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Bi/Bi2WO6 Plasmonic Composites with Enhanced Photocatalytic Activity for Degradation of Gasphase Toluene

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Abstract

Semimetal bismuth with plasmonic properties has attracted more and more interest to enhance photocatalytic activity. Herein Bi/Bi2WO6 composites catalyst was successfully synthesized via a simple two-step route in solvothermal reaction. Compared with pure Bi2WO6, the photocatalytic degradation efficiency of gasphase toluene of the Bi/Bi2WO6 composites is significantly increased from 44 to 93%, and the degradation efficiency increased by more than two times. From the analysis of UV–vis diffuse reflectance spectra, it is obvious that the optical absorption in visible light region of Bi/Bi2WO6 composites has significantly enhanced compared to pure Bi2WO6, which is due to the surface plasmon resonance (SPR) of Bi nanoparticles on the surface of pure Bi2WO6. The dramatically enhanced activity could be attributed to the synergistic effect of the strong SPR of Bi metals and the enhancement of charge separation efficiency caused by the interfacial interaction between Bi metal and Bi2WO6.

Graphical Abstract

Compared with pure Bi2WO6, the photocatalytic degradation efficiency of gasphase toluene of the Bi/Bi2WO6 composites is significantly increased from 44 to 93%, and the degradation efficiency increased by more than two times. The dramatically enhanced activity could be attributed to the synergistic effect of the strong SPR of Bi metals and the enhancement of charge separation efficiency caused by the interfacial interaction between Bi metal and Bi2WO6.

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Acknowledgements

The authors thank the financial supports from National Natural Science Foundation of China (No. 21802119).

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Authors and Affiliations

  1. School of Environmental Science and Enginnering, Yancheng Institute of Technology, Yancheng, 224000, People’s Republic of China

    Hui Liang, Han Sun, Yuyu Zhu & Qi Xu

  2. Yancheng Lanfeng Environmental Engineering Technology Co, LTD, Yancheng, 224051, People’s Republic of China

    Lan Fan

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  1. Hui Liang
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  2. Han Sun
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  4. Lan Fan
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Liang, H., Sun, H., Zhu, Y. et al. Bi/Bi2WO6 Plasmonic Composites with Enhanced Photocatalytic Activity for Degradation of Gasphase Toluene. Catal Lett 153, 559–569 (2023). https://doi.org/10.1007/s10562-022-04001-7

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