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Metal-complex catalysis during the reduction of functional groups by sodium borohydride in the synthesis of pyrrolidine derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A selective method was developed for the reduction of functional groups with sodium borohydride using complexes of CoCl2 and CuCl2 with triethylbenzylammonium chloride and cobalt and copper mesotetra[4-(2-hydroxyethyl)pyridyl]porphyrinates as catalysts.

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Authors and Affiliations

  1. A. L. Mndzhoyan Institute of Fine Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan

    A. O. Martirosyan, V. E. Hovhanesyan & S. P. Gasparyan

  2. Center of Research on the Structure of Molecules, National Academy of Sciences of the Republic of Armenia, Erevan

    S. S. Mamayan

  3. M. Heratsi Erevan Medical University, Erevan, Republic of Armenia

    R. K. Ghazaryan & V. N. Madakyan

Authors
  1. A. O. Martirosyan
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  2. V. E. Hovhanesyan
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  3. S. P. Gasparyan
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  4. S. S. Mamayan
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  5. R. K. Ghazaryan
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  6. V. N. Madakyan
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 205–208, February, 2006.

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Martirosyan, A.O., Hovhanesyan, V.E., Gasparyan, S.P. et al. Metal-complex catalysis during the reduction of functional groups by sodium borohydride in the synthesis of pyrrolidine derivatives. Chem Heterocycl Compd 42, 180–183 (2006). https://doi.org/10.1007/s10593-006-0068-4

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  • DOI: https://doi.org/10.1007/s10593-006-0068-4

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