Abstract
A superhydrophobic cotton fabric exhibiting excellent self-cleaning and antibacterial activity prepared by a facile, cost-effective method involving deposition of copper and stearic acid has been reported in this article. The surface morphology and microstructure of the modified fabric have been characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction analysis and X-ray photoelectron spectroscopy. The antibacterial activity of the as-prepared superhydrophobic textiles has been evaluated by the disc diffusion method using Gram-positive and Gram-negative microorganisms. Evaluation of the modified fabric by a simple washing method and immersion in media of various pH values revealed the durability of the superhydrophobic textiles. In view of the robustness of this technique, it is certain that textiles with the dual functionalities of superhydrophobicity and antibacterial activity could be developed by this method and exploited in application domains in the years to come.
Similar content being viewed by others
References
Afzal S, Daoud WA, Langford SJ (2014) Superhydrophobic and photocatalytic self-cleaning cotton. J Mater Chem A 2:18005–18011. doi:10.1039/c4ta02764g
Alomayria T, Assaedia H, Shaikhc FUA, Lowa IM (2014) Effect of water absorption on the mechanical properties of cotton fabric-reinforced geopolymer composites. J Asian Ceram Soc 2:223–230. doi:10.1016/j.jascer.2014.05.005
Barthwal S, Kim YS, Lim S-H (2013) Mechanically robust superamphiphobic aluminum surface with nanopore-embedded microtexture. Langmuir 29:11966–11974. doi:10.1021/la402600h
Brown PS, Bhushan B (2015) Mechanically durable, superoleophobic coatings prepared by layer-by-layer technique for anti-smudge and oil-water separation. Sci Rep 5:8701. doi:10.1038/srep08701
Chang S, Slopek RP, Condon B, Grunlan JC (2014) Surface coating for flame-retardant behavior of cotton fabric using a continuous layer-by-layer process. Ind Eng Chem Res 53:3805–3812. doi:10.1021/ie403992x
Duan W, Xie A, Shen Y, Wang X, Wang F, Zhang Y, Li J (2011) Fabrication of superhydrophobic cotton fabrics with UV protection based on CeO2 Particles. Ind Eng Chem Res 50:4441–4445. doi:10.1021/ie101924v
Kenawy E-R, Abdel-Hay FI, El- Shanshoury AE-RR, El-Newehy MH (1998) Biologically active polymers: synthesis and antimicrobial activity of modified glycidyl methacrylate polymers having a quaternary ammonium and phosphonium groups. J Control Release 50:145–152. doi:10.1016/s0168-3659(97)00126-0
Li X-M, Reinhoudt D, Crego-Calama M (2007) What do we need for a superhydrophobic surface? A review on the recent progress in the preparation of superhydrophobic surfaces. Chem Soc Rev 36:1350–1368. doi:10.1039/b602486f
Li L, Breedveld V, Hess DW (2012) Creation of superhydrophobic stainless steel surfaces by acid treatments and hydrophobic film deposition. ACS Appl Mater Interfaces 4:4549–4556. doi:10.1021/am301666c
Li J, Yan L, Zhao Y, Zha F, Wang Q, Lei Z (2015) One-step fabrication of robust fabrics with both-faced superhydrophobicity for the separation and capture of oil from water. Phys Chem Chem Phys 17:6451–6457. doi:10.1039/c5cp00154d
Liu Y, Liu Y, Hu H, Liu Z, Pei X, Yu B, Yan P, Zhou F (2015) Mechanically induced self-healing superhydrophobicity. J Phys Chem C 119:7109–7114. doi:10.1021/jp5120493
Mahltig B, Haufe H, Bottcher H (2005) Functionalisation of textiles by inorganic sol–gel coatings. J Mater Chem 15:4385–4398. doi:10.1039/b505177k
Meghana S, Kabra P, Chakraborty S, Padmavathy N (2015) Understanding the pathway of antibacterial activity of copper oxide nanoparticles. RSC Adv 5:12293–12299. doi:10.1039/c4ra12163e
