Abstract
Multifunctional cotton fabric was prepared by coating AgBr–TiO2/OV-POSS nanocomposites using the spray coating method. The increase in surface roughness and high adhesion between the coating and the cotton textile were attributed to the presence of AgBr–TiO2 nanoparticles and the superimposed crosslinking agent octavinyl polyhedral oligomeric silsesquioxane (OV-POSS). Incorporation of the coated layers resulted in an increase in hydrophobicity and a decrease in the surface energy of the cotton fabric. The analytical results showed that the highest water contact angle (WCA) of the cotton fabric coated with AgBr–TiO2(5%)/OV-POSS (0.09%) was 150.8 ± 1.2°. The as-prepared samples exhibited excellent mechanical durability and chemical resistance with up to 30 washes, good UV protection and self-cleaning properties. In addition, the AgBr–TiO2/OV-POSS coated fabrics showed high efficiency in oil/water separation and methylene blue degradation under UV-A irradiation. The antibacterial activity of AgBr–TiO2(5%)/OV-POSS (0.09%) cotton fabrics was tested with K. pneumoniae and S. aureus and showed excellent antibacterial efficacy of > 99%.
Similar content being viewed by others
Availability of data and materials
The authors declare that all relevant data are included in the article and/or its supplementary information files.c
References
Anderson SE, Mitchell C, Haddad TS, Vij A, Schwab JJ, Bowers MT (2006) Structural characterization of POSS siloxane dimer and trimer. Chem Mater 18:1490–1497. https://doi.org/10.1021/cm052589c
Atacan K, Özacar M, Özacar M (2018) Investigation of antibacterial properties of novel papain immobilized on tannic acid modified Ag/CuFe2O4 magnetic nanoparticles. Int J Biol Macromol 109:720–731. https://doi.org/10.1016/j.ijbiomac.2017.12.066
Ataee B, Khorasani MT, Karimi M, Daliri-Joupari M (2022) Surface modification of polyurethane/HCNT nanocomposite with octavinyl polyhedral oligomeric silsesquioxane as a heart valve material. Int J Polym Mater Polym Biomater 71:1037–1050. https://doi.org/10.1080/00914037.2021.1937160
Awazu K, Fujimaki M, Rockstuhl C, Tominaga J, Murakami H, Ohki Y, Yoshida N, Watanabe T (2008) A plasmonic photocatalyst consisting of silver nanoparticles embedded in titanium dioxide. J Am Chem Soc 130:1676–1680. https://doi.org/10.1021/ja076503n
Bai W, Chen K, Chen J, Xu J, Lin H, Lin Y, Xu Y, Lin J (2020) Natural Highly-hydrophobic urushiol@TiO2 coated cotton fabric for effective oil–water separation in highly acidic alkaline and salty environment. Sep Purif Technol 253:117495. https://doi.org/10.1016/j.seppur.2020.117495
Beshkar F, Salavati-Niasari M, Amiri O (2020) A reliable hydrophobic/superoleophilic fabric filter for oil–water separation: hierarchical bismuth/purified terephthalic acid nanocomposite. Cellulose 27:9559–9575. https://doi.org/10.1007/s10570-020-03441-x
Cao C, Wang F, Lu M (2020) Superhydrophobic CuO coating fabricated on cotton fabric for oil/water separation and photocatalytic degradation. Colloids Surfaces A Physicochem Eng Asp 601:125033. https://doi.org/10.1016/j.colsurfa.2020.125033
Chen D, Yi S, Wu W, Zhong Y, Liao J, Huang C, Shi WJ (2010) Synthesis and characterization of novel room temperature vulcanized (RTV) silicone rubbers using vinyl-POSS derivatives as cross linking agents. Polymer 51:3867–3878. https://doi.org/10.1016/j.polymer.2010.06.028
