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Ionic strength effects on the microstructure and shear rheology of cellulose nanocrystal suspensions

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Abstract

The effect of ionic strength on the rheology and microstructure of Cellulose nanocrystals (CNC) aqueous suspensions are studied over a broad range of CNC (3–15 wt%) and NaCl concentrations (0–15 mM), using polarized optical microscopy combined with rheometry. The CNC suspensions are isotropic at low concentration and form chiral nematic liquid crystalline structure above a first critical concentration and gel above a second critical one. It has been shown that for isotropic CNC suspensions, increasing the ionic strength of the system up to 5 mM NaCl concentration weakens the electro-viscous effects and thus reduces the viscosity of these suspensions. For biphasic samples, which contain chiral nematic liquid crystal domains, increasing the ionic strength up to 5 mM NaCl concentration decreases the size of the chiral nematic domains, and leads the viscosity of the samples at low shear rates to increase. On the other hand, at high shear rates, where all the ordered domains are broken, the viscosity decreases with NaCl addition. For gels, the addition of NaCl up to 5 mM weakens the gel structure and decreases the viscosity. Further addition of NaCl (10 and 15 mM NaCl concentrations) results in extensive aggregation and de-stabilizes the CNC suspensions.

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Acknowledgments

The authors would like to acknowledge NSERC and FPInnovations for financial support under grant CRD-379851-2008.

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Authors and Affiliations

  1. Chemical and Biological Engineering, The University of British Columbia, Vancouver, BC, V6T 1Z3, Canada

    S. Shafiei-Sabet & S. G. Hatzikiriakos

  2. Biomaterials Group, FPInnovations, 3800 Wesbrook Mall, Vancouver, BC, V6S 2L9, Canada

    W. Y. Hamad

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  1. S. Shafiei-Sabet
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  2. W. Y. Hamad
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  3. S. G. Hatzikiriakos
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Correspondence to W. Y. Hamad or S. G. Hatzikiriakos.

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Shafiei-Sabet, S., Hamad, W.Y. & Hatzikiriakos, S.G. Ionic strength effects on the microstructure and shear rheology of cellulose nanocrystal suspensions. Cellulose 21, 3347–3359 (2014). https://doi.org/10.1007/s10570-014-0407-z

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  • DOI: https://doi.org/10.1007/s10570-014-0407-z

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