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AgInS2 Decorated g-C3N4 for Highly Efficient Photocatalytic Nitrogen Fixation Synergistic Tetracycline Degradation

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Abstract

Combining photocatalytic nitrogen fixation with antibiotic wastewater degradation reaction is of great significance. As a metal-free photocatalyst, g-C3N4 has great application prospect in the field of bifunctional photocatalytic reaction because of its abundant raw materials, simple preparation method, low toxicity, and high stability. However, the further development of g-C3N4 is limited by its wide band gap (2.7 eV) and high recombination rate of carriers. In this paper, AgInS2 nanospheres modified g-C3N4 nanosheets were successfully prepared by a simple hydrothermal method. The photocatalytic nitrogen fixation activity of the obtained AgInS2-g-C3N4 hybrid was nearly two times (91 μmol/h/g) higher than that of g-C3N4. In addition, by adding a proper amount of tetracycline pollutant into the photocatalytic system, the photocatalytic nitrogen fixation activity was further increased to 248 μmol/h/g, and the synergistic degradation of tetracycline environmental pollutants was realized. Through a series of experimental characterization and theoretical calculation, the morphology and carrier dynamics of photocatalyst were systematically explored. The results show that the introduction of AgInS2 nanospheres improves the utilization rate of sunlight, surface active sites and carrier transport rate of g-C3N4. This work provides references for the design of environmentally friendly photocatalysts and their applications in the fields of environmental purification and energy conversion.

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References

  1. Leigh GJ (1998) Chemistry: Fixing nitrogen any which way. Science 279:506–507

    Article  CAS  Google Scholar 

  2. Burgess BK, Lowe DJ (1996) Mechanism of molybdenum nitrogenase. Chem Rev 96:2983–3012

    Article  CAS  PubMed  Google Scholar 

  3. Fu JW, Yu JG, Jiang CJ, Cheng B (2017) g-C3N4-based heterostructured photocatalysts. Adv Energy Mater 8:1701503

    Article  Google Scholar 

  4. Schrauzer GN, Guth TD (1977) Photolysis of water and photoreduction of nitrogen on titanium dioxide. J Am Chem Soc 99:22

    Article  Google Scholar 

  5. Qiu PY, Liang ZQ, Liu X, Qian X, Cui HZ, Tian J (2020) Synthesis of salicylic acid-modified graphite carbon nitride for enhancing photocatalytic nitrogen fixation. J Colloid Interface Sci 571:318–325

    Article  CAS  PubMed  Google Scholar 

  6. Wang BY, Zhang YJ, Zhu DQ, Li H (2020) Assessment of bioavailability of biochar-sorbed tetracycline to Escherichia coli for activation of antibiotic resistance genes. Environ Sci Technol 54:12920–12928

    Article  CAS  PubMed  Google Scholar 

  7. Song J, Rensing C, Holm PE, Virta M, Brandt KK (2017) Comparison of metals and tetracycline as selective agents for development of tetracycline resistant bacterial communities in agricultural soil. Environ Sci Technol 51:3040–3047

    Article  CAS  PubMed  Google Scholar 

  8. Liu Y, Li X, Zhang QH, Li WD, Xie Y, Liu HY, Shang L, Liu ZY, Chen ZM, Gu L, Tang ZY, Zhang TR, Lu SY (2020) A general route to prepare low-ruthenium-content bimetallic electrocatalysts for pH-universal hydrogen evolution reaction by using carbon quantum dots. Angew Chem Int Ed 59:1718–1726

    Article  CAS  Google Scholar 

  9. Chen SB, Liao JH, Zhou ZN, Yang SY, Gao QZ, Cai X, Peng F, Fang YP, Zhang SS (2021) Boosting photocatalytic hydrogen evolution using a noble-metal-free co-catalyst: CuNi@C with oxygen-containing functional groups. Appl Catal B: Environ 291:120139

    Article  CAS  Google Scholar 

  10. Zhou G, Shan Y, Hu YY, Xu XY, Long LY, Zhang JL, Dai J, Guo JH, Shen JC, Li S, Liu LZ, Wu XL (2020) Half-metallic carbon nitride nanosheets with micro grid mode resonance structure for efficient photocatalytic hydrogen evolution. Nat Commun 9:9

