A one-step synthesis of potentially useful enantiomerically pure macroheterocycles with four esters was developed starting from natural castor oil [(R,Z)-(+)-12-hydroxy-9-octadecenoic acid triglyceride].
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G. Yu. Ishmuratov, M. P. Yakovleva, G. R. Mingaleeva, M. A. Shutova, R. R. Muslukhov, E. M. Vyrypaev, and A. G. Tolstikov, Makrogeterotsikly, 6, 180 (2013).
L. N. Ovsyannikov (ed.), Catalog of Chemical Reagents and High Purity Chemicals [in Russian], Khimiya, Moscow, 1971, 548 pp.
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The work was supported financially in part by the RFBR (Grant 17-03-01050).
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, July–August, 2017, pp. 528–530.
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Ishmuratov, G.Y., Yakovleva, M.P., Vydrina, V.A. et al. One-Step Synthesis from Castor Oil of Enantiomeric Macrolides. Chem Nat Compd 53, 620–622 (2017). https://doi.org/10.1007/s10600-017-2073-5
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DOI: https://doi.org/10.1007/s10600-017-2073-5