Cheng QY, Guan CS, Wang M, Li YD, Zeng JB (2018) Cellulose nanocrystal coated cotton fabric with superhydrophobicity for efficient oil/water separation. Carbohydr Polym 199:390–396. https://doi.org/10.1016/j.carbpol.2018.07.046
Cheng D, Zhang Y, Bai X, Liu Y, Deng Z, Wu J, Bi S, Ran J, Cai G, Wang X (2020) Mussel-inspired fabrication of superhydrophobic cotton fabric for oil/water separation and visible light photocatalytic. Cellulose 27:5421–5433. https://doi.org/10.1007/s10570-020-03149-y
Chuang W, Hui Y, Fei C, Lei P, Hong-Fang G, Li-Ping Z (2018) Influences of VTMS/SiO2 ratios on the contact angle and morphology of modified super-hydrophobic silicon dioxide material by vinyl trimethoxysilane. Results Phys 10:891–902. https://doi.org/10.1016/j.rinp.2018.08.007
Chung C, Lee M, Choe EK (2004) Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr Polym 58:417–420. https://doi.org/10.1016/j.carbpol.2004.08.005
Cong C, Cui C, Meng X, Zhou Q (2014) Stability of POSS crosslinks and aggregates in tetrafluoroethylenepropylene elastomers/OVPOSS composites exposed to hydrochloric acid solution. Polym Degrad Stab 100:29–36. https://doi.org/10.1016/j.polymdegradstab.2013.12.032
Foorginezhad S, Zerafat MM (2019a) Fabrication of superhydrophobic coatings with self-cleaning properties on cotton fabric based on Octa vinyl polyhedral oligomeric silsesquioxane/polydimethylsiloxane (OV-POSS/PDMS) nanocomposite. J Colloid Interface Sci 540:78–87. https://doi.org/10.1016/j.jcis.2019.01.007
Foorginezhad S, Zerafat MM (2019b) Fabrication of stable fluorine-free superhydrophobic fabrics for anti-adhesion and self-cleaning properties. Appl Surf Sci 464:458–471. https://doi.org/10.1016/j.apsusc.2018.09.058
Gorguluer H, Cakiroglu B, Ozacar M (2021) Ag NPs deposited TiO2 coating material for superhydrophobic, antimicrobial and self-cleaning surface fabrication on fabric. J Coatings Technol Res 18:569–579. https://doi.org/10.1007/s11998-020-00412-6
He T, Zhao H, Liu Y, Zhao C, Wang L, Wang H, Zhao Y, Wang H (2020) Facile fabrication of superhydrophobic Titanium dioxide-composited cotton fabrics to realize oil-water separation with efficiently photocatalytic degradation for water-soluble pollutants. Colloids Surfaces A Physicochem Eng Asp 585:124080. https://doi.org/10.1016/j.colsurfa.2019.124080
Hou Y, Li X, Zhao Q, Chen G, Raston CL (2012) Role of hydroxyl radicals and mechanism of escherichia coli inactivation on Ag/AgBr/TiO2 nanotube array electrode under visible light irradiation. Environ Sci Technol 46:4042–4050. https://doi.org/10.1021/es204079d
Ibrahim NA, El-Zairy EM, Eid BM, Emam E, Barkat SR (2017a) A new approach for imparting durable multifunctional properties to linen-containing fabrics. Carbohydr Polym 157:1085–1093. https://doi.org/10.1016/j.carbpol.2016.10.074
Ibrahim NA, Eid BM, El-Aziz EA, Abou Elmaaty TM, Ramadan SM (2017b) Loading of chitosan—Nano metal oxide hybrids onto cotton/polyester fabrics to impart permanent and effective multifunctions. Int J Biol Macromol 105:769–776. https://doi.org/10.1016/j.ijbiomac.2017.07.099
Ibrahim NA, Aly AA, Eid BM, Fahmy HM (2018) Green approach for multifunctionalization of cellulose-containing fabrics. Fibers Polym 19:2298–2306. https://doi.org/10.1007/s12221-018-8602-4
Ibrahim NA, Amr A, Eid BM (2020) Multipurpose treatment of cellulose-containing fabrics to impart durable antibacterial and repellent properties. Fibers Polym 21:513–521. https://doi.org/10.1007/s12221-020-9221-4
