Abstract
Copper (Cu) and nitrogen (N) co-doped titanium dioxide (TiO2) loaded catalysts were synthesized through the sol–gel process. Butyl titanate was used as the precursor, while urea and blue vitriol served as the N and Cu sources, respectively. These materials were applied to foam ceramics using the dip-coating method, which was followed by a photocatalytic oxidation test was carried out using an RhB solution to simulated dye wastewater. The catalysts were characterized via scanning electron microscopy, X-ray diffraction, and ultraviolet–visible spectrophotometry. The results revealed that the modified TiO2 was well dispersed on the foam ceramic surface, with all nanoparticles exhibiting an anatase phase structure. Additionally, the visible light responsiveness of the TiO2 was optimal. The study further investigated the effects of Cu and N–TiO2 catalysts on the photocatalytic oxidation of dyeing wastewater under UV light.
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Benkhaya S, M’rabet S, El Harfi A (2020) A review on classifications, recent synthesis and applications of textile dyes. Inorg Chem Commun 115:107891. https://doi.org/10.1016/j.inoche.2020.107891
Al-Tohamy R, Ali SS, Li F et al (2022) A critical review on the treatment of dye-containing wastewater: ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety. Ecotoxicol Environ Saf 231:113160. https://doi.org/10.1016/j.ecoenv.2021.113160
Lili L (2016) Application of printing and dyeing wastewater treatment engineering. Resour Conserv Environ Protect 06:67–68. https://doi.org/10.3969/j.issn.1673-2251.2016.06.048
Hao XU, Dan QIAO, Zhicheng XU et al (2021) Application of electrocatalytic oxidation technology in organic wastewater treatment. Ind Water Treat 41(03):1–9. https://doi.org/10.11894/iwt.2020-0371
Gamelas SRD, Tomé JPC, Tomé AC, Lourenço LMO (2023) Advances in photocatalytic degradation of organic pollutants in wastewaters: harnessing the power of phthalocyanines and phthalocyanine-containing materials. RSC Adv 13(48):33957–33993. https://doi.org/10.1039/d3ra06598g
Kanakaraju D, Glass BD, Oelgemöller M (2014) Titanium dioxide photocatalysis for pharmaceutical wastewater treatment. Environ Chem Lett 12:27–47. https://doi.org/10.1007/s10311-013-0428-0
Kansal SK, Kundu P, Sood S et al (2014) Photocatalytic degradation of the antibiotic levofloxacin using highly crystalline TiO2 nanoparticles. New J Chem 38(7):3220–3226. https://doi.org/10.1039/C3NJ01619F
Espíndola JC, Cristóvão RO, Santos SGS et al (2019) Intensification of heterogeneous TiO2 photocatalysis using the NETmix mili-photoreactor under microscale illumination for oxytetracycline oxidation. Sci Total Environ 681:467–474. https://doi.org/10.1016/j.scitotenv.2019.05.066
Zeng Y, Chen D, Chen T et al (2019) Study on heterogeneous photocatalytic ozonation degradation of ciprofloxacin by TiO2/carbon dots: kinetic, mechanism and pathway investigation. Chemosphere 227:198–206. https://doi.org/10.1016/j.chemosphere.2019.04.039
Sandikly N, Kassir M, El Jamal M et al (2019) Comparison of the toxicity of waters containing initially sulfaquinoxaline after photocatalytic treatment by TiO2 and polyaniline/TiO2. Environ Technol. https://doi.org/10.1080/09593330.2019.1630485
Gupta S, Tripathi M (2012) A review on the synthesis of TiO2 nanoparticles by solution route. Open Chem 10(2):279–294. https://doi.org/10.2478/s11532-011-0155-y
Sachs M, Pastor E, Kafizas A et al (2016) Evaluation of surface state mediated charge recombination in anatase and rutile TiO2. Jf Phys Chem Lett 7(19):3742–3746. https://doi.org/10.1021/acs.jpclett.6b01501
Talat-Mehrabad J, Khosravi M, Modirshahla N et al (2016) Synthesis, characterization, and photocatalytic activity of co-doped Ag–, Mg–TiO2-P25 by photodeposition and impregnation methods. Desalin Water Treat 57(22):10451–10461. https://doi.org/10.1080/19443994.2015.1036780
