Abstract
Thermal storage cotton possessing solid–solid phase change properties was prepared by direct grafting of polyethylene glycol (PEG) on cotton fiber/cloth. Attempt has been made to characterize intermediates so that desired grafting could be obtained. The grafting was done by using urethane linkage and the grafted cotton was found to undergo solid–solid phase transition. The modified cotton was characterized by using Fourier transform infrared spectroscopy (FT-IR), 13C CPMAS, polarizing optical microscopy, differential scanning calorimetry (DSC) and thermogravimetry respectively. The DSC study revealed quite good storage effect of grafted cotton and the enthalpy of melting was found to be 55–59 J/g with a peak appearing at around 60 °C. During cooling scan, the crystallization peak appeared at around 38 °C. Further, thermogravimetric analysis confirmed good thermal stability up to 300 °C. Appreciable improvement of mechanical properties of cotton has been observed after grafting. The polarizing optical micrograph clearly showed change of morphology after grafting, i.e., the grafted PEG adhering to fiber surface.
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References
Alkan C, Sari A (2008) Fatty acid/poly(methyl methacrylate) (PMMA)blends as form-stable phase change materials for latent heat thermal energy storage. Sol Energy 82:118–124
Alper AA, Hasancan O (2011) High-chain fatty acid esters of myristyl alcohol with even carbon number: novel organic phase change materials for thermal energy storage-1. Sol Energy Mater Sol Cells 95:2752–2762
Bruno JS, Danna GF, Frost CM, Vigo TL (1989) Temperature adaptable textile fibers and method of preparing same. US 4(851):291
Bruno JS, Danna GF, Vigo TL, Zimmerman CM (1990) Temperature adaptable textile fibers and method of preparing same US 4908238A
Cao Q, Liu P (2006) Hyperbranched polyurethane as novel solid–solid phase change material for thermal energy storage. Eur Polymer J 42(11):2931–2939
Chen C, Liu W, Yang H, Zhao Y, Liu S (2011) Synthesis of solid–solid phase change material for thermal energy storage by cross linking of polyethylene glycol with poly(glycidyl methacrylate). Sol Energy 85:2679–2685
Clarksean RL (2006) Phase-change material (PCM) system and methods for shifting peak electrical load. US Patent 7096929
Collier BJ, Epps HH (1999) Textile testing and analysis. Prentice Hall, New Jersey
Dragunski DC, Pawlicka A (2001) Preparation and characterization of starch grafted with toluene poly (propylene oxide) Diisocyanate, Mater Res 4
Hale DV, Hoover MJ, O.Neill MJ (1971) Phase change materials handbook. Report No. HREC-5183-LMSCHREC D225138. NASA, Marshal Space Flight Centre. Alabama
Harlan SL (1991) ACS Symposium Series 457:248
Hasan A, McCormack SJ, Huang MJ, Norton B (2010) Evaluation of phase change materials for thermal regulation enhancement of building integrated photovoltaics. Sol Energy 84(9):1601–1612
Hawes DW, Banu D, Feldman D (1990) Latent heat storage in concrete II. Sol Energy Mater 21(1):61–80
Hu J (2008) Fabric testing, Woodhead Publishing Series in Textiles: Number 76
Jiang Y, Ding EY, Li GK (2002) Study on transition characteristics of PEG/CDA solid–solid phase change materials. Polymer 43:117–122
Kadolph SJ (2007) Quality assurance for textiles and apparel, Fairchild Publication, New York. ISBN: 156367-144-1
Kaizawa A, Kamano H, Kawai A, Jozuka T, Senda T, Maruoka N, Okinaka N, Akiyama T (2008) Technical feasibility study of waste heat transportation system using phase change material from industry to city. ISIJ Int 48:540–548
