Abstract
Flax and hemp fibres were treated by various combinations of water/diluted alkaline solution and stirring/ultrasound, respectively. Changes in the microstructure (scanning electron microscopy) and porous structure (low-temperature nitrogen adsorption), removal of non-cellulosic materials (weight loss, FTIR), mean fibre diameter, and adhesion of the polypropylene matrix to the fibres (micro-bond test) were investigated. For both types of fibres, removal of (FTIR) was observed. The fibre diameter of hemp was decreased by several treatments, most of all by stirring in alkali and subsequent sonication in water, while the ultrasound applied in alkali solution did not change the fibre fineness. This can be attributed to the dual effect of ultra-sonication: the swelling effect of alkali combined with ultrasound energy probably served the sticking of inter-fibrillar material rather than their dissolution. Fibre diameter of flax did not change in any circumstances. The porosity of hemp in the mesopore range increased, while that of flax decreased by alkali treatment and subsequent sonication. The reason for this difference might be the dissimilar cell wall structures of the two bast fibres, the high arabinose content of the hemp, and/or the cottonisation of hemp. No treatments altered the fibre-matrix adhesion measured by pulling out the fibre from a micro-droplet of polypropylene.
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Abramova A, Gedanken A, Popov V, Ooi E-H, Mason TJ, Joyce EM, Beddow J, Perelshtein I, Bayazitov V (2013) A sonochemical technology for coating of textiles with antibacterial nanoparticles and equipment for its implementation. Mater Lett 96:121–124. doi:10.1016/j.matlet.2013.01.041
Aimin T, Hongwei Z, Gang C, Guohui X, Wenzhi L (2005) Influence of ultrasound treatment on accessibility and regioselective oxidation reactivity of cellulose. Ultrason Sonochem 12:467–472. doi:10.1016/j.ultsonch.2004.07.003
Alemdar A, Sain M (2008) Isolation and characterization of nanofibers from agricultural residues—Wheat straw and soy hulls. Bioresour Technol 99:1664–1671. doi:10.1016/j.polymertesting.2011.10.007
Amaducci S, Scordia D, Liu FH, Zhang Q, Guo H, Testa G, Cosentino SL (2015) Key cultivation techniques for hemp in Europe and China. Ind Crop Prod 68:2–16. doi:10.1016/j.indcrop.2014.06.041
Anandjiwala RD, Bogoslavsky L (2008) Development of needle-punched nonwoven fabrics from flax fibers for air filtration applications. Text Res J 78:614–624. doi:10.1177/0040517507081837
Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380. doi:10.1021/ja01145a126
Barth M, Carus M (2015) Carbon footprint and sustainability of different natural fibres for biocomposites and insulation material. Bio-based Economy, Services of Nova-Institute www.bio-based.eu/ecology. Accessed 18 Aug 2015
Batra SK (2007) Other long vegetable fibers: abaca, banana, sisal, henequen, flax, ramie, hemp, sunn, and coir. In: Lewin M (ed) Handbook of fiber chemistry, 3rd edn. CRC Press, Boca Raton, pp 464–479
Benli H, Bahtiyari MI (2015) Use of ultrasound in biopreparation and natural dyeing of cotton fabric in a single bath. Cellulose 22:867–877. doi:10.1007/s10570-014-0494-x
Chandra RP, Arantes V, Saddler J (2015) Steam pretreatment of agricultural residues facilitates hemicellulose recovery while enhancing enzyme accessibility to cellulose. Bioresour Technol 185:302–307. doi:10.1016/j.biortech.2015.02.106
Davulcu A, Eren HA, Avinc O, Erişmiş B (2014) Ultrasound assisted biobleaching of cotton. Cellulose 21:2973–2981. doi:10.1007/s10570-014-0273-8
Entezari MH, Al-Hoseini ZS (2007) Sono-sorption as a new method for the removal of methylene blue from aqueous solution. Ultrason Sonochem 14:599–604. doi:10.1016/j.ultsonch.2006.10.004
Eriksson I, Haglind I, Lidbrandt O, Salmén L (1991) Fiber swelling favoured by lignin softening. Wood Sci Technol 25:135–144. doi:10.1007/BF00226813