Ibrahim NA, Eid BM, Emam EM (2022) An eco-friendly facile approach for imparting multifunctional protection properties to cellulose/wool blends. Polym Bull. https://doi.org/10.1007/s00289-021-04072-3
Kang T, Tang L, Qu J (2018) Preparation and properties of high hardness ultraviolet curable polyethylene terephthalates surface coatings modified with octavinyl-polyhedral oligomeric silsesquioxane. Coatings 8:411. https://doi.org/10.3390/coatings8110411
Kanjana N, Maiaugree W, Poolcharuansin P, Laokul P (2020) Size controllable synthesis and photocatalytic performance of mesoporous TiO2 hollow spheres. J Mater Sci Technol 48:105–113. https://doi.org/10.1016/j.jmst.2020.03.013
Kanjana N, Maiaugree W, Laokul P (2022) Photocatalytic activity of nanocrystalline Fe3+-doped anatase TiO2 hollow spheres in a methylene blue solution under visible-light irradiation. J Mater Sci Mater Electron. https://doi.org/10.1007/s10854-021-07654-z
Khan MZ, Militky J, Baheti V, Wiener J, Vik M (2020) Development of durable superhydrophobic and UV protective cotton fabric via TiO2/trimethoxy(octadecyl)silane nanocomposite coating. J Text Inst. https://doi.org/10.1080/00405000.2020.1834235
Liang J, Zhou Y, Jiang G, Wang R, Wang X, Hu R, Xi X (2013) Transformation of hydrophilic cotton fabrics into superhydrophobic surfaces for oil/water separation. J Text Inst 104:305–311. https://doi.org/10.1080/00405000.2012.721207
Liu X, Zhang D, Guo B, Qu Y, Tian G, Yue H, Feng S (2015) Recyclable and visible light sensitive Ag–AgBr/TiO2: surface adsorption and photodegradation of MO. Appl Surf Sci 353:913–923. https://doi.org/10.1016/j.apsusc.2015.06.206
Liu J, Cheng Y, Xu K, An L, Su Y, Li X, Zhang Z (2018) Effect of nano-silica filler on microstructure and mechanical properties of polydimethylsiloxane-based nanocomposites prepared by “inhibition grafting” method. Compos Sci Technol 167:355–363. https://doi.org/10.1016/j.compscitech.2018.08.014
Lu P, Hsieh YL (2010) Preparation and properties of cellulose nanocrystals: rods, spheres, and network. Carbohydr Polym 82:329–336. https://doi.org/10.1016/j.carbpol.2010.04.073
Mao Z, Xie R, Fu D, Zhang L, Xu H, Zhong Y, Sui X (2017) PAN supported Ag-AgBr@Bi20TiO32 electrospun fiber mats with efficient visible light photocatalytic activity and antibacterial capability. Sep Purif Technol 176:277–286. https://doi.org/10.1016/j.seppur.2016.12.027
Pal S, Mondal S, Pal P, Das A, Pramanik S, Maity J (2021) Fabrication of durable, fluorine-free superhydrophobic cotton fabric for efficient self-cleaning and heavy/light oil-water separation. Colloid Interface Sci Commun 44:100469. https://doi.org/10.1016/j.colcom.2021.100469
Qi L, Qiu S, Xi J, Yu B, Hu Y, Xing W (2022) Construction of super-hydrophobic, highly effective flame retardant coating for cotton fabric with superior washability and abrasion resistance. J Colloid Interface Sci 607:2019–2028. https://doi.org/10.1016/j.jcis.2021.10.021
Ramaiah B, Ari AP (2019) Evaluation of color strength (K/S) values of cotton fabrics dyed with reactive dye and treated with silver nanoparticles. AIP Conf Proc 2162:020111. https://doi.org/10.1063/1.5130321
Ran J, Chen H, Bi S, Guo Q, Deng Z, Cai G, Cheng D, Tang X, Wang X (2020) One-step in-situ growth of zeolitic imidazole frameworks-8 on cotton fabrics for photocatalysis and antimicrobial activity. Cellulose 27:10447–10459. https://doi.org/10.1007/s10570-020-03483-1
