Skip to main content
Log in

One-step nanocellulose coating converts tissue paper into an efficient separation membrane

  • Communication
  • Published:
Cellulose Aims and scope Submit manuscript

Abstract

This article reports robust technology for converting tissue paper (TP) into an efficient separation membrane by coating with a novel superhydrophobic material that was synthesized by a rapid, one step approach without using any hazardous chemicals viz fluorinated materials or organic/inorganic nanoparticles. The coating was prepared using modified cellulose nanofibers which can readily transform a TP into an excellent oil/water separation membrane as well as a highly efficient dye absorbent upon spray coating. While the as-synthesized superhydrophobic cellulose surface shows water contact angle 161° (±3°), the coated TP displays 144° (±3°). Nevertheless, the coated TP shows outstanding separation performances towards various oil/water mixtures. Besides that, the coated TP also shows excellent dye absorption capacity from aqueous solution within 10 min. To further explore the multifunctional roles of the coating material, when spray it on a dishwasher sponge, the sponge became a super oil absorbent material and able to separate various oils from water at unbelievably faster rate. Hence, we believe that our ecofriendly versatile superhydrophobic coating material can be a new promising choice for many advanced applications to create more sustainable earth.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

References

  • Bashar MM, Zhu H, Yamamoto S, Mitsuishi M (2017) Superhydrophobic surfaces with fluorinated cellulose nanofiber assemblies for oil–water separation. RSC Adv 7:37168–37174

    Article  CAS  Google Scholar 

  • Boinovich LB, Emelyanenko AM (2013) Anti-icing potential of superhydrophobic coatings. Mendeleev Commun 23:3–10

    Article  CAS  Google Scholar 

  • Cengiz U, Avci MZ, Erbil HY, Sarac AS (2012) Superhydrophobic terpolymer nanofibers containing perfluoroethyl alkyl methacrylate by electrospinning. Appl Surf Sci 258:5815–5821

    Article  CAS  Google Scholar 

  • Chen J, Li K, Zhang H, Liu J, Wu S, Fan Q, Xue H (2017) Highly efficient and robust oil/water separation materials based on wire mesh coated by reduced graphene oxide. Langmuir 33:9590–9597

    Article  CAS  PubMed  Google Scholar 

  • Ding X, Zhou S, Gu G, Wu L (2011) A facile and large-area fabrication method of superhydrophobic self-cleaning fluorinated polysiloxane/TiO2 nanocomposite coatings with long-term durability. J Mater Chem 21:6161–6164

    Article  CAS  Google Scholar 

  • Draper MC, Crick CR, Orlickaite V, Turek VA, Parkin IP, Edel JB (2013) superhydrophobic surfaces as an on-chip microfluidic toolkit for total droplet control. Anal Chem 85:5405–5410

    Article  CAS  PubMed  Google Scholar 

  • Feng J, Tuominen MT, Rothstein JP (2011) Hierarchical superhydrophobic surfaces fabricated by dual-scale electron-beam-lithography with well-ordered secondary nanostructures. Adv Funct Mater 21:3715–3722

    Article  CAS  Google Scholar 

  • Gao X, Yan X, Yao X, Xu L, Zhang K, Zhang J, Yang B, Jia L (2007) The dry-style antifogging properties of mosquito compound eyes and artificial analogues prepared by soft lithography. Adv Mater 19:2213–2217

    Article  CAS  Google Scholar 

  • Gao X, Wang X, Ouyang X, Wen C (2016) Flexible superhydrophobic and superoleophilic MoS2 sponge for highly efficient oil–water separation. Sci Rep 6:27207

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Gonçalves G, Marques PA, Trindade T, Neto CP, Gandini A (2008) Superhydrophobic cellulose nanocomposites. J Colloid Interface Sci 324:42–46

    Article  CAS  PubMed  Google Scholar 

  • Gu J, Xiao P, Huang Y, Zhang J, Chen T (2015) Controlled functionalization of carbon nanotubes as superhydrophobic material for adjustable oil/water separation. J Mater Chem A 3:4124–4128

    Article  CAS  Google Scholar 

  • He M, Wang J, Li H, Song Y (2011) Super-hydrophobic surfaces to condensed micro-droplets at temperatures below the freezing point retard ice/frost formation. Soft Matter 7:3993–4000

    Article  CAS  Google Scholar 

  • Kafy A, Kim HC, Zhai L, Kim JW, Kang TJ (2017) Cellulose long fibers fabricated from cellulose nanofibers and its strong and tough characteristics. Sci Rep 7:17683