    Google Scholar 

  11. Zhou G, Shan Y, Wang LL, Hu YY, Guo JH, Hu FR, Shen JC, Gu Y, Cui JT, Liu LZ, Wu XL (2019) Photoinduced semiconductor-metal transition in ultrathin troilite FeS nanosheets to trigger efficient hydrogen evolution. Nat Commun 10:8

    Google Scholar 

  12. Ye S, Wang R, Wu MZ, Yuan YP (2015) A review on g-C3N4 for photocatalytic water splitting and CO2 reduction. Appl Surf Sci 358:15–27

    Article  CAS  Google Scholar 

  13. Jo WK, Lee JY, Selvam NCS (2016) Synthesis of MoS2 nanosheets loaded ZnO-g-C3N4 nanocomposites for enhanced photocatalytic applications. Chem Eng J 289:306–318

    Article  CAS  Google Scholar 

  14. Jiang ZX, Zhang X, Chen HS, Hu X, Yang P (2019) Formation of g-C3N4 Nanotubes towards Superior Photocatalysis Performance. ChemCatChem 11:4558–4567

    Article  CAS  Google Scholar 

  15. Li YF, Zhou MH, Cheng B, Shao Y (2020) Recent advances in g-C3N4-based heterojunction photocatalysts. J Mater Sci Technol 56:1–17

    Article  Google Scholar 

  16. Li K, Gao SM, Wang QY, Xu H, Wang ZY, Huang BB, Dai Y, Lu J (2015) In-situ-reduced synthesis of Ti3+ self-doped TiO2/g-C3N4 heterojunctions with high photocatalytic performance under LED light irradiation. ACS Appl Mater Interfaces 7:9023–9030

    Article  CAS  PubMed  Google Scholar 

  17. Sun MM, Chen ZY, Li JR, Hou J, Xu FL, Xu LK, Zeng RC (2018) Enhanced visible light-driven activity of TiO2 nanotube array photoanode co-sensitized by “green” AgInS2 photosensitizer and In2S3 buffer layer. Electrochimi Acta 269:429–440

    Article  CAS  Google Scholar 

  18. Liu JJ, Chen SF, Liu QZ, Zhu YF, Lu YF (2014) Density functional theory study on electronic and photocatalytic properties of orthorhombic AgInS2. Comput Mater Sci 91:159–164

    Article  CAS  Google Scholar 

  19. Du JG, Ma SL, Liu HP, Fu HC, Li L, Li ZQ, Li Y, Zhou JG (2019) Uncovering the mechanism of novel AgInS2 nanosheets/TiO2 nanobelts composites for photocatalytic remediation of combined pollution. Appl Catal B Environ 259:118062

    Article  CAS  Google Scholar 

  20. Guo Y, Zhou QX, Chen XL, Fu YZ, Lan SY, Zhu MS, Du YK (2022) Near-infrared response Pt-tipped Au nanorods/g-C3N4 realizes photolysis of water to produce hydrogen. J Mater Sci Technol 119:53–60

    Article  CAS  Google Scholar 

  21. Niu JF, Wang K, Yang L, Shi JH, Zhang Y, Yang F, Yu XJ, Yao BH (2022) Construction of a novel g-C3N4@Bi/BiOBr ternary heterojunction with Z-scheme mechanism for the efficient photocatalytic removal of ciprofloxacin. Opt Mater 134:113125

    Article  CAS  Google Scholar 

  22. Wang HT, Yu LL, Jiang JZ, Arramel, Zou J (2023) S-doping of the N-Sites of g-C3N4 to enhance photocatalytic H2 evolution activity. Acta Phys-Chim Sin. https://doi.org/10.3866/PKU.WHXB202305047

    Article  Google Scholar 

  23. Dong F, Zhao ZW, Sun YJ, Zhang YX, Yan S, Wu ZB (2015) An advanced semimetal-organic Bi spheres-g-C3N4 nanohybrid with SPR-enhanced visible-light photocatalytic performance for NO purification. Environ Sci Technol 49:12432–12440

    Article  CAS  PubMed  Google Scholar 

  24. Liu DN, Chen DY, Li NJ, Xu QF, Li H, He JH, Lu JM (2020) Surface engineering of g-C3N4 by stacked BiOBr sheets rich in oxygen vacancies for boosting photocatalytic performance. Angew Chem Int Ed 59:4519–4524

