Abstract
The possibility of using molecular beam mass spectrometry (MBMS) to study the structure of counterflow flames was shown by the example of a CH4/N2-O2/N2 flame. The thermal structure of the flame was studied, and the CH4, O2, and CO2 concentration distributions were measured using a microprobe technique and MBMS. The results of the measurements performed by the two methods were compared. The MBMS technique was used to study the hydroxyl concentration distribution in the flame. The species concentrations and temperature profiles on the burner axis were calculated.
Similar content being viewed by others
References
S. C. Li and F. A. Williams, “Counterflow heptane flame structure,” Proc. Combust. Inst., 28, 1031–1038 (2000).
M. M. Y. Waly and F. A. Williams, “Structures of nonsooting counterflow diluted acetylene-air flames, ” ibid, pp. 2005–2012.
R. R. Skaggs, R. G. Daniel, A. W. Miziolek, and K. L. McNesby, “Spectroscopic studies of inhibited opposed flow propane/air flames,” in: Proc. First Joint Meeting of the U.S. Sections of the Combustion Institute, Washington, DC (1999), pp. 575–578.
D. D. Thomsen and N. M. Laurendeau, “LIF measurements and modeling of nitric oxide concentration in atmospheric counter.ow premixed flames,” Combust. Flame, 124, 350–369 (2001).
M. A. MacDonald, F. C. Gouldin, and E. M. Fisher, “Temperature dependence of phosphorus-based flame inhibition,” Combust. Flame, 125, 668–683 (2001).
J. E. Siow and N. M. Laurendeau, “Flame inhibition activity of phosphorus-containing compounds using laser-induced fluorescence measurements of hydroxyl,” Combust. Flame, 136, 16–24 (2004).
E. M. Fisher, B. A. Williams, and J. W. Fleming, “Determination of the strain in counterflow diffusion flames from flow conditions,” in: Proc. Eastern States Section, Combust. Inst. (1997), pp. 191–194.
H. K. Chelliah, C. K. Law, and T. Ueda, et al., “An experimental and theoretical investigation of the dilution pressure and flow field effects on the extinction condition of methane-air-nitrogen diffusion flames,” Proc. Combust. Inst., 23, 503–510 (1990).
K. Seshadri and F. A. Williams, “Laminar flow between parallel plates with injection of a reactant at high Reynolds number,” Int. J. Heat Mass Transfer, 21, 251–253 (1978).
O. P. Korobeinichev, S. B. Il’in, V. M. Mokrushin, and A. G. Shmakov, “Destruction chemistry of dimethyl methylphosphonate in H2/O2/Ar flames studied by molecular beam mass spectrometry,” Combust. Sci. Technol., 116–117, 51–67 (1996).
A. E. Lutz, R. J. Kee, J. F. Grcar, and F. M. Rupley, “CHEMKIN collection,” Unlimited Release, Sandia National Laboratories, Livermore (1997).
R. J. Kee, F. M. Rupley, and J. A. Miller, “CHEMKIN-II: A Fortran chemical kinetics package for the analysis of gas-phase chemical kinetics,” Sandia National Laboratories, Report No. SAND 89-8009B (1989).
W. C. Gardiner (Jr.) (ed.), Combustion Chemistry, Springer Verlag, New York (1984).
G. P. Smith, D. M. Golden, M. Frenklach, et al., “GRI Mech 3.0,” http: //www.me.berkeley.edu/gri_mech/.
R. V. Ravikrishna, C. S. Cooper, and N. M. Laurendeau, “Comparison of saturated and linear laser-induced fluorescence measurements of nitric oxide in counterflow diffusion flames,” Combust. Flame, 117, 810–820 (1999).
H. K. Chelliah, M. Bui-Pham, K. Seshadri, and C. K. Law, “Numerical descriptions of the structure of counterflow heptane-air flames using detailed and reduced chemistry with comparison to experiments,” Proc. Combust. Inst., 24, 851–857 (1992).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 4, pp. 26–33, July–August, 2006.
Rights and permissions
About this article
Cite this article
Knyaz’kov, D.A., Korobeinichev, O.P. & Shmakov, A.G. Investigation of the structure of a CH4/N2-O2/N2 Counterflow diffusion flame using molecular beam and microprobe mass spectrometry. Combust Explos Shock Waves 42, 389–395 (2006). https://doi.org/10.1007/s10573-006-0067-x
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10573-006-0067-x