Abstract
Textile structural color is an important method to replace the highly polluting coloring of traditional dyes and colors. The polydopamine (PDA) film with melanin-like characteristics can achieve multiple bright structural colors on the white cotton fabrics surface. However, PDA can cause cracking and inferior color fastness due to the influence of capillary tension during the film formation on the surface of cotton fabrics. A novel polysiloxane binder containing reactive groups, PVS, can form strong chemical bonds with PDA polymers, thereby improving the color fastness of structurally colored cotton fabrics. Moreover, the introduction of chemical bonds also reduced the proportion of surface hydrophilic groups, thus improved the hydrophobicity of the structural color film. Scanning electron microscopy was used to reveal the structure and morphology of the double-layer composite aggregates formed by the DA self-polymerization. Fourier transform infrared spectroscopy and X-ray diffraction spectroscopy were used to investigate the surface composition of structural color cotton fabrics. The color properties of PDA structured color films were revealed by UV-Vis diffuse reflectance and reflectance spectrometer.
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References
Allauddin S, Narayan R, Raju KVSN (2013) Synthesis and properties of alkoxysilane castor oil and their polyurethane/urea–silica hybrid coating films. ACS Sustain Chem Eng 1:910–918
Cazacu M, Vlad A, Munteanu G, Airinei A (2008) Multifunctional materials based on polyazomethines derived from 2,5-dihydroxy-1,4-benzoquinone and siloxane diamines. J Polym Sci Part A Polym Chem 46:1862–1872
Chen D, Chen F, Zhang H et al (2016) Preparation and characterization of novel hydrophobic cellulose fabrics with polyvinylsilsesquioxane functional coatings. Cellulose 23:941–953
Chen F, Yang H, Li K et al (2017) Facile and effective coloration of dye-inert carbon fiber fabrics with tunable colors and excellent laundering durability. ACS Nano 11:10330–10336
Cong H, Yu B, Zhao XS (2011) Imitation of variable structural color in paracheirodon innesi using colloidal crystal films. Opt Express 19:12799–12808
Cong H, Yu B, Wang S et al (2013) Preparation of iridescent colloidal crystal coatings with variable structural colors. Opt Express 21:17831–17838
Dong X, Gao S, Huang J et al (2019) A self-roughened and biodegradable superhydrophobic coating with UV shielding, solar-induced self-healing and versatile oil–water separation ability. J Mater Chem A 7:2122–2128
Dumanli AG, Savin T (2016) Recent advances in the biomimicry of structural colours. Chem Soc Rev 45:6698–6724
Fang K, Xie R, Liu X et al (2019) Reactive dye/poly(styrene-co-butyl acrylate-co-trimethyl(vinylbenzyl) ammonium chloride) nanospheres with high coloration performance for cleaner dyeing of cotton fabrics. Cellulose 26:5807–5819
Fu Y, Tippets CA, Donev EU, Lopez R (2016) Structural colors: from natural to artificial systems. Wiley Interdiscip Rev Nanomed Nanobiotechnol 8:758–775
Gu P, Fan N, Wang Y et al (2019) Linear control of moisture permeability and anti-adhesion of bacteria in a broad temperature region realized by cross-linking thermoresponsive microgels onto cotton fabrics. ACS Appl Mater Interfaces 11:30269–30277
Haensel T, Comouth A, Lorenz P et al (2009) Pyrolysis of cellulose and lignin. Appl Surf Sci 255:8183–8189
Haroun AA, Diab HA, Hakeim OA (2016) Cellulosic fabrics printing with multifunctional encapsulated phthalocyanine pigment blue using phase separation method. Carbohydr Polym 146:102–108
Hirogaki K, Nakamura D, Sekiguchi K et al (2018) The structural formation of closely packed colloidal crystals on fibre and the effect of fibre surface functionality on crystalline structure. Color Technol 134:271–274
Jeong G, Jung J-H, Lim J-H et al (2014) A computational mechanistic study of breakpoint chlorination for the removal of ammonia nitrogen from Water. J Chem Eng Jpn 47:225–229
Kinoshita S, Yoshioka S (2005) Structural colors in nature: the role of regularity and irregularity in the structure. ChemPhysChem 6:1442–1459
Kohri M, Kohma H, Shinoda Y et al (2013) A colorless functional polydopamine thin layer as a basis for polymer capsules. Polym Chem 4:2696–2702
Kohri M, Yamazaki S, Kawamura A et al (2017) Bright structural color films independent of background prepared by the dip-coating of biomimetic melanin-like particles having polydopamine shell layers. Colloids Surf A 532:564–569
Li Q, Zhang Y, Shi L et al (2018) Additive mixing and conformal coating of noniridescent structural colors with robust mechanical properties fabricated by atomization deposition. ACS Nano 12:3095–3102
