Abstract
Nitrogen-doped copper-biochar (N–Cu-biochar) was synthesized via pyrolysis of glucose in the presence of copper and melamine and used as a catalyst in the reduction of p-nitrophenol by NaBH4. N–Cu–biochar was characterized by field emission scanning electron microscopy/energy-dispersive spectroscopy, Raman spectroscopy, X-ray Diffraction, and Brunauer–Emmett–Teller surface analyzer. The catalytic performance of N–Cu-biochar was evaluated under varying conditions of NaBH4 concentration, biochar dosage, and initial p-nitrophenol concentration. N–Cu-biochar was composed of ~83% C, ~9% O, and ~8% Cu, with Cu/Cu2O phases evenly dispersed on graphitic carbon aggregates possessing both macro- and meso-pores. N–Cu-biochar showed superior catalytic ability in mediating p-nitrophenol reduction as compared to Cu-biochar and N-doped biochar, achieving complete reduction of 0.35 mM p-nitrophenol within 30 min at a dose of 0.25 g L−1. Reduction of p-nitrophenol catalyzed by N–Cu-biochar followed pseudo-first-order kinetics, and the reaction rate was dependent upon NaBH4 concentration. The overall results indicate that biochar can be a suitable candidate as a support for catalyst synthesis, and N-doped Cu-biochar can be a promising catalyst for the reduction of p-nitrophenol.
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Ahmad, M., Rajapaksha, A. U., Lim, J. E., Zhang, M., Bolan, N., Mohan, D., et al. (2014). Biochar as a sorbent for contaminant management in soil and water: A review. Chemosphere, 99, 19–33.
Baricelli, P. J., Castillo, A., Longo, C., & Pardey, A. J. (2000). Homogeneous catalytic oxidation of cyclohexene by nitro complexes of copper(II). Reaction Kinetics and Catalysis Letters, 70(1), 133–138.
Bhandari, R., & Knecht, M. R. (2011). Effects of the Material Structure on the Catalytic Activity of Peptide-Templated Pd Nanomaterials. Acs Catalysis, 1(2), 89–98.
Chen, J., Zhang, H., Liu, P., Li, Y., Liu, X., Li, G., et al. (2015). Cross-linked ZnIn2S4/rGO composite photocatalyst for sunlight-driven photocatalytic degradation of 4-nitrophenol. Applied Catalysis, B: Environmental, 168–169, 266–273.
Choi, H., Al-Abed, S. R., Agarwai, S., & Dionysiou, D. D. (2008). Synthesis of reactive nano-Fe/Pd bimetallic system-impregnated activated carbon for the simultaneous adsorption and dechlorination of PCBs. Chemistry of Materials, 20(11), 3649–3655.
Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., et al. (2006). Raman spectrum of graphene and graphene layers. Physical Review Letters, 97(18), 187401.
Frindy, S., El Kadib, A., Lahcini, M., Primo, A., & Garcia, H. (2016). Isotropic and oriented copper nanoparticles supported on graphene as aniline guanylation catalysts. ACS Catalysis, 6(6), 3863–3869.
Gamez, P., Aubel, P. G., Driessen, W. L., & Reedijk, J. (2001). Homogeneous bio-inspired copper-catalyzed oxidation reactions. Chemical Society Reviews, 30(6), 376–385.
Gao, L., Li, R., Sui, X. L., Li, R., Chen, C. L., & Chen, Q. W. (2014). Conversion of chicken feather waste to N-doped carbon nanotubes for the catalytic reduction of 4-nitrophenol. Environmental Science and Technology, 48(17), 10191–10197.
Guo, M. Z., He, J., Li, Y., Ma, S., & Sun, X. H. (2016). One-step synthesis of hollow porous gold nanoparticles with tunable particle size for the reduction of 4-nitrophenol. Journal of Hazardous Materials, 310, 89–97.
Han, N., Cao, S., Han, J., Hu, J., Zhang, X., & Guo, R. (2016). Surface cavities of Ni(OH)2 nanowires can host Au nanoparticles as supported catalysts with high catalytic activity and stability. Journal of Materials Chemistry A, 4, 2590–2596.