    Article  CAS  Google Scholar 

  25. Shi WL, Wang LJ, Wang J, Sun HR, Shi YX, Guo F, Lu CY (2022) Magnetically retrievable CdS/reduced graphene oxide/ZnFe2O4 ternary nanocomposite for self-generated H2O2 towards photo-Fenton removal of tetracycline under visible light irradiation. Sep Purif Technol 292:120987

    Article  CAS  Google Scholar 

  26. Jiang JZ, Xiong ZG, Wang HT, Liao GD, Bai SS, Zou J, Wu PX, Zhang P, Li X (2022) Sulfur-doped g-C3N4/g-C3N4 isotype step-scheme heterojunction for photocatalytic H2 evolution. J Mater Sci Technol 118:15–24

    Article  CAS  Google Scholar 

  27. Zou J, Wu SL, Liu Y, Sun YJ, Cao Y, Hsu JPP, Wee ATS, Jiang JZ (2018) An ultra-sensitive electrochemical sensor based on 2D g-C3N4/CuO nanocomposites for dopamine detection. Carbon 130:652–663

    Article  CAS  Google Scholar 

  28. Wang YY, Qu Y, Qu BH, Bai LL, Liu Y, Yang ZD, Zhang W, Jing LQ, Fu HG (2021) Construction of six-oxygen-coordinated single Ni sites on g-C3N4 with boron-oxo species for photocatalytic water-activation-induced CO2 reduction. Adv Mater 33:2105482

    Article  CAS  Google Scholar 

  29. Wang LJ, Zhang Z, Xu XY, Yu LM, Yang TY, Zhang XY, Zhang YW, Zhu HG, Li JQ, Zhang J (2022) Zn-P bond induced S-scheme heterojunction for efficient photocatalytic tetracycline degradation synergistic H2 generation. J Alloy Compd 926:166981

    Article  CAS  Google Scholar 

  30. Zhou G, Wang PF, Hu B, Shen XY, Liu CC, Tao WX, Huang PL, Liu LZ (2022) Spin-related symmetry breaking induced by half-disordered hybridization in BixEr2-xRu2O7 pyrochlores for acidic oxygen evolution. Nat Commun 13:4106

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  31. Sun HR, Wang LJ, Guo F, Shi YX, Li LL, Xu Z, Yan X, Shi WL (2022) Fe-doped g-C3N4 derived from biowaste material with Fe-N bonds for enhanced synergistic effect between photocatalysis and Fenton degradation activity in a broad pH range. J Alloy Compd 900:163410

    Article  CAS  Google Scholar 

  32. Zhou G, Li TH, Huang R, Wang PF, Hu B, Li H, Liu LZ, Sun Y (2021) Recharged catalyst with memristive nitrogen reduction activity through learning networks of spiking neurons. J Am Chem Soc 143:5378–5385

    Article  CAS  PubMed  Google Scholar 

  33. Li SJ, Wang CC, Dong KX, Zhang P, Chen XB, Li X (2023) MIL-101(Fe)/BiOBr S-scheme photocatalyst for promoting photocatalytic abatement of Cr(VI) and enrofloxacin antibiotic: Performance and mechanism. Chin J Catal. https://doi.org/10.1016/S1872-2067(23)64479-1

    Article  Google Scholar 

  34. Li SJ, Cai MJ, Wang CC, Liu YP (2023) Ta3N5/CdS core-shell S-scheme heterojunction nanofibers for efficient photocatalytic removal of antibiotic tetracycline and Cr(VI): Performance and mechanism insights. Adv Fiber Mater 5:994–1007

    Article  CAS  Google Scholar 

  35. Li SJ, Yan RY, Cai MJ, Jiang W, Zhang MY, Li X (2023) J Mater Sci Technol 164:59–67

    Article  CAS  Google Scholar 

  36. Wang LJ, Hu YY, Qi F, Ding L, Wang JM, Zhang XY, Liu QW, Liu LZ, Sun HZ, Qu P (2020) Anchoring black phosphorus nanoparticles onto ZnS porous nanosheets: efficient photocatalyst design and charge carrier dynamics. ACS Appl Mater Inter 12:8157–8167

