Abstract
The structure of a laminar rich premixed 1,3-butadiene/CH4/O2/Ar flame has been investigated, 1,3-butadiene, methane, oxygen, and argon mole fractions being 0.033, 0.2073, 0.3315, and 0.4280, respectively, for an equivalence ratio of 1.80. The flame has been stabilized on a burner at a pressure of 6.7 kPa. The concentration profiles of stable species have been measured by gas chromatography after sampling with a quartz probe. The quantified species include carbon monoxide and dioxide, methane, oxygen, hydrogen, ethane, ethylene, acetylene, propyne, allene, propene, cyclopropane, 1,3-butadiene, butenes, 1-butyne, vinylacetylene, diacetylene, C5 compounds, benzene, and toluene. The temperature distribution in the flame has also been measured.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. A. Cole, J. D. Bittner, J. P. Longwell, and J. B. Howard, “Formation mechanisms of aromatic compounds in aliphatic flames,” Combust. Flame, 56, 51 (1984).
P. R. Westmoreland, A. M. Dean, J. B. Howard, and J. P. Longwell, “Forming benzene in flames by chemically activated isomerization,” J. Phys. Chem., 93, 9171 (1989).
J. A. Miller and C. F. Melius, “Kinetic and thermodynamic issues in the formation of aromatic compounds in flames of aliphatic fuels,” Combust. Flame, 91, 21 (1992).
N. M. Marinov, W. J. Pitz, C. K. Westbrook, et al., “Modeling of aromatic and polycyclic aromatic hydrocarbon formation in premixed methane and ethane flames,” Combust. Sci. Technol., 116–117, 211 (1996).
H. Wang and M. Frenklach, “A detailed kinetic modeling study of aromatics formation in laminar premixed acetylene and ethylene flames,” Combust. Flame, 110, 173 (1997).
H. A. Gueniche, P. A. Glaude, G. Dayma, et al., “Rich methane premixed laminar flames doped with light unsaturated hydrocarbons: I. Allene and propyne,” Combust. Flame, 146, 620–634 (2006).
R. Fournet, J. C. Baugé, and F. Battin-Leclerc, “Experimental and modeling of oxidation of acetylene, propyne, allene, and 1,3-butadiene,” Int. J. Chem. Kin., 31, 361 (1999).
K. Brezinsky, E. J. Burke, and I. Glassman, “The high temperature oxidation of butadiene,” Proc. Combust. Inst., 20, 613 (1984).
N. Belmekki, P. A. Glaude, Da Costa, et al., “Experimental and modeling study of the oxidation of 1-butyne, 2-butyne,” Int. J. Chem. Kin., 34, 172 (2002).
J. H. Kent, “A noncatalytic coating for platinum-rhodium thermocouples,” Combust. Flame, 14, 279 (1970).
U. Bonne, T. Grewer, and H. W. Wagner, “Messungen in der reaktionszone von wasserstoff-sauerstoff und methan-sauerstoff flammen,” Z. Phys. Chem., 26, 93 (1960).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 6, pp. 89–95, November–December, 2006.
Rights and permissions
About this article
Cite this article
Gueniche, H.A., Glaude, P.A., Fournet, R. et al. Experimental study of the structure of a rich premixed 1,3-butadiene/CH4/O2/Ar flame. Combust Explos Shock Waves 42, 702–707 (2006). https://doi.org/10.1007/s10573-006-0104-9
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10573-006-0104-9