Hasan, Z., Cho, D. W., Chon, C. M., Yoon, K., & Song, H. (2016). Reduction of p-nitrophenol by magnetic Co-carbon composites derived from metal organic frameworks. Chemical Engineering Journal, 298, 183–190.
Jiang, Y. J., Li, G. Z., Li, X. D., Lu, S. X., Wang, L., & Zhang, X. W. (2014). Water-dispersible Fe3O4 nanowires as efficient supports for noble-metal catalysed aqueous reactions. Journal of Materials Chemistry A, 2(13), 4779–4787.
Jiang, Y. F., Sun, H., Yves, U. J., Li, H., & Hu, X. F. (2016). Impact of biochar produced from post-harvest residue on the adsorption behavior of diesel oil on loess soil. Environmental Geochemistry and Health, 38(1), 243–253.
Kozma, G., Rónavári, A., Kónya, Z., & Kukovecz, Á. (2016). Environmentally benign synthesis methods of zero-valent iron nanoparticles. ACS Sustainable Chemistry and Engineering, 4, 291–297.
Lee, W. J., Maiti, U. N., Lee, J. M., Lim, J., Han, T. H., & Kim, S. O. (2014). Nitrogen-doped carbon nanotubes and graphene composite structures for energy and catalytic applications. Chemical Communications, 50(52), 6818–6830.
Lin, F. H., & Doong, R. A. (2011). Bifunctional Au–Fe3O4 heterostructures for magnetically recyclable catalysis of nitrophenol reduction. Journal of Physical Chemistry C, 115(14), 6591–6598.
Lin, F. H., & Doong, R. A. (2014). Highly efficient reduction of 4-nitrophenol by heterostructured gold-magnetite nanocatalysts. Applied Catalysis a-General, 486, 32–41.
Lu, W., Chen, W., Li, N., Xu, M., & Yao, Y. (2009). Oxidative removal of 4-nitrophenol using activated carbon fiber and hydrogen peroxide to enhance reactivity of metallophthalocyanine. Applied Catalysis, B: Environmental, 87, 146–151.
Mahamallik, P., & Pal, A. (2015). A soft-template mediated approach for Au(0) formation on a heterosilica surface and synergism in the catalytic reduction of 4-nitrophenol. RSC Advances, 5(95), 78006–78016.
Marais, E., & Nyokong, T. (2008). Adsorption of 4-nitrophenol onto Amberlite® IRA-900 modified with metallophthalocyanines. Journal of Hazardous Materials, 152, 293–301.
Modirshahla, N., Behnajady, M. A., & Mohammadi-Aghdam, S. (2008). Investigation of the effect of different electrodes and their connections on the removal efficiency of 4-nitrophenol from aqueous solution by electrocoagulation. Journal of Hazardous Materials, 154, 778–786.
Nasrollahzadeh, M., Zahraei, A., Ehsani, A., & Khalaj, M. (2014). Synthesis, characterization, antibacterial and catalytic activity of a nanopolymer supported copper(II) complex as a highly active and recyclable catalyst for the formamidation of arylboronic acids under aerobic conditions. RSC Advances, 4(39), 20351–20357.
Nasrollahzadeh, M., Sajadi, S. M., Rostami-Vartooni, A., Bagherzadeh, M., & Safari, R. (2015). Immobilization of copper nanoparticles on perlite: Green synthesis, characterization and catalytic activity on aqueous reduction of 4-nitrophenol. Journal of Molecular Catalysis A: Chemical, 400, 22–30.
Nemanashi, M., & Meijboom, R. (2013). Synthesis and characterization of Cu, Ag and Au dendrimer-encapsulated nanoparticles and their application in the reduction of 4-nitrophenol to 4-aminophenol. Journal of Colloid and Interface Science, 389, 260–267.