    Article  PubMed  PubMed Central  Google Scholar 

  • Kobayashi N, Izumi H, Morimoto Y (2017) Review of toxicity studies of carbon nanotubes. J Occup Health 59:394–407

    Article  PubMed  PubMed Central  Google Scholar 

  • Laurén P, Lou YR, Raki M, Urtti A, Bergström K, Yliperttula M (2014) Technetium-99 m-labeled nanofibrillar cellulose hydrogel for in vivo drug release. Eur J Pharm Sci 65:79–88

    Article  CAS  PubMed  Google Scholar 

  • Li S, Zhang S, Wang X (2008) Fabrication of superhydrophobic cellulose-based materials through a solution-immersion process. Langmuir 24:5585–5590

    Article  CAS  PubMed  Google Scholar 

  • Liu Y, Liu Z, Liu Y, Hu H, Li Y, Yan P, Yu B, Zhou F (2015a) one-step modification of fabrics with bioinspired polydopamine@octadecylamine nanocapsules for robust and healable self-cleaning performance. Small 11:426–431

    Article  CAS  PubMed  Google Scholar 

  • Liu Y, Zhou J, Zhu E, Tang J, Liu X, Tang W (2015b) Covalently intercalated graphene oxide for oil–water separation. Carbon 82:264–272

    Article  CAS  Google Scholar 

  • Liu L, Lei J, Li L, Zhang R, Mi N, Chen H, Huang D, Li N (2017) A facile method to fabricate the superhydrophobic magnetic sponge for oil–water separation. Mater Lett 195:66–70

    Article  CAS  Google Scholar 

  • Lu Y, Sathasivam S, Song J, Crick CR, Carmalt CJ, Parkin IP (2015) Robust self-cleaning surfaces that function when exposed to either air or oil. Science 347:1132–1135

    Article  CAS  PubMed  Google Scholar 

  • Luo Y, Jiang S, Xiao Q, Chen C, Li B (2017) Highly reusable and superhydrophobic spongy graphene aerogels for efficient oil/water separation. Sci Rep 7:7162

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Mahadik SA, Fernando PD, Hegade ND, Wagh PB, Gupta SC (2013) Durability and restoring of superhydrophobic properties in silica-based coatings. J Colloid Interface Sci 405:262–268

    Article  CAS  PubMed  Google Scholar 

  • Malik NS, Ahmad M, Minhas MU (2017) Cross-linked β-cyclodextrin and carboxymethyl cellulose hydrogels for controlled drug delivery of acyclovir. PLoS ONE 12:e0172727

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Nguyen DD, Tai NH, Lee SB, Kuo WS (2012) Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method. Energy Environ Sci 5:7908–7912

    Article  CAS  Google Scholar 

  • Ogawa T, Ding B, Sone Y, Shiratori S (2007) Super-hydrophobic surfaces of layer-by-layer structured film-coated electrospun nanofibrous membranes. Nanotechnology 18:165607

    Article  CAS  Google Scholar 

  • Pan C, Shen L, Shang S, Xing Y (2012) Preparation of superhydrophobic and UV blocking cotton fabric via sol-gel method and self-assembly. Appl Surf Sci 259:110–117

    Article  CAS  Google Scholar 

  • Poma A, Guerreiro A, Whitcombe MJ, Piletska EV, Turner AP, Piletsky SA (2016) Solid phase synthesis of molecularly imprinted polymer nanoparticles with a reusable template– “plastic antibodies”. Nat Protoc 11:443–453

    Article  CAS  PubMed  Google Scholar 

  • Roy S, Das T, Yue CY (2013) High performance of cyclic olefin copolymer-based capillary electrophoretic chips. ACS Appl Mater Interfaces 5:5683–5689

    Article  CAS  PubMed  Google Scholar 

  • Roy S, Kuddannaya S, Das T, Lee HY, Lim J, Hu XM, Yoon YC, Kim J (2017) A novel approach for fabricating highly tunable and fluffy bioinspired 3D poly(vinyl alcohol) (PVA) fiber scaffolds. Nanoscale 9:7081–7093

    Article  CAS  PubMed  Google Scholar 

  • Ruan M, Li W, Wang B, Deng B, Ma F, Yu Z (2013) Preparation and anti-icing behavior of superhydrophobic surfaces on aluminum alloy substrate. Langmuir 29:8482–8491

    Article  CAS  PubMed  Google Scholar 

  • Shannon MA, Bohn PW, Elimelech M, Georgiadis JG, Marinas BJ, Mayes AM (2008) Science and technology for water purification in the coming decades. Nature 452:301–310

