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Reusable and Self-Assembly Supramolecular Palladium Catalyst for C–C Coupling Reactions in Aqueous

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Abstract

A novel fluorescent supramolecular polymer (named N3T) has been synthesized resoundingly, which can effectively identify trace amounts of Pd2+ in solution, and then a self-assembled supramolecular catalyst catalyst N3T-Pd was obtained. The N3T-Pd with spherical structure could be used for C–C coupling reactions in an eco-friendly aqueous medium. The catalyst was characterized by NMR, FT-IR, XPS, SEM and fluorescence spectra. The N3T-Pd has prominent stability and recyclability without any decrease of catalytic activity after least five cycles. Notably, the reaction degree of Pd2+ with the supramolecular polymer can be conformed by the fluorescence intensity of the supramolecular polymer. With that, the N3T detection limit (LOD) of Pd2+ was measured by fluorescent titration. Surprisingly, N3T can ultrasensitive detection of Pd2+, the limit of detection was 1.9 × 10−7 M.

Graphical Abstract

The self-assembly supramolecular palladium catalyst N3T-Pd has been developed as a novel and efficient catalyst for ligand-free C–C cross-coupling reactions in aqueous at room temperature.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 21962017), the Natural Science Foundation of Gansu Province (No. 22JR5RA215). We also thank Key laboratory for Utility of Environmental Friendly Composite Materials and Biomass in University of Gansu Province (Northwest Minzu University), for financial support.

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Authors and Affiliations

  1. Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission, Gansu Provincial Biomass Function Composites Engineering Research Center, Key Laboratory for Utility of Environmental-Friendly Composites and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, Lanzhou, 730030, People’s Republic of China

    Yuzhi Sun, Shuaishuai Fu, Ying Zhang & Shang Wu

  2. College of Chemical Engineering, Lanzhou University of Arts and Science, Beimiantan 400, Lanzhou, 730000, Gansu, China

    Quanlu Yang

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  1. Yuzhi Sun
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  2. Shuaishuai Fu
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Correspondence to Shang Wu or Quanlu Yang.

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Sun, Y., Fu, S., Zhang, Y. et al. Reusable and Self-Assembly Supramolecular Palladium Catalyst for C–C Coupling Reactions in Aqueous. Catal Lett (2024). https://doi.org/10.1007/s10562-024-04603-3

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