Niu, H. Y., Liu, S. L., Cai, Y. Q., Wu, F. C., & Zhao, X. L. (2016). MOF derived porous carbon supported Cu/Cu2O composite as high performance non-noble catalyst. Microporous and Mesoporous Materials, 219, 48–53.
O’Connor, O. A., & Young, L. Y. (1989). Toxicity and anaerobic biodegradability of substituted phenols under methanogenic conditions. Environmental Toxicology and Chemistry, 8, 853–862.
Pradhan, N., Pal, A., & Pal, T. (2002). Silver nanoparticle catalyzed reduction of aromatic nitro compounds. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 196(2–3), 247–257.
Rajapaksha, A. U., Ahmad, M., Vithanage, M., Kim, K. R., Chang, J. Y., Lee, S. S., et al. (2015). The role of biochar, natural iron oxides, and nanomaterials as soil amendments for immobilizing metals in shooting range soil. Environmental Geochemistry and Health, 37(6), 931–942.
Shi, J. J., Wang, Y. Y., Du, W. C., & Hou, Z. Y. (2016). Synthesis of graphene encapsulated Fe3C in carbon nanotubes from biomass and its catalysis application. Carbon, 99, 330–337.
Subashchandrabose, S. R., Megharaj, M., Venkateswarlu, K., & Naidu, R. (2012). p-nitrophenol toxicity to and its removal by three select soil isolates of microalgae: The role of antioxidants. Environmental Toxicology and Chemistry, 31(9), 1980–1988.
Tian, Y., Cao, Y. Y., Pang, F., Chen, G. Q., & Zhang, X. (2014). Ag nanoparticles supported on N-doped graphene hybrids for catalytic reduction of 4-nitrophenol. RSC Advances, 4(81), 43204–43211.
Torkamani, F., & Azizian, S. (2016). Green and simple synthesis of Ag nanoparticles loaded onto cellulosic fiber as efficient and low-cost catalyst for reduction of 4-nitrophenol. Journal of Molecular Liquids, 214, 270–275.
Usman, A. R. A., Ahmad, M., El-Mahrouky, M., Al-Omran, A., Ok, Y. S., Sallam, A. S., et al. (2016). Chemically modified biochar produced from conocarpus waste increases NO3 removal from aqueous solutions. Environmental Geochemistry and Health, 38(2), 511–521.
Vats, T., Dutt, S., Kumar, R., & Siril, P. F. (2016). Facile synthesis of pristine graphene-palladium nanocomposites with extraordinary catalytic activities using swollen liquid crystals. Scientific Reports, 6, article number 33053.
Wang, H. B., Maiyalagan, T., & Wang, X. (2012). Review on recent progress in nitrogen-doped graphene: Synthesis, characterization, and its potential applications. ACS Catalysis, 2(5), 781–794.
Wunder, S., Polzer, F., Lu, Y., Mei, Y., & Ballauff, M. (2010). Kinetic analysis of catalytic reduction of 4-nitrophenol by metallic nanoparticles immobilized in spherical polyelectrolyte brushes. Journal of Physical Chemistry C, 114(19), 8814–8820.
Xu, J., Wang, L., & Zhu, Y. F. (2012). Decontamination of bisphenol A from aqueous solution by graphene adsorption. Langmuir, 28(22), 8418–8425.
Yang, X. L., Zhong, H., Zhu, Y. H., Jiang, H. L., Shen, J. H., Huang, J. F., et al. (2014). Highly efficient reusable catalyst based on silicon nanowire arrays decorated with copper nanoparticles. Journal of Materials Chemistry A, 2(24), 9040–9047.
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This research was supported by Korea Ministry of Environment (MOE) as Waste to Energy-recycling Human Resource Development project.
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Cho, DW., Kim, S., Tsang, Y.F. et al. Preparation of nitrogen-doped Cu-biochar and its application into catalytic reduction of p-nitrophenol. Environ Geochem Health 41, 1729–1737 (2019). https://doi.org/10.1007/s10653-017-9966-x
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DOI: https://doi.org/10.1007/s10653-017-9966-x