    Article  CAS  PubMed  Google Scholar 

  • Skocaj M, Filipic M, Petkovic J, Novak S (2011) Titanium dioxide in our everyday life; is it safe? Radiol Oncol 45:227–247

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Sun Z, Liao T, Liu K, Jiang L, Kim JH, Dou SX (2014) Fly-eye inspired superhydrophobic anti-fogging inorganic nanostructures. Small 10:3001–3006

    Article  CAS  PubMed  Google Scholar 

  • Suryaprabha T, Sethuraman TG (2017) Fabrication of copper-based super hydrophobic self-cleaning antibacterial coating over cotton fabric. Cellulose 24:395–407

    Article  CAS  Google Scholar 

  • Wang CF, Lin SJ (2013) Robust super hydrophobic/superoleophilic sponge for effective continuous absorption and expulsion of oil pollutants from water. ACS Appl Mater Interfaces 5:8861–8864

    Article  CAS  PubMed  Google Scholar 

  • Wang Y, Lin F, Peng J, Dong Y, Li W, Huang Y (2016) A robust bilayer nanofilm fabricated on copper foam for oil–water separation with improved performances. J Mater Chem A 4:10294–10303

    Article  CAS  Google Scholar 

  • Wei B, Xu X, Jin Z, Tian Y (2014) Surface chemical compositions and dispersity of starch nanocrystals formed by sulfuric and hydrochloric acid hydrolysis. PLoS ONE 9:e86024

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Wu D, Yu Z, Wu W, Fang L, Zhu H (2014a) Continuous oil–water separation with surface modified sponge for cleanup of oil spills. RSC Adv 4:53514–53519

    Article  CAS  Google Scholar 

  • Wu G, An J, Tang XZ, Xiang Y, Yang J (2014b) A versatile approach towards multifunctional robust microcapsules with tunable, restorable, and solvent-proof superhydrophobicity for self-healing and self-cleaning coatings. Adv Funct Mater 24:6751–6761

    Article  CAS  Google Scholar 

  • Xue CH, Bai X, Jia ST (2016) Robust, self-healing superhydrophobic fabrics prepared by one-step coating of PDMS and octadecylamine. Sci Rep 6:27262

    Article  PubMed  PubMed Central  Google Scholar 

  • Yang H, Dou X, Fang Y, Jiang P (2013) Self-assembled biomimetic superhydrophobic hierarchical arrays. J Colloid Interface Sci 405:51–57

    Article  CAS  PubMed  Google Scholar 

  • Yang S, Chen L, Wang C, Rana M, Ma PC (2017) Surface roughness induced superhydrophobicity of graphene foam for oil–water separation. J Colloid Interface Sci 508:254–262

    Article  CAS  PubMed  Google Scholar 

  • Zhang H, Li Y, Lu Z, Chen L, Huang L, Fan M (2017a) A robust superhydrophobic TiO2 NPs coated cellulose sponge for highly efficient oil–water separation. Sci Rep 7:9428

    Article  PubMed  PubMed Central  Google Scholar 

  • Zhang L, Li H, Lai X, Su X, Liang T, Zeng X (2017b) Thiolated graphene-based superhydrophobic sponges for oil–water separation. Chem Eng J 316:736–743

    Article  CAS  Google Scholar 

  • Zhang X, Liu D, Ma Y, Nie J, Sui G (2017c) Super-hydrophobic graphene coated polyurethane (GN @ PU) sponge with great oil–water separation performance. Appl Surf Sci 422:116–124

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was funded by National Research Foundation of Korea (NRF-2015R1A3A2066301).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Sunanda Roy or Jaehwan Kim.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 261 kb)

Supplementary material 2 (AVI 2169 kb)

Supplementary material 3 (AVI 878 kb)

Supplementary material 4 (AVI 3883 kb)

Supplementary material 5 (AVI 988 kb)

Supplementary material 6 (AVI 1092 kb)

Supplementary material 7 (AVI 2586 kb)

Supplementary material 8 (AVI 502 kb)

Supplementary material 9 (AVI 1017 kb)

Supplementary material 10 (AVI 1797 kb)

Supplementary material 11 (AVI 781 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Roy, S., Zhai, L., Van Hai, L. et al. One-step nanocellulose coating converts tissue paper into an efficient separation membrane. Cellulose 25, 4871–4886 (2018). https://doi.org/10.1007/s10570-018-1945-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10570-018-1945-6

Keywords

Navigation