Skip to main content
Log in

Testing ogranophosphorus, organofluorine, and metal-containing compounds and solid-propellant gas-generating compositions doped with phosphorus-containing additives as effective fire suppressants

  • Published:
Combustion, Explosion and Shock Waves Aims and scope

Abstract

The development and investigation of new effective and environmentally clean flame suppressants is a promising direction in fire extinguishing. Organophosphorus and metal-containing compounds are the most promising candidates for the replacement of CF3Br. However, for many of these compounds, data on their minimum extinguishing concentration are not available. In the present work, the minimum extinguishing concentrations for a number of new phosphorus-and metal-containing compounds and some of their mixtures, solid-propellant gas-generating compositions containing phosphorus additives were determined using the cup-burner technique and a setup with a turbulent flame source and transient application of flame suppressants.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. G. Gann, “Next generation fire suppression technology program: FY2003 progress,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-1, Albuquerque (2003). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0301557.pdf.)

  2. J. D. Mather, R. E. Tapscott, J. M. Shreeve, and R. P. Singh, “Fluoroalkyl phosphorus compounds NGP element: 4D/14/1,” ibid. (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0301564.pdf.)

  3. O. P. Korobeinichev, A. G. Shmakov, V. M. Shvartsberg, et al., “Study of effect of aerosol and vapor of organophosphorus fire suppressants on diffusion heptane and premixed C3H8/air flames,” ibid. (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0301562.pdf.)

  4. A. G. Shmakov, O. P. Korobeinichev, V. M. Shvartsberg, et al., “Inhibition of premixed and nonpremixed flames with phosphorus-containing compounds,” Proc. Combust. Inst., 30, No. 2, 2345–2352 (2004).

    Article  Google Scholar 

  5. O. P. Korobeinichev, A. G. Shmakov, A. A. Chernov, et al., “Study of effectiveness of flame suppression by organophosphorus compounds in laboratory and scaled-up tests,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-2, Albuquerque (2004). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0401176.pdf.)

  6. J. Riches, K. Grant, and L. Knutsen, “Laboratory testing of some phosphorus-containing compounds as flame suppressants,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-2, Albuquerque (1999). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R9902743.pdf.)

  7. L. Knutsen, E. Morrey, and J. Riches, “Comparison of agent extinguishment of hydrogen and hydrocarbon flames using FID,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-2, Albuquerque (2001). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0200493.pdf.)

  8. E. Morrey and L. Knutsen, “Initial investigation of combined fire extinguishing effectiveness of novel phosphorus containing compounds in potential delivery media,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-2, Albuquerque (2003). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0301565.pdf.)

  9. G. T. Linteris, “Suppression of cup-burner diffusion flames by supereffective chemical inhibitors and inert compounds,” in: Proc. of the Halon Options Technical Working Conference, NIST SP 984-2, Albuquerque (2001). (www.bfrl.nist.gov/866/HOTWC/HOTWC2006/pubs/R0200488.pdf.)

  10. G. T. Linteris, V. R. Katta, and F. Takahashi, “Experimental and numerical evaluation of metallic compounds for suppressing cup-burner flames,” Combust. Flame, 138, 78–96 (2004).

    Article  Google Scholar 

  11. B. P. Zhukov, “Powder, pyrotechnics, and special solid propellants in fire fighting,” in: Effective Systems of Fire Extinguishing Based on Powders and Special Solid Propellants [in Russian], InformTÉI, Moscow (1991), pp. 4–10.

    Google Scholar 

  12. W. Grosshandler, A. Hamins, K. Mc Grattan, and C. Presser, Transient Application, Recirculating Pool Fire, Agent Effectiveness Screen, Final Report, NGP Project 3A/2/890, April (2001).

  13. A. N. Baratov, Combustion-Fire-Explosion-Safety [in Russian], Fire Safety Research Institute, Moscow (2003).

    Google Scholar 

  14. J. L. Lott et al. “Synergism between chemical and physical fire-suppressant agents,” Fire Technol., 32, No. 3, 260–271 (1996).

    Article  MathSciNet  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 6, pp. 64–73, November–December, 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shmakov, A.G., Korobeinichev, O.P., Shvartsberg, V.M. et al. Testing ogranophosphorus, organofluorine, and metal-containing compounds and solid-propellant gas-generating compositions doped with phosphorus-containing additives as effective fire suppressants. Combust Explos Shock Waves 42, 678–687 (2006). https://doi.org/10.1007/s10573-006-0101-z

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10573-006-0101-z

Key words

Navigation