Rana M, Hao B, Mu L, Chen L, Ma PC (2016) Development of multi-functional cotton fabrics with Ag/AgBr–TiO2 nanocomposite coating. Compos Sci Technol 122:104–112. https://doi.org/10.1016/j.compscitech.2015.11.016
Riaz S, Ashraf M, Aziz H, Younus A, Umair M, Salam A, Iqbal K, Hussain MT, Hussain T (2022) Cationization of TiO2 nanoparticles to develop highly durable multifunctional cotton fabric. Mater Chem Phys 278:125573. https://doi.org/10.1016/j.matchemphys.2021.125573
Sethy NK, Arif Z, Kumar Mishra P, Kumar P (2020) Nanocomposite film with green synthesized TiO2 nanoparticles and hydrophobic polydimethylsiloxane polymer: synthesis, characterization, and antibacterial test. J Polym Eng 40:211–220. https://doi.org/10.1515/polyeng-2019-0257
Shang Q, Cheng J, Liu C, Hu L, Bo C, Hu Y, Yang X, Ren X, Zhou Y, Lei W (2021) Fabrication of sustainable and durable bio-polybenzoxazine based superhydrophobic cotton fabric for efficient oil/water separation. Prog Org Coatings 158:106343. https://doi.org/10.1016/j.porgcoat.2021.106343
Singh AK, Singh JK (2017) Fabrication of durable superhydrophobic coatings on cotton fabrics with photocatalytic activity by fluorine-free chemical modification for dual-functional water purification. New J Chem 41:4618–4628. https://doi.org/10.1039/C7NJ01042G
Sun J, Bi H, Jia H, Su S, Dong H, Xie X, Sun L (2020) A low cost paper tissue-based PDMS/SiO2 composite for both high efficient oil absorption and water-in-oil emulsion separation. J Clean Prod 244:118814. https://doi.org/10.1016/j.jclepro.2019.118814
Tanaka K, Chujo Y (2012) Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS). J Mater Chem 22:1733–1746. https://doi.org/10.1039/C1JM14231C
Tao C, Li XH, Liu B, Zhang KQ, Zhao YH, Zhu KY, Yuan XY (2017) Highly icephobic properties on slippery surfaces formed from polysiloxane and fluorinated POSS. Prog Org Coat 103:48–59. https://doi.org/10.1016/j.porgcoat.2016.11.018
Tian L, Sun K, Rui Y, Cui W, An W (2018) Facile synthesis of an Ag@AgBr nanoparticle-decorated K4Nb6O17 photocatalyst with improved photocatalytic properties. RSC Adv 8:29309–29320. https://doi.org/10.1039/c8ra03597k
Turemen M, Demir A, Gokce Y (2021) The synthesis and application of chitosan coated ZnO nanorods for multifunctional cotton fabrics. Mater Chem Phys 268:124736. https://doi.org/10.1016/j.matchemphys.2021.124736
Ugur SS, Sariisik M, Aktas AH, Ucar MC, Erden E (2010) Modifying of cotton fabric surface with nano-ZnO multilayer films by layer-by-layer deposition method. Nanoscale Res Lett 5:1204–1210. https://doi.org/10.1007/s11671-010-9627-9
Wang P, Huang B, Qin X, Zhang X, Dai Y, Whangbo MH (2009) Ag/AgBr/WO3-H2O: visible-light photocatalyst for bacteria destruction. Inorg Chem 48:10697–10702. https://doi.org/10.1021/ic9014652
Wang D, Duan Y, Luo Q, Li X, An J, Bao L, Shi L (2012) Novel preparation method for a new visible light photocatalyst: Mesoporous TiO2 supported Ag/AgBr. J Mater Chem 22:4847–4854. https://doi.org/10.1039/c2jm14628b
Xiang F, Zong Y, Chen M, Li Z (2022) Preparation of super-hydrophobic cotton fabrics with the controllable roughening fiber surface by carbene polymerization grafting. Prog Org Coatings 163:106635. https://doi.org/10.1016/j.porgcoat.2021.106635
Xue Y, Liu Y, Lu F, Qu J, Chen H, Dai L (2012) Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications. J Phys Chem Lett 3:1607–1612. https://doi.org/10.1021/jz3005877
Yang Y, Guo Z, Li Y, Qing Y, Wang W, Ma Z, You S, Li W (2022) Multifunctional superhydrophobic self-cleaning cotton fabrics with oil-water separation and dye degradation via thiol-ene click reaction. Sep Purif Technol 282:120123. https://doi.org/10.1016/j.seppur.2021.120123