Espinal-Ruiz M, Restrepo-Sanchez L-P, Narvaez-Cuenca C-E, McClements DJ (2016) Impact of pectin properties on lipid digestion under simulated gastrointestinal conditions: comparison of citrus and banana passion fruit (Passiflora tripartita var. mollissima) pectins. Food Hydrocoll 52:329–342. doi:10.1016/j.foodhyd.2015.05.042
Fages E, Cano MA, Gironés S, Boronat T, Fenollar O, Balart R (2013) The use of wet-laid techniques to obtain flax nonwovens with different thermoplastic binding fibers for technical insulation applications. Text Res J 83:426–437. doi:10.1177/0040517512454183
Gadhe JB, Gupta RB, Elder T (2006) Surface modification of lignocellulosic fibers using high-frequency ultrasound. Cellulose 13:9–22. doi:10.1007/s10570-005-9018-z
Gaur U, Miller B (1989) Microbond method for determination of the shear strength of a fiber/resin interface: evaluation of experimental parameters. Compos Sci Technol 34:35–51
Gouveia IC, Dias LP, Fiadeiro JM, Queiroz JA (2010) Enzymatic treatments to improve the dyeability of linen fabrics: optimization and empirical modeling using experimental design techniques. Text Res J 80:1602–1615. doi:10.1177/0040517510363186
Hebeish A, Sharaf S, Abd El-Hady MM (2011) Ultrasound aided KMnO4-acid systems for bleaching linen fabric. Carbohydr Polym 83:1370–1376. doi:10.1016/j.carbpol.2010.09.052
Huang X, Netravali A (2007) Characterization of flax fiber reinforced soy protein resin based green composites modified with nano-clay particles. Compos Sci Technol 67:2005–2014. doi:10.1016/j.compscitech.2007.01.007
Jianyong F, Jianchun Z (2013) Oil filtration performance of a hemp/cotton spunlaced nonwoven. Text Res J 83:2191–2203. doi:10.1177/0040517513490058
Jinqiu Z, Jianchun Z (2010) Effect of refined processing on the physical and chemical properties of hemp bast fibers. Text Res J 80:744–753. doi:10.1177/0040517509342317
Kačuráková M, Capek P, Sasinková V, Wellner N, Ebringerová A (2000) FT-IR study of plant cell wall model compounds: pectic polysaccharides and hemicelluloses. Carbohydr Polym 43:195–203. doi:10.1016/S0144-8617(00)00151-X
Khajavi R, Atlasi A, Yazdanshenas M-E (2013) Alkali treatment of cotton yarns with ultrasonic bath. Text Res J 83:827–835. doi:10.1177/0040517512467077
Kim JT, Netravali AN (2011) Development of aligned-hemp yarn-reinforced green composites with soy protein resin: effect of pH on mechanical and interfacial properties. Compos Sci Technol 71:541–547. doi:10.1016/j.compscitech.2011.01.004
Kyzas GZ, Terzopoulou Z, Nikolaidis V, Alexopoulou E, Bikiaris DN (2015) Low-cost hemp biomaterials for nickel ions removal from aqueous solutions. J Mol Liq 209:209–218. doi:10.1016/j.molliq.2015.05.060
Latif E, Tucker S, Ciupala MA, Wijeyesekera DC, Newport D (2014) Hygric properties of hemp bio-insulations with differing compositions. Constr Build Mater 66:702–711. doi:10.1016/j.conbuildmat.2014.06.021
Lee KW, Kim JP (2001) Effect of ultrasound on disperse dye particle size. Text Res J 71:395–398. doi:10.1177/004051750107100505
Łojewska J, Miśkowiec P, Łojewski T, Proniewicz LM (2005) Cellulose oxidative and hydrolytic degradation: in situ FTIR approach. Polym Degrad Stab 88:512–520. doi:10.1016/j.polymdegradstab.2004.12.012
Mason TJ (1999) Sonochemistry. Oxford University Press, Oxford, p 9
Miao C, Hamad WY (2013) Cellulose reinforced polymer composites and nanocomposites: a critical review. Cellulose 20:2221–2262. doi:10.1007/s10570-013-0007-3
Miao M, Pierlot AP, Millington K, Gordon SG, Best A, Clarke M (2013) Biodegradable mulch fabric by surface fibrillation and entanglement of plant fibers. Text Res J 83:1906–1917. doi:10.1177/0040517513483861
Miller B, Muri P, Rebenfeld L (1987) A microbond method for determination of the shear strength of a fiber/resin interface. Compos Sci Technol 28:17–32
