Abstract
This work proposes the use of eucalyptus pulp as an adsorbent for biodiesel purification. Methyl sunflower biodiesel was produced by alkaline transesterification and passed through a column containing the adsorbent. The evaluated impurities were free glycerol, methanol, water content and alkali metals (Na+, K+, Ca2+ and Mg2+). The cellulose fibers were fractionated by sieving in three fractions (sieve pore sizes of 500, 600 and 1,180 μm). The pulp was characterized by infrared, x-ray diffraction, viscosimetric molecular weight, water content, morphological analysis and fiber content of α-cellulose and hemicelluloses. The size of fibers, mass of adsorbent (0.2 and 1.0 g), column diameter (1.0 and 1.3 cm) and the aid of pressure for filtration (atmospheric or 18 psi) on the impurities removal were also evaluated. The physicochemical characterization of biodiesel was performed following tests in accordance with the limits set by the European Standard for oxidative stability at 110 °C, density at 20 °C, water content, acid value, free glycerol, kinematic viscosity at 40 °C, and residual methanol. The optimal condition was observed using 1.0 g of cellulose in a column of 1.3 cm in diameter under pressure of 18 psi was applied. In this condition the free glycerol, methanol and water content in the permeate presented values of 0.0081 ± 0.0001, 0.268 ± 0.009 % w/w and 636 mg kg−1, respectively. The results indicate that this cellulosic adsorbent is a promising material for biodiesel purification instead of using water washing, avoiding the generation of high wastewater volumes.
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References
Abidi N, Cabrales L, Haigler CH (2014) Changes in the cell wall and cellulose content of developing cotton fibers investigated by FTIR spectroscopy. Carbohydr Polym 100:9–16. doi:10.1016/j.carbpol.2013.01.074
Alila S, Boufi S (2009) Removal of organic pollutants from water by modified cellulose fibres. Ind Crops Prod 30:93–104. doi:10.1016/j.indcrop.2009.02.005
Alves MJ, Nascimento SM, Pereira IG, Martins MI, Cardoso VL, Reis M (2013) Biodiesel purification using micro and ultrafiltration membranes. Renew Energy 58:15–20. doi:10.1016/j.renene.2013.02.035
Atadashi IM, Aroua MK, Aziz ARA, Sulaiman NMN (2011) Refining technologies for the purification of crude biodiesel. Appl Energy 88:4239–4251. doi:10.1016/j.apenergy.2011.05.029
Atadashi IM, Aroua MK, Abdul Aziz AR, Sulaiman NMN (2012) High quality biodiesel obtained through membrane technology. J Memb Sci 421–422:154–164. doi:10.1016/j.memsci.2012.07.006
Berrios M, Skelton RL (2008) Comparison of purification methods for biodiesel. Chem Eng J 144:459–465. doi:10.1016/j.cej.2008.07.019
Bousher A, Shen X, Edyvean RGJ (1997) Removal of coloured organic matter by adsorption onto low-cost waste materials. Water Res 31:2084–2092. doi:10.1016/S0043-1354(97)00037-7
Çaylı G, Küsefoğlu S (2008) Increased yields in biodiesel production from used cooking oils by a two step process: comparison with one step process by using TGA. Fuel Process Technol 89:118–122. doi:10.1016/j.fuproc.2007.06.020
da Silva Filho EC, de Melo JCP, Airoldi C (2006) Preparation of ethylenediamine-anchored cellulose and determination of thermochemical data for the interaction between cations and basic centers at the solid/liquid interface. Carbohydr Res 341:2842–2850. doi:10.1016/j.carres.2006.09.004
Dantas MB et al (2011) Evaluation of the oxidative stability of corn biodiesel. Fuel 90:773–778. doi:10.1016/j.fuel.2010.09.014
Faccini CS et al (2011) Dry washing in biodiesel purification: a comparative study of adsorbents. J Braz Chem Soc 22:558–563. doi:10.1590/S0103-50532011000300021
Fadhil AB, Dheyab MM, Abdul-Qader A-QY (2012) Purification of biodiesel using activated carbons produced from spent tea waste. J Assoc Arab Univ Basic and Appl Sci 11:45–49. doi:10.1016/j.jaubas.2011.12.001
Fernandes DM, Serqueira DS, Portela FM, Assunção RMN, Munoz RAA, Terrones MGH (2012) Preparation and characterization of methylic and ethylic biodiesel from cottonseed oil and effect of tert-butylhydroquinone on its oxidative stability. Fuel 97:658–661. doi:10.1016/j.fuel.2012.01.067
Fracassi da Silva JA, do Lago CL (1998) An oscillometric detector for capillary electrophoresis. Anal Chem 70:4339–4343. doi:10.1021/ac980185g
Francisco KJ, do Lago CL (2009) A compact and high-resolution version of a capacitively coupled contactless conductivity detector. Electrophoresis 30:3458–3464. doi:10.1002/elps.200900080
French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. doi:10.1007/s10570-013-0030-4
Gerpen JV (2005) Biodiesel processing and production. Fuel Process Technol 86:1097–1107. doi:10.1016/j.fuproc.2004.11.005
Gomes MCS, Pereira NC, Barros STDD (2010) Separation of biodiesel and glycerol using ceramic membranes. J Memb Sci 352:271–276. doi:10.1016/j.memsci.2010.02.030
Gomes MCS, Arroyo PA, Pereira NC (2013) Influence of acidified water addition on the biodiesel and glycerol separation through membrane technology. J Memb Sci 431:28–36. doi:10.1016/j.memsci.2012.12.036