    Article  CAS  Google Scholar 

  37. Shi WL, Sun W, Liu YN, Zhang K, Sun HR, Lin X, Hong YZ, Guo F (2022) A self-sufficient photo-Fenton system with coupling in-situ production H2O2 of ultrathin porous g-C3N4 nanosheets and amorphous FeOOH quantum dots. J Hazard Mater 436:129141

    Article  CAS  PubMed  Google Scholar 

  38. Yuan H, Shi WL, Lu JL, Wang JX, Shi YX, Guo F, Kang ZH (2023) Dual-channels separated mechanism of photo-generated charges over semiconductor photocatalyst for hydrogen evolution: Interfacial charge transfer and transport dynamics insight. Chem Eng J 454:140442

    Article  CAS  Google Scholar 

  39. Shi WL, Cao LW, Shi YX, Chen ZZ, Cai Y, Guo F, Du X (2023) Environmentally friendly supermolecule self-assembly preparation of S-doped hollow porous tubular g-C3N4 for boosted photocatalytic H2 production. Ceram Int 49:11989–11998

    Article  CAS  Google Scholar 

  40. Shi YX, Li LL, Xu Z, Guo F, Li Y, Shi WL (2023) Synergistic coupling of piezoelectric and plasmonic effects regulates the Schottky barrier in Ag nanoparticles/ultrathin g-C3N4 nanosheets heterostructure to enhance the photocatalytic activity. Appl Surf Sci 616:156466

    Article  CAS  Google Scholar 

  41. Shi WL, Hao CC, Shi YX, Guo F, Tang YB (2023) Effect of different carbon dots positions on the transfer of photo-induced charges in type I heterojunction for significantly enhanced photocatalytic activity. Sep Purif Technol 304:122337

    Article  CAS  Google Scholar 

  42. Yuan H, Sun HR, Shi YX, Wang JX, Bian A, Hu YY, Guo F, We L, Shi XDu, Kang ZHH (2023) Cooperation of carbon doping and carbon loading boosts photocatalytic activity by the optimum photo-induced electron trapping and interfacial charge transfer. Chem Eng J 472:144654

    Article  CAS  Google Scholar 

  43. Kuate LJN, Chen ZZ, Lu JL, Wen HB, Guo F, Shi WL (2023) Photothermal-assisted photocatalytic degradation of tetracycline in seawater based on the black g-C3N4 nanosheets with cyano group defects. Catalysts 13:1147

    Article  Google Scholar 

  44. Zhang K, Wang LJ, Hong YZ, Duan XX, Ai CJ, Zhang LL, Zhang TF, Chen Y, Lin X, Shi WL, Guo F (2023) Iron phthalocyanine nanodots decorated ultra-thin porous carbon nitride: A combination of photocatalysis and Fenton reaction to achieve two-channel efficient tetracycline degradation. J Alloys Compd 966:171580

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the Science and technology project of Henan Province (232102240073), Eceshi (www.eceshi. com) was acknowledged for the TEM and XPS analysis.

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Authors and Affiliations

  1. College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, 113001, Liaoning, China

    Tianyi Yang, Daosheng Liu, Rui Wang & Wei Wei

  2. Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, People’s Republic of China

    Lijing Wang, Xiangyu Xu, Xiaoting Lv & Yawei Zhang

  3. The Comprehensive Service Center of Songyuan City Ningjiang District Maodu Station Town, Songyuan, China

    Feng Jiang

  4. College of Chemistry, Baicheng Normal University, Baicheng, 137000, People’s Republic of China

    Bo Feng

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  1. Tianyi Yang
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  2. Lijing Wang
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  3. Daosheng Liu
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  4. Xiangyu Xu
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  5. Feng Jiang
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  8. Bo Feng
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  9. Rui Wang
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  10. Wei Wei
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Bo Feng contributed to the conception of the study; Rui Wang contributed significantly to analysis and manuscript preparation; Wei Wei performed the data analyses and wrote the manuscript.

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Correspondence to Lijing Wang.

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Yang, T., Wang, L., Liu, D. et al. AgInS2 Decorated g-C3N4 for Highly Efficient Photocatalytic Nitrogen Fixation Synergistic Tetracycline Degradation. Catal Lett 154, 2275–2284 (2024). https://doi.org/10.1007/s10562-023-04471-3

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