Ke GZ, Xie HF, Ruan RP (2010) Preparation and performance of porous phase change polyethylene glycol/polyurethane membrane. Energy Conserv Manag 51:2294–2298
Kenisarin M, Mahkamov K (2007) Solar energy storage using phase change materials. Renew Sustain Energy Rev 11(9):1913–1965
Li WD, Ding EY (2007) Preparation and characterization of cross-linking PEG/MDI/PE copolymer as solid–solid phase change heat storage material. Solar Energy Mater Solar Cells 91:764–768
Li Y, Liu R, Huang Y (2008) Synthesis and phase transition of cellulose-graft-poly(ethylene glycol) copolymers. J Appl Polym Sci 110:1797–1803
Li Y, Wu M, Liu R, Huang Y (2009) Cellulose-based solid–solid phase change materials synthesized in ionic liquid. Sol Energy Mater Sol Cells 93:1321–1328
Liang XH, Guo YQ (1995) Crystalline–amorphous phase transition of a poly(ethylene glycol)/cellulose blend. Macromolecules 28:6551–6555
Marand A, Dahlin J, Karlsson D, Gunnar S, Marianne D (2004) Determination of technical grade isocyanates used in the production of polyurethane plastics. J Environ Monit 6(7):606–614
Marco B, Wim VH, Andreas H (2009) Materials for compact thermal energy storage: A new IEA joint SHC/ECES task. In 11th international conference on thermal energy storage; Effstock. June 14-17, Stockholm, Sweden
Mehling H, Cabeza LF (2008) Heat and cold storage with PCM. Hand book. Springer, Berlin
Meng Q, Hu J (2008) A poly (ethylene glycol)-based smart phase change material. Sol Energy Mater Sol Cells 92:1260–1268
Mondal S (2007) Phase change material for smart textiles—an overview. Appl Therm Eng 28(11–12):1536–1550
Okano T, Sarko A (1985) Mercerization of cellulose. II. Alkali–cellulose intermediates and a possible mercerization mechanism. J Appl Polym Sci 30:325–332
Rolle KC (2000) Heat and mass transfer. Prentice-Hall Inc., Upper Saddle River
Salaun F, Devaux E, Bourbigot S, Rumeau P (2010) Development of phase change material in clothing Pt I: formulation of microencapsulated phase change. Textile Res J 80:195–205
Sarı A, Cemil A, Alper B, Ali K (2011) Synthesis and thermal energy storage characteristics of polystyrene-graft-palmitic acid copolymers as solid–solid phase change materials. Sol Energy Mater Sol Cells 95(12):3195–3201
Shin Y, Yoo D-Il, Son K (2005) Development of thermoregulating textile materials with microencapsulated phase change materials (PCM). II. Preparation and application of PCM microcapsules. J Appl Polym Sci 96:2005–2010
Takahashi Y, Sakamoto R, Kamimoto M, Kanari K, Ozawa T (1981) Investigation of latent heat-thermal energy storage materials. I. Thermoanalytical evaluation of modified polyethylene. Thermochim Acta 50(1–3):31–39
Ullman AZ, Newman CD (2010) Phase-change cooling system. US Patent 0157525
Xi P, Duan Y, Fei P, Xia L, Liu R (2012a) Cheng Bowen, Synthesis and thermal energy storage properties of the polyurethane solid–solid phase change materials with a novel tetrahydroxy compound. Eur Polymer J 48:1295–1303
Xi P, Xia L, Fei P, Zhang D, Chenga B (2012b) Preparation and performance of a novel thermoplastics polyurethane solid–solid phase change materials for energy storage. Sol Energy Mater Sol Cells 102:36–43
Zhang M, Na Y, Jiang Z (2005) Preparation and properties of polymeric Solid–solid phase change materials of polyethylene glycol (PEG)/poly(vinyl alcohol) (PVA) copolymers by graft copolymerization. Chem J Chin Univ 26:170–174
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Kumar, A., Kulkarni, P.S. & Samui, A.B. Polyethylene glycol grafted cotton as phase change polymer. Cellulose 21, 685–696 (2014). https://doi.org/10.1007/s10570-013-0120-3
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DOI: https://doi.org/10.1007/s10570-013-0120-3