Mei L, Zhang X, Wang Y, Zhang W, Lu Z, Luo Y, Zhao Y, Li C (2014) Multivalent polymer–Au nanocomposites with cationic surfaces displaying enhanced antimicrobial activity. Polym Chem 5:3038–3044. doi:10.1039/c3py01578e
Mondal B, Eain MMG, Xu QF, Egan VM, Punch J, Lyons AM (2015) Design and fabrication of a hybrid superhydrophobic-hydrophilic surface that exhibits stable dropwise condensation. ACS Appl Mater Interfaces 7:23575–23588. doi:10.1021/acsami.5b06759
Nam S, French AD, Condon BD, Concha M (2016) Segal crystallinity index revisited by the simulation of X-ray diffraction patterns of cotton cellulose Iβ and cellulose II. Carbohydr Polym 135:1–9
Parthasarathi V, Charmini B (2015) Development of Dual Finished Surgical Gown. Int J Pharm Tech Res 8: 924–927. ISSN: 0974-4304
Sahoo BN, Kandasubramanian B (2014) Recent progress in fabrication and characterization of hierarchical biomimetic superhydrophobic structures. RSC Adv 4:22053–22093. doi:10.1039/c4ra00506f
Sasaki K, Tenjimbayashi M, Manabe K, Shiratori S (2015) Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles. ACS Appl Mater Interfaces 8:651–659. doi:10.1021/acsami.5b09782
Sasmal AK, Mondal C, Sinha AK, Gauri SS, Pal J, Aditya T, Ganguly M, Dey S, Pal T (2014) Fabrication of superhydrophobic copper surface on various substrates for roll-off, self-cleaning, and water/oil separation. ACS Appl Mater Interfaces 6:22034–22043. doi:10.1021/am5072892
Sawai J (2003) Quantitative evaluation of antibacterial activities of metallic oxide powders (ZnO, MgO and CaO) by conductimetric assay. J Microbiol Methods 54:177–182. doi:10.1016/S0167-7012(03)00037-X
Shafei AE, Abou-Okeil A (2011) ZnO/carboxymethyl chitosan bionano-composite to impart antibacterial and UV protection for cotton fabric. Carbohydr Polym 83:920–925. doi:10.1016/j.carbpol.2010.08.083
Shateri-Khalilabad M, Yazdanshenas ME (2013) Fabrication of superhydrophobic, antibacterial, and ultraviolet-blocking cotton fabric. J Text Inst 104:861–869. doi:10.1080/00405000.2012.761330
Thiligavathi G, Kannaian T (2008) Dual antimicrobial and blood repellent finishes for cotton hospital fabrics. Indian J Fibre Text 33:23–29
Wang L, Zhang X, Li B, Sun P, Yang J, Xu H, Liu Y (2011) Superhydrophobic and ultraviolet-blocking cotton textiles. ACS Appl Mater Interfaces 3:1277–1281. doi:10.1021/am200083z
Wu J, Li J, Deng B, Jiang H, Wang Z, Yu M, Li L, Xing C, Li Y (2013) Self-healing of the superhydrophobicity by ironing for the abrasion durable superhydrophobic cotton fabrics. Sci Rep 3:2951. doi:10.1038/srep02951
Xiao F, Yuan S, Liang B, Li G, Pehkonen SO, Zhang T (2015) Superhydrophobic CuO nanoneedle-covered copper surfaces for anticorrosion. J Mater Chem A 3:4374–4388. doi:10.1039/c4ta05730a
Xu L, Geng Z, He J, Zhou G (2014) Mechanically robust, thermally stable, broadband antireflective, and superhydrophobic thin films on glass substrates. ACS Appl Mater Interfaces 6:9029–9035. doi:10.1021/am5016777
Zhang J, Li B, Wu L, Wang A (2013) Facile preparation of durable and robust superhydrophobic textiles by dip coating in nanocomposite solution of organosilanes. Chem Commun 49:11509–11511. doi:10.1039/c3cc43238f
Zhang M, Zang D, Shi J, Gao Z, Wang C, Li J (2015) Superhydrophobic cotton textile with robust composite film and flame retardancy. RSC Adv 5:67780–67786. doi:10.1039/c5ra09963c
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Suryaprabha, T., Sethuraman, M.G. Fabrication of copper-based superhydrophobic self-cleaning antibacterial coating over cotton fabric. Cellulose 24, 395–407 (2017). https://doi.org/10.1007/s10570-016-1110-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-016-1110-z