Li N, Li T, Qiao X-Y et al (2020) Universal strategy for efficient fabrication of blood compatible surfaces via polydopamine-assisted surface-initiated activators regenerated by electron transfer atom-transfer radical polymerization of zwitterions. ACS Appl Mater Interfaces 12:12337–12344
Li S, Jia L, Dong P et al (2021) Construction of photonic crystal structural colors on white polyester fabrics. Opt Mater 116:111115
Liu Y, Ai K, Lu L (2014) Polydopamine and its derivative materials: synthesis and promising applications in energy, environmental, and biomedical fields. Chem Rev 114:5057–5115
Liu P, Chen J, Zhang Z et al (2018) Bio-inspired robust non-iridescent structural color with self-adhesive amorphous colloidal particle arrays. Nanoscale 10:3673–3679
Nair BP, Pavithran C (2010) Bifunctionalized hybrid silica spheres by hydrolytic cocondensation of 3-Aminopropyltriethoxysilane and vinyltriethoxysilane. Langmuir 26:730–735
Ran J, Bi S, Jiang H et al (2019) Core–shell BiVO4@PDA composite photocatalysts on cotton fabrics for highly efficient photodegradation under visible light. Cellulose 26:6259–6273
Riedel F, Spange S (2009) A solvatochromic study of silicates and borate containing 4-nitrocatechol ligands. J Phys Org Chem 22:203–211
Sun M, He Y, Yang W, Yin M (2014) A fluorescent perylene-assembled polyvinylpyrrolidone film: synthesis, morphology and nanostructure. Soft Matter 10:3426–3431
Takeoka Y, Yoshioka S, Takano A et al (2013) Production of colored pigments with amorphous arrays of black and white colloidal particles. Angew Chem 52:7261–7265
Tu W, Liu Y, Chen M et al (2022) A mussel-induced approach to secondary functional cross-linking 3-aminopropytriethoxysilane to modify the graphene oxide membrane for wastewater purification. Chin Chem Lett 34(1), 107322
Wan M, Wang Q, Zhan S et al (2017) In situ growth of mesoporous silica with drugs on titanium surface and its biomedical applications. ACS Appl Mater Interfaces 9:18609–18618
Wang Z, Wang C, Hou H et al (2019a) A facile fabrication of stimulus-responsive amorphous photonic crystals in the near-infrared region. Appl Surf Sci 479:1014–1020
Wang Z, Zhao S, Zhang W et al (2019b) Bio-inspired cellulose nanofiber-reinforced soy protein resin adhesives with dopamine-induced codeposition of “water-resistant” interphases. Appl Surf Sci 478:441–450
Xu Y, Zhao J, Zhang Z et al (2020) Preparation of electrospray ALG/PDA–PVP nanocomposites and their application in cancer therapy. Soft Matter 16:132–141
Yang H, Wang Y, Liu K et al (2019) Facile fabrication of ultraviolet-protective silk fabrics via atomic layer deposition of TiO2 with subsequent polyvinylsilsesquioxane modification. Text Res J 89:3529–3538
Yang H, Zhou J, Duan Z et al (2022) Preparation of structural color on cotton cabric with high color fastness through multiple hydrogen bonds between polyphenol hydroxyl and lactam. ACS Appl Mater Interfaces 14:3244–3254
Zhao Y, Xie Z, Gu H et al (2012) Bio-inspired variable structural color materials. Chem Soc Rev 41:3297–3317
Zhou L, Li Y, Liu G et al (2016) Study on the correlations between the structural colors of photonic crystals and the base colors of textile fabric substrates. Dyes Pigm 133:435–444
Zhou L, Yang L, Liu Y et al (2020a) Dynamic structural color from wrinkled thin films. Adv Opt Mater 8:2000234
Zhou Q, Wu W, Zhou S et al (2020b) Polydopamine-induced growth of mineralized γ-FeOOH nanorods for construction of silk fabric with excellent superhydrophobicity, flame retardancy and UV resistance. Chem Eng J 382:122988
Zhu X, Yan B, Yan X et al (2020) Fabrication of non-iridescent structural color on silk surface by rapid polymerization of dopamine. Prog Org Coat 149:105904
Acknowledgments
The authors would like to thank the support of the National Natural Science Foundation of China (Grant 52173062); and the Key Laboratory of Textile Fiber&Product (Wuhan Textile University) (Grant FZXW2017013), Ministry of Education.
Funding
This work was supported by the National Natural Science Foundation of China (Grant 52173062); and the Key Laboratory of Textile Fiber&Product (Wuhan Textile University) (Grant FZXW2017013), Ministry of Education.
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ZJ: contributed to the theoretical analysis and investigation. DZ and LB: participated in the discussion. LX: contributed to the supervision and editing. YH: contributed to the methodology and investigation, and wrote the paper. DB: contributed to the conceptualization, supervision and editing.
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Zhou, J., Duan, Z., Lu, B. et al. Preparation of structural colors on cotton fabrics with hydrophobicity and high color fastness through chemical bonds between polyphenolic hydroxyl groups and polysiloxanes. Cellulose 30, 6639–6653 (2023). https://doi.org/10.1007/s10570-023-05243-3
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DOI: https://doi.org/10.1007/s10570-023-05243-3