Gonçalves Filho LC, Micke GA (2007) Development and validation of a fast method for determination of free glycerol in biodiesel by capillary electrophoresis. J Chromatogr A 1154:477–480. doi:10.1016/j.chroma.2007.04.063
Gonzalo A, García M, Luis Sánchez J, Arauzo JS, Peña JA (2010) Water cleaning of biodiesel. Effect of catalyst concentration, water amount, and washing temperature on biodiesel obtained from rapeseed oil and used oil. Ind Eng Chem Res 49:4436–4443. doi:10.1021/ie901707q
Grunin YB, Grunin LY, Nikol’skaya EA, Talantsev VI, Gogelashvili GS (2013) Features of the sorption of water vapor and nitrogen on cellulose. Russ J Phys Chem 87:100–103. doi:10.1134/S0036024413010093
Heinze T, Liebert T (2001) Unconventional methods in cellulose functionalization. Prog Polym Sci 26:1689–1762. doi:10.1016/S0079-6700(01)00022-3
Jain S, Sharma MP (2013) Effect of metal contaminants and antioxidants on the storage stability of Jatropha curcas biodiesel. Fuel 109:379–383. doi:10.1016/j.fuel.2013.03.050
Karaosmanoğlu F, Cığızoğlu KB, Tüter M, Ertekin S (1996) Investigation of the refining step of biodiesel production. Energy Fuels 10:890–895. doi:10.1021/ef9502214
Kouzu M, Hidaka J-S (2013) Purification to remove leached CaO catalyst from biodiesel with the help of cation-exchange resin. Fuel 105:318–324. doi:10.1016/j.fuel.2012.06.019
Lazarin AM, Borgo CA, Gushikem Y, Kholin YV (2003) Aluminum phosphate dispersed on a cellulose acetate fiber surface: preparation, characterization and application for Li+, Na+ and K+ separation. Anal Chim Acta 477:305–313. doi:10.1016/S0003-2670(02)01420-4
Lin H, Haagenson DM, Wiesenborn DP, Pryor SW (2011) Effect of trace contaminants on cold soak filterability of canola biodiesel. Fuel 90:1771–1777. doi:10.1016/j.fuel.2011.01.029
Mittelbach M, Roth G, Bergmann A (1996) Simultaneous gas chromatographic determination of methanol and free glycerol in biodiesel. Chromatographia 42:431–434. doi:10.1007/BF02272135
Nogueira T, Lago CLD (2011) Determination of Ca, K, Mg, Na, sulfate, phosphate, formate, acetate, propionate, and glycerol in biodiesel by capillary electrophoresis with capacitively coupled contactless conductivity detection. Microchem J 99:267–272. doi:10.1016/j.microc.2011.05.014
Rahimi M, Aghel B, Alitabar M, Sepahvand A, Ghasempour HR (2014) Optimization of biodiesel production from soybean oil in a microreactor. Energy Convers Manag 79:599–605. doi:10.1016/j.enconman.2013.12.065
Ribeiro APB, de Moura JMLN, Gonçalves LAG, Petrus JCC, Viotto LA (2006) Solvent recovery from soybean oil/hexane miscella by polymeric membranes. J Memb Sci 282:328–336. doi:10.1016/j.memsci.2006.05.036
Richter EM, Jesus DPD, Muñoz RAA, Lago CLD, Angnes L (2005) Determination of anions, cations, and sugars in coconut water by capillary electrophoresis. J Braz Chem Soc 16:1134–1139. doi:10.1590/S0103-50532005000700008
Saleh J, Tremblay AY, Dubé MA (2010) Glycerol removal from biodiesel using membrane separation technology. Fuel 89:2260–2266. doi:10.1016/j.fuel.2010.04.025
Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the x-ray diffractometer. Text Res J 29:786–794. doi:10.1177/004051755902901003
Serqueira DS, Fernandes DM, Cunha RR, Squissato AL, Santos DQ, Richter EM, Munoz RAA (2014) Influence of blending soybean, sunflower, colza, corn, cottonseed, and residual cooking oil methyl biodiesels on the oxidation stability. Fuel 118:16–20. doi:10.1016/j.fuel.2013.10.028
Siler-Marinkovic S, Tomasevic A (1998) Transesterification of sunflower oil in situ. Fuel 77:1389–1391. doi:10.1016/S0016-2361(98)00028-3
Talebian-Kiakalaieh A, Amin NAS, Mazaheri H (2013) A review on novel processes of biodiesel production from waste cooking oil. Appl Energy 104:683–710. doi:10.1016/j.apenergy.2012.11.061
Tomasevic AV, Siler-Marinkovic SS (2003) Methanolysis of used frying oil. Fuel Process Technol 81:1–6. doi:10.1016/S0378-3820(02)00096-6
Wan J, Wang Y, Xiao Q (2010) Effects of hemicellulose removal on cellulose fiber structure and recycling characteristics of eucalyptus pulp. Bioresour Technol 101:4577–4583. doi:10.1016/j.biortech.2010.01.026
Wang X, Xing B (2007) Sorption of organic contaminants by biopolymer-derived chars. Environ Sci Technol 41:8342–8348. doi:10.1021/es071290n
Wang Y, Wang X, Liu Y, Ou S, Tan Y, Tang S (2009) Refining of biodiesel by ceramic membrane separation. Fuel Process Technol 90:422–427. doi:10.1016/j.fuproc.2008.11.004
Acknowledgments
The authors are grateful to FAPEMIG (APQ-01537-14), CNPq (308174/2013-5 and 481086/2012-9) and CAPES for the financial support.
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Squissato, A.L., Fernandes, D.M., Sousa, R.M.F. et al. Eucalyptus pulp as an adsorbent for biodiesel purification. Cellulose 22, 1263–1274 (2015). https://doi.org/10.1007/s10570-015-0557-7
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DOI: https://doi.org/10.1007/s10570-015-0557-7