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Cu(II)/Triazine-Based Dendrimer as an Efficacious Recoverable Nano-catalyst for CO2 Fixation Under Solvent-Free Conditions

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Abstract

In this study, a new and efficient solvent-less procedure was expanded to synthesize cyclic carbonate derivatives by chemical fixation of CO2 using Cu(II)/hydroxyl terminated triazine-based dendrimer (Cu(II)/TD) as a proficient heterogeneous nano-catalyst. The Cu(II)/TD nano-catalyst was characterized using TEM, TGA, FT-IR, SEM, EDS, and ICP techniques. The application of this new nano-catalyst provides the preparation of assorted cyclic carbonate derivatives in the attendance of 0.045 mol% of nano-catalyst and 0.3 MPa of CO2 pressure at 50 °C under solvent-less situations in outstanding yields. The Cu(II)/TD catalyst was able to be reprocessed and recovered many times without considerable failure of its performance. The findings strongly confirm that Cu(II)/TD can be considered as an environmentally friendly and retrievable catalyst for fixation of CO2 into the valuable products.

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References

  1. Lim M, Han GC, Ahn JW, You KS (2010) Int J Environ Res Public Health 7:203–228

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  2. Cokoja M, Bruckmeier C, Rieger B, Herrmann WA, Kühn FE (2011) Angew Chem Int Ed 50:8510–8537

    Article  CAS  Google Scholar 

  3. Sakakura T, Choi JC, Yasuda H (2007) Chem Rev 107:2365–2387

    Article  PubMed  CAS  Google Scholar 

  4. Webster DC (2003) Prog Org Coat 47:77–86

    Article  CAS  Google Scholar 

  5. Rokicki G (2000) Prog Polym Sci 25:259–342

    Article  CAS  Google Scholar 

  6. Guha N, Gupta AK, Chatterjee S, Krishnan S, Singh MK, Rai DK (2021) J CO2 Util 49:101575

    Article  CAS  Google Scholar 

  7. Taghavi F, Khojastehnezhad A, Khalifeh R, Rajabzadeh M, Rezaei F, Abnous K, Taghdisi SM (2021) New J Chem 45:15405–15414

    Article  CAS  Google Scholar 

  8. Bai D, Jing H (2010) Green Chem 12:39–41

    Article  CAS  Google Scholar 

  9. Cui M, Shamsa F (2021). Catal Lett. https://doi.org/10.1007/s10562-021-03616-6

    Article  Google Scholar 

  10. Dai W, Zou M, Long J, Li B, Zhang S, Yang L, Wang D, Mao P, Luo S, Luo X (2021) Appl Surf Sci 540:148311

    Article  CAS  Google Scholar 

  11. Paninho AB, Mustapa AN, Mahmudov KT, Pombeiro AJ, Guedes da Silva MFC, Bermejo MD, Martín Á, Cocero MJ, Nunes AV (2021) Catalysts 11:872

    Article  CAS  Google Scholar 

  12. Boushehri PH, Hafizi A, Rahimpour MR, Khalifeh R (2021). Top Catal. https://doi.org/10.1007/s11244-021-01456-7

    Article  Google Scholar 

  13. Arayachukiat S, Kongtes C, Barthel A, Vummaleti SV, Poater A, Wannakao S, Cavallo L, D’Elia V (2017) ACS Sustain Chem Eng 5:6392–6397

    Article  CAS  Google Scholar 

  14. Sodpiban O, Phungpanya C, Del Gobbo S, Arayachukiat S, Piromchart T, D’Elia V (2021) Chem Eng J 422:129930

    Article  CAS  Google Scholar 

  15. Wang Z, Wang Y, Xie Q, Fan Z, Shen Y (2021) New J Chem 45:9403–9408

    Article  CAS  Google Scholar 

  16. Sodpiban O, Del Gobbo S, Barman S, Aomchad V, Kidkhunthod P, Ould-Chikh S, Poater A, D’Elia V, Basset JM (2019) Catal Sci Technol 9:6152–6165

    Article  CAS  Google Scholar 

  17. Aomchad V, Del Gobbo S, Yingcharoen P, Poater A, D’Elia V (2021) Catal Today 375:324–334

    Article  CAS  Google Scholar 

  18. Aomchad V, Cristòfol À, Della Monica F, Limburg B, D’Elia V, Kleij AW (2021) Green Chem 23:1077–1113

    Article  CAS  Google Scholar 

  19. Grignard B, Gennen S, Jérôme C, Kleij AW, Detrembleur C (2019) Chem Soc Rev 48:4466–4514

    Article  PubMed  CAS  Google Scholar 

  20. Tomalia DA (2004) Aldrichimica Acta 37:39–57

    CAS  Google Scholar 

  21. Patel H, Patel P (2013) Int J Pharm Bio Sci 4:454–463

    CAS  Google Scholar 

  22. Mollazade M, Nejati-Koshki K, Akbarzadeh A, Zarghami N, Nasiri M, Jahanban-Esfahlan R, Alibakhshi A (2013) Asian Pac J Cancer Prev 14:6925–6928