Chen Q, Zhang Y, Zhang D et al (2017) Ag and N co-doped TiO2 nanostructured photocatalyst for printing and dyeing wastewater. J Water Process Eng 16:14–20. https://doi.org/10.1016/j.jwpe.2016.11.007
Asahi R, Morikawa T, Irie H et al (2014) Nitrogen-doped titanium dioxide as visible-light-sensitive photocatalyst: designs, developments, and prospects. Chem Rev 114(19):9824–9852. https://doi.org/10.1021/cr5000738
Chen M, Wang H, Chen X et al (2020) High-performance of Cu-TiO2 for photocatalytic oxidation of formaldehyde under visible light and the mechanism study. Chem Eng J 390:124481. https://doi.org/10.1016/j.cej.2020.124481
Lee BH, Park S, Kim M et al (2019) Reversible and cooperative photoactivation of single-atom Cu/TiO2 photocatalysts. Nat Mater 18(6):620–626. https://doi.org/10.1038/s41563-019-0344-1
Zhou J, Gao Y, Zhou Z et al (2020) Activated carbon particles loaded with Fe-TiO2 photovoltaic for synergistic treatment of folic acid wastewater. Ind Water Treat 40(04):39–43. https://doi.org/10.11894/iwt.2019-0455
Reza M, Khaki D, Saleh M et al (2017) Application of doped photocatalysts for organic pollutant degradation—A review. J Environ Manag 198:78–94. https://doi.org/10.1016/j.jenvman.2017.04.099
Schneider J, Matsuoka M, Takeuchi M et al (2014) Understanding TiO2 photocatalysis: mechanisms and materials. Chem Rev 114(19):9919–9986. https://doi.org/10.1021/cr5001892
Ajayan J, Nirmal D, Mohankumar P et al (2020) A review of photovoltaic performance of organic/inorganic solar cells for future renewable and sustainable energy technologies. Superlattices Microstruct 143:106549. https://doi.org/10.1016/j.spmi.2020.106549
Wang A, Wu S, Dong J et al (2021) Interfacial facet engineering on the Schottky barrier between plasmonic Au and TiO2 in boosting the photocatalytic CO2 reduction under ultraviolet and visible light irradiation. Chem Eng J 404:127145. https://doi.org/10.1016/j.cej.2020.127145
Li XZ, Li FB (2001) Study of Au/Au3+-TiO2 photocatalysts toward visible photooxidation for water and wastewater treatment. Environ Sci Technol 35(11):2381–2387. https://doi.org/10.1021/es001752w
Mariappan A, Pandi P, Rajeswarapalanichamy R et al (2022) Bandgap and visible-light-induced photocatalytic performance and dye degradation of silver doped HAp/TiO2 nanocomposite by sol-gel method and its antimicrobial activity. Environ Res 211:113079. https://doi.org/10.1016/j.envres.2022.113079
Warren Z, Guaraldo TT, Martins AS et al (2023) Photocatalytic foams for water treatment: a systematic review and meta-analysis. J Environ Chem Eng 11(1):109238. https://doi.org/10.1016/j.jece.2022.109238
Chen J, Poon CS (2009) Photocatalytic activity of titanium dioxide modified concrete materials—Influence of utilizing recycled glass cullets as aggregates. J Environ Manage 90(11):3436–3442. https://doi.org/10.1016/j.jenvman.2009.05.029
Katheresan V, Kansedo J, Lau SY (2018) Efficiency of various recent wastewater dye removal methods: a review. J Environ Chem Eng 6(4):4676–4697. https://doi.org/10.1016/j.jece.2018.06.060
Rico-Santacruz M, García-Muñoz P, Keller V et al (2019) Alveolar TiO2-β-SiC photocatalytic composite foams with tunable properties for water treatment. Catal Today 328:235–242. https://doi.org/10.1016/j.cattod.2018.11.059
Choi W, Termin A, Hoffmann MR (1994) The role of metal ion dopants in quantum-sized TiO2: correlation between photoreactivity and charge carrier recombination dynamics. J Phys Chem 98(51):13669–13679. https://doi.org/10.1021/j100102a038
Wei Y, Ji J, Liang F et al (2023) Pd/P–CeO2–Al2O3 coatings supported on foam ceramic with controlled morphology for high-performance CO2 methanation. Ceram Int 49(22):35071–35081. https://doi.org/10.1016/j.ceramint.2023.08.180