Yu H, Wu M, Duan G, Gong X (2022) One-step fabrication of eco-friendly superhydrophobic fabrics for high-efficiency oil/water separation and oil spill cleanup. Nanoscale. https://doi.org/10.1039/D1NR07111D
Yuzer B, Aydin MI, Con AH, Inan H, Can S, Selcuk H, Kadmi Y (2022) Photocatalytic, self-cleaning and antibacterial properties of Cu(II) doped TiO2. J Environ Manage. https://doi.org/10.1016/j.jenvman.2021.114023
Zang Y, Farnood R (2008) Photocatalytic activity of AgBr/TiO2 in water under simulated sunlight irradiation. Appl Catal B Environ 79:334–340. https://doi.org/10.1016/j.apcatb.2007.10.019
Zeng W, Huang H, Song L, Jiang X, Zhang X (2020) A novel hydroxyl polyacrylate latex modified by OvPOSS and its application in two-component waterborne polyurethane coatings. J Coat Technol Res 17:181–191. https://doi.org/10.1007/s11998-019-00256-9
Zhang Q, He H, Xi K, Huang X, Yu X, Jia X (2011) Synthesis of n-phenylaminomethyl POSS and its utilization in polyurethane. Macromolecules 44:550–557. https://doi.org/10.1021/ma101825j
Zhang D, Liu Y, Shi Y, Huang G (2014) Effect of polyhedral oligomeric silsesquioxane (POSS) on crystallization behaviors of POSS/polydimethylsiloxane rubber nanocomposites. RSC Adv 4:6275–6283
Zhou X, Zhang Z, Xu X, Guo F, Zhu X, Men X, Ge B (2013) Robust and durable superhydrophobic cotton fabrics for oil/water separation. ACS Appl Mater Interfaces 5:7208–7214. https://doi.org/10.1021/am4015346
Zhou P, Lv J, Xu H, Wang X, Sui X, Zhong Y, Wang B, Chen Z, Feng X, Zhang L, Mao Z (2019a) Functionalization of cotton fabric with bismuth oxyiodide nanosheets: applications for photodegrading organic pollutants, UV shielding and self-cleaning. Cellulose 26:2873–2884. https://doi.org/10.1007/s10570-019-02281-8
Zhou Q, Long M, Wen N, Deng W, Deng W (2019b) Rapid reversible superwettability transition and controllable oil/water separation based on hierarchical CuO. Surf Coatings Technol 374:144–151. https://doi.org/10.1016/j.surfcoat.2019.03.050
Acknowledgments
The authors would like to thanks Plasma technology research unit, Faculty of Science, Mahasarakham University for WCA facility.
Funding
This research was supported by Mahasarakham University (Postdoctoral Fellowship 2022).
Author information
Authors and Affiliations
Contributions
NK and PL wrote the main manuscript text. Material preparation, data collection and analysis were performed by NK, RR, SR, and NK. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Competing interests
The authors declare that there is no affiliation with any institute/organization with indirect or direct financial interest with this paper.
Ethics approval and consent for publication
This work does not contain any studies involving human participants performed by any of the authors.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Supplementary file2 (MP4 11688 kb)
Supplementary file3 (MP4 1635 kb)
Supplementary file4 (MP4 529 kb)
Supplementary file5 (MP4 2431 kb)
Supplementary file6 (MP4 11957 kb)
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Kanjana, N., Ruangjan, S., Kotsarn, N. et al. Multifunctional fluorine-free cotton fabrics modified by AgBr–TiO2/OV-POSS nanocomposites. Cellulose 30, 2503–2527 (2023). https://doi.org/10.1007/s10570-022-04985-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-022-04985-w