    Article  PubMed  Google Scholar 

  23. Mignani S, El Kazzouli S, Bousmina M, Majoral JP (2013) Adv Drug Deliv Rev 65:1316–1330

    Article  PubMed  CAS  Google Scholar 

  24. Wang D, Astruc D (2013) Coord Chem Rev 257:2317–2334

    Article  CAS  Google Scholar 

  25. Saberi D, Hashemi H, Ghanaatzadeh N, Moghadam M, Niknam K (2020) Appl Organomet Chem 34:e5563

    Article  CAS  Google Scholar 

  26. Fakhar A, Dinari M, Lammertink R, Sadeghi M (2020) Sep Purif Technol 241:116734

    Article  Google Scholar 

  27. Franc G, Badetti E, Colliere V, Majoral JP, Sebastian RM, Caminade AN (2009) Nanoscale 1:233–237

    Article  PubMed  CAS  Google Scholar 

  28. Hagiwara H, Sasaki H, Tsubokawa N, Hoshi T, Suzuki T, Tsuda T, Kuwabata S (2010) Synlett 2010:1990–1996

    Article  Google Scholar 

  29. Pan S, Yan S, Osako T, Uozumi Y (2018) Synlett 29:1152–1156

    Article  CAS  Google Scholar 

  30. Gajjar D, Patel R, Patel H, Patel PM (2014) Chem Sci Trans 3:897–908

    Google Scholar 

  31. Kuśtrowski P, Chmielarz L, Dziembaj R, Cool P, Vansant EF (2005) J Phys Chem B 109:11552–11558

    Article  PubMed  Google Scholar 

  32. Khalifeh R, Zarei Z, Rajabzadeh M (2021) New J Chem 45:810–820

    Article  CAS  Google Scholar 

  33. Rajabzadeh M, Khalifeh R, Eshghi H, Hafizi A (2020) J Ind Eng Chem 89:458–469

    Article  CAS  Google Scholar 

  34. Khalifeh R, Karimi M, Rajabzadeh M, Hafizi A, Nogorani FS (2020) J CO2 Util 41:101233

    Article  CAS  Google Scholar 

  35. Kim J, Kim SN, Jang HG, Seo G, Ahn WS (2013) Appl Catal A Gen 453:175–180

    Article  CAS  Google Scholar 

  36. Aresta M, Dibenedetto A, Gianfrate L, Pastore C (2003) J Mol Catal 204:245–252

    Article  Google Scholar 

  37. Tambe PR, Yadav GD (2018) Clean Technol Environ Policy 20:345–356

    Article  CAS  Google Scholar 

  38. Dai WL, Yin SF, Guo R, Luo SL, Du X, Au CT (2010) Catal Lett 136:35–44

    Article  CAS  Google Scholar 

  39. Prasad D, Patil KN, Bhanushali JT, Nagaraja BM, Jadhav AH (2019) Catal Sci Technol 9:4393–4412

    Article  CAS  Google Scholar 

  40. Wu YL, Yang GP, Cheng S, Qian J, Fan D, Wang YY (2019) ACS Appl Mater Interfaces 11:47437–47445

    Article  PubMed  CAS  Google Scholar 

  41. Zhi Y, Shao P, Feng X, Xia H, Zhang Y, Shi Z, Mu Y, Liu X (2018) J Mater Chem A 6:374–382

    Article  CAS  Google Scholar 

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Acknowledgements

The authors are grateful for the financial support of the Islamic Azad University Bandar. Abbas Branch and Shiraz University of Technology for this study.

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Authors and Affiliations

  1. Department of Chemistry, Bandar Abbas Branch, Islamic Azad University, Bandar Abbas, Iran

    Farid Moeinpour & Samaneh Javdan

  2. Department of Chemistry, Shiraz University of Technology, 71555-313, Shiraz, Iran

    Reza Khalifeh, Maryam Rajabzadeh & Fahimeh Rezaei

Authors
  1. Farid Moeinpour
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  2. Reza Khalifeh
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  3. Maryam Rajabzadeh
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  4. Fahimeh Rezaei
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  5. Samaneh Javdan
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Correspondence to Farid Moeinpour.

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Moeinpour, F., Khalifeh, R., Rajabzadeh, M. et al. Cu(II)/Triazine-Based Dendrimer as an Efficacious Recoverable Nano-catalyst for CO2 Fixation Under Solvent-Free Conditions. Catal Lett 152, 3679–3690 (2022). https://doi.org/10.1007/s10562-022-03935-2

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  • DOI: https://doi.org/10.1007/s10562-022-03935-2

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