Banhart J (2001) Manufacture, characterisation and application of cellular metals and metal foams. Prog Mater Sci 46(6):559–632. https://doi.org/10.1016/S0079-6425(00)00002-5
Jaiswal R, Bharambe J, Patel N et al (2015) Copper and nitrogen co-doped TiO2 photocatalyst with enhanced optical absorption and catalytic activity. Appl Catal B 168:333–341. https://doi.org/10.1016/j.apcatb.2014.12.053
Zhao Z, Omer AA, Qin Z, Osman S, Xia L, Singh RP (2019) Cu/N-codoped TiO2 prepared by the sol-gel method for phenanthrene removal under visible light irradiation. Environ Sci Pollut Res 27:17530–17540. https://doi.org/10.1007/s11356-019-05787-7
Wang Z (2017) Preparation, modification and photocatalytic properties of titanium dioxide nanomaterials. Jilin University
Survase AA, Kanase SS (2023) Green synthesis of TiO2 nanospheres from isolated Aspergillus eucalypticola SLF1 and its multifunctionality in nanobioremediation of CI reactive blue 194 with antimicrobial and antioxidant activity. Ceram Int 49(10):14964–14980. https://doi.org/10.1016/j.ceramint.2023.01.079
Dhonde M, Sahu Dhonde K, Purohit K et al (2019) Facile synthesis of Cu/N co-doped TiO2 nanoparticles and their optical and electrical properties. Indian J Phys 93(1):27–32. https://doi.org/10.1007/s12648-018-1275-4
Song KX, Zhou JH, Bao JC et al (2008) Photocatalytic activity of (copper, nitrogen)-codoped titanium dioxide nanoparticles. J Am Ceram Soc 91:1369–1371. https://doi.org/10.1111/j.1551-2916.2008.02291.x
Xueqing R, Qiaoling Z, Yanfen Z et al (2023) Preparation of Cu/N-TiO2 nano photocatalyst using high gravity technology for photodegradation of phenol wastewater. Chin Pet Process Pe Technol 25(1):151
He RM, Zhang QL, Liu YZ et al (2021) Preparation of Fe and Co co-doped TiO2 by precipitation method in an impinging stream rotating packed bed for photodegradation of phenolwastewater. Adv Appl Ceram 9:6–8. https://doi.org/10.1080/17436753.2021.1904766
Chen DM, Jiang ZY, Geng JQ et al (2007) Carbon and nitrogen co-doped TiO2 with enhanced visible-light photocatalytic activity. Ind Eng Chem Res 46:2741–2746. https://doi.org/10.1021/ie061491k
Hou C, Liu W (2018) One-step synthesis of OH-TiO2/TiOF2 nanohybrids and their enhanced solar light photocatalytic performance. R Soc Open Sci 5(6):172005. https://doi.org/10.1098/rsos.172005
Jimenez-Relinque E, Castellote M (2018) Hydroxyl radical and free and shallowly trapped electron generation and electron/hole recombination rates in TiO2 photocatalysis using different combinations of anatase and rutile. Appl Catal A 565:20–25. https://doi.org/10.1016/j.apcata.2018.07.045
Yin H, Zhang C, Bai X, Yang Z, Liu Z (2022) Tuning electrochemical properties of silver nanomaterials by doping with boron: application for highly non-enzymatic sensing of hydrogen peroxide. ChemistrySelect. https://doi.org/10.1002/slct.202201310
Liang H, Zhang G, Li Z, Zhang Y, Peng F (2023) Catalytic hydrogenation of CO2 to methanol over Cu-based catalysts: active sites profiling and regulation strategy as well as reaction pathway exploration. Fuel Process Technol. https://doi.org/10.1016/j.fuproc.2023.107995
Yin Y, Jiang B, Liu Y et al (2023) A new type of composite catalyst α-nBACoPc/TiO2 for the synergistic photo-catalytic degradation of dyes. Catal Lett. https://doi.org/10.1007/s10562-023-04507-8
Acknowledgements
This research was funded by the Serve Local Projects of Liaoning Provincial Department of Education (No. lnfw202009); China National Critical Project for Science and Technology on Water Pollution Prevention and Control (No. 2018ZX07601002).
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Chao, L., Wang, Z. & He, J. Photocatalytic Oxidation of Printing and Dyeing Wastewater by Foam Ceramics Loaded with Cu and N–TiO2. Catal Lett (2024). https://doi.org/10.1007/s10562-024-04614-0
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DOI: https://doi.org/10.1007/s10562-024-04614-0