., Maciejewska, M., Teuerle, M., & Wyłomańska, A. (2015). Method to characterize collective impact of factors on indoor air. Physica A: Statistical Mechanics and its Applications, 420, 190–199.

    Article  CAS  Google Scholar 

  • Uchiyama, S., Tomizawa, T., Tokoro, A., Aoki, M., Hishiki, M., Yamada, T., Tanaka, R., Sakamoto, H., Yoshida, T., Bekki, K., Inaba, Y., Nakagome, H., & Kunugita, N. (2015). Gaseous chemical compounds in indoor and outdoor air of 602 houses throughout Japan in winter and summer. Environmental Research, 137, 364–372.

    Article  CAS  Google Scholar 

  • Waring, M. S., & Wells, J. R. (2014). Volatile organic compound conversion by ozone, hydroxyl radicals, and nitrate radicals in residential indoor air: magnitudes and impacts of oxidant sources. Atmospheric Environment, 106, 382–391.

  • Wei, J., Guo, X., Marinova, D., & Fan, J. (2014). Industrial SO2 pollution and agricultural losses in China: evidence from heavy air polluters. Journal of Cleaner Production, 64, 404–413.

    Article  CAS  Google Scholar 

  • Wichmann, J., Lind, T., Nilsson, M. A. M., & Bellander, T. (2010). PM2.5, soot and NO2 indoor outdoor relationships at homes, pre-schools and schools in Stockholm. Sweden Atmospheric Environment, 44, 4536–4544.

    Article  CAS  Google Scholar 

  • Zhao, Z., Zhang, Z., Wang, Z., Ferm, M., Liang, Y., & Norback, D. (2008). Asthmatic symptoms among pupils in relation to winter indoor and outdoor air pollution in schools in Taiyuan, China. Environmental Health Perspectives, 116, 90–97.

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support from the TÜBİTAK (The Scientific & Technological Research Council of Turkey) Grant (104Y275) is gratefully acknowledged.

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The authors declare that they have no competing interests.

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Informed consent was obtained from all individual participants included in the study.

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For this type of study, formal consent is not required.

This article does not contain any studies with animals performed by any of the authors.

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Correspondence to Zehra Bozkurt.

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Bozkurt, Z., Doğan, G., Arslanbaş, D. et al. Determination of the personal, indoor and outdoor exposure levels of inorganic gaseous pollutants in different microenvironments in an industrial city. Environ Monit Assess 187, 590 (2015). https://doi.org/10.1007/s10661-015-4816-8

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