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Conjugates of Polyguluronic and Polymannuronic Acids with 4-Aminoantipyrine. Determination Using 1H–13C HSQC Spectra of Triad Units and Their Distribution in the Polysaccharide Chain

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Conjugates of poly-α-(1→4)-L-guluronic and poly-β-(1→4)-D-mannuronic acids with 1-phenyl-2,3-dimethyl-4-aminopyrazol-5-one (4-aminoantipyrine) were synthesized and characterized using 1H–13C HSQC spectra by the contents of intact A units, modified B units, and triad sequences of units with an A center (AAA, AAB + BAA, and BAB) and with a B center (BBB, BBA + ABB, and ABA).

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Acknowledgment

We thank Cand. Chem. Sci. I. R. Ramazanov (Institute of Petroleum Chemistry and Catalysis, RAS) for useful discussions.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, Russian Federation, 450075, Ufa, Prosp. Oktyabrya, 141

    D. I. Araslanova, I. Yu. Ponedel’kina, T. V. Tyumkina & V. N. Odinokov

Authors
  1. D. I. Araslanova
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  2. I. Yu. Ponedel’kina
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  3. T. V. Tyumkina
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  4. V. N. Odinokov
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Corresponding author

Correspondence to V. N. Odinokov.

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Translated from Khimiya Prirodnykh Soedinenii, No. 2, March–April, 2014, pp. 197–200.

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Araslanova, D.I., Ponedel’kina, I.Y., Tyumkina, T.V. et al. Conjugates of Polyguluronic and Polymannuronic Acids with 4-Aminoantipyrine. Determination Using 1H–13C HSQC Spectra of Triad Units and Their Distribution in the Polysaccharide Chain. Chem Nat Compd 50, 220–224 (2014). https://doi.org/10.1007/s10600-014-0917-9

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  • DOI: https://doi.org/10.1007/s10600-014-0917-9

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