Miller B, Gaur U, Hirt DE (1991) Measurement and mechanical aspects of the microbond pull-out technique for obtaining fiber/resin interfacial shear strength. Compos Sci Technol 42:207–219
Moholkar VS, Warmoeskerken MMCG (2003) Acoustical characteristics of textile materials. Text Res J 73:827–837. doi:10.1177/004051750307300914
Moriana R, Vilaplana F, Karlsson S, Ribes A (2014) Correlation of chemical, structural and thermal properties of natural fibres for their sustainable exploitation. Carbohydr Polym 112:422–431. doi:10.1016/j.carbpol.2014.06.009
Morlin B, Czigány T (2012) Cylinder test: development of a new microbond method. Polym Test 31:164–170. doi:10.1016/j.polymertesting.2011.10.007
Muzyczek M (2012) The use of flax and hemp for textile applications. In: Kozłowski RM (ed) Handbook of natural fibres, vol 2., Processing and applicationWoodhead Publishing Ltd, Oxford, pp 312–328
Pappas C, Tarantilis PA, Daliani I, Mavromoustakos T, Polissiou M (2002) Comparison of classical and ultrasound-assisted isolation procedures of cellulose from kenaf (Hibiscus cannabinus L.) and eucalyptus (Eucalyptus rodustrus Sm.). Ultrason Sonochem 9:19–23. doi:10.1016/j.carbpol.2012.02.052
Rehman MSU, Rashid N, Saif A, Mahmood T, Han J (2013) Potential of bioenergy production from industrial hemp (Cannabis sativa): Pakistan perspective. Renew Sustain Energy Rev 18:154–164. doi:10.1016/j.rser.2012.10.019
Renouard S, Hano C, Doussot J, Blondeau J-Ph, Lainé E (2014) Characterization of ultrasonic impact on coir, flax and hemp fibers. Mater Lett 129:137–141. doi:10.1016/j.matlet.2014.05.018
Roelofsen PA (1951) Contradictory data on spiral structures in the secondary cell wall of fibers of flax, hemp, and ramie. Text Res J 21:412–418. doi:10.1177/004051755102100605
Schwartz P (2001) Measuring interface strength in composite materials. In: Pastore CM, Kiekens P (eds) Surface characteristics of fibers and textiles. Marcel Dekker, New York, pp 219–233
Silveira RL, Stoyanov SR, Gusarov S, Skaf MS, Kovalenko A (2013) Plant biomass recalcitrance: effect of hemicellulose composition on nanoscale forces that control cell wall strength. J Am Chem Soc 135:19048–19051. doi:10.1021/ja405634k
Sun RC, Tomkinson J, Wang YW, Xiao B (2000) Physico-chemical and structural characterization of hemicelluloses from wheat straw by alkaline peroxide extraction. Polymer 41:2647–2656. doi:10.1016/S0032-3861(99)00436-X
Surina R, Andrassy M (2013) Effect of preswelling and ultrasound treatment on the properties of flax fibers cross-linked with polycarboxylic acids. Text Res J 83:66–75. doi:10.1177/0040517512452928
Tonoli GHD, Teixeira EM, Corrêa AC, Marconcini JM, Caixeta LA, Pereira-da-Silva MA, Mattoso LHC (2012) Cellulose micro/nanofibres from Eucalyptus kraft pulp: preparation and properties. Carbohydr Polym 89:80–88. doi:10.1016/j.carbpol.2012.02.052
Wells T Jr, Kosa M, Ragauskas AJ (2013) Polymerization of Kraft lignin via ultrasonication for high-molecular-weight applications. Ultrason Sonochem 20:1463–1469. doi:10.1016/j.ultsonch.2013.05.001
Xu F, Yu J, Tesso T, Wang D (2013) Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: a mini-review. Appl Energy 104:801–809. doi:10.1016/j.apenergy.2012.12.019
Acknowledgments
The authors would like to thank Ms. Kinga Simon for the valuable fibre treatments and Mr. György Bosznai for the nitrogen adsorption measurements. The authors also thank Prof. Tibor Czigány and Dr. Bálint Morlin for their valuable help in the micro-bond test and the CHT/Bezema AG (Switzerland) for kindly providing chemicals.
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Borsa, J., László, K., Boguslavsky, L. et al. Effect of mild alkali/ultrasound treatment on flax and hemp fibres: the different responses of the two substrates. Cellulose 23, 2117–2128 (2016). https://doi.org/10.1007/s10570-016-0909-y
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DOI: https://doi.org/10.1007/s10570-016-0909-y