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Nano-magnetic-iron Oxides@choline Acetate as a Heterogeneous Catalyst for the Synthesis of 1,2,3-Triazoles

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Abstract

In this research, four cholines supported on core–shell iron oxides, Fe2O3@MgO@Ch.OAc (choline acetate), Fe2O3@MgO@Ch.OH (choline hydroxide), Fe3O4@Ch.OAc, Fe3O4@Ch.OH, were synthesized. The synthesized catalysts were tested in 1,2,3-triazoles synthesis by the reaction of nitromethane, aldehyde, and benzyl azide in EtOH as a green solvent. Among four synthesized heterogeneous catalysts, the Fe2O3@MgO@ch.OAc showed superior catalytic activity for the reaction and afforded the desired triazoles in good isolated yields under mild reaction conditions.

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Data Availability

The data that supports the findings of this study are available in the supplementary material of this article.

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Acknowledgements

We gratefully acknowledge the Faculty of chemistry at Tarbiat Modares University for supporting this work, Also, we gratefully acknowledge the Part Pishtaz Pouya Golestan Company especially Dr. Hossein Rahmani.

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  1. Chemistry Department, Tarbiat Modares University, PO Box:14155-4838, Tehran, Iran

    Abolfazl Mohammadkhani & Akbar Heydari

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  1. Abolfazl Mohammadkhani
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  2. Akbar Heydari
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Correspondence to Akbar Heydari.

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Mohammadkhani, A., Heydari, A. Nano-magnetic-iron Oxides@choline Acetate as a Heterogeneous Catalyst for the Synthesis of 1,2,3-Triazoles. Catal Lett 152, 1678–1691 (2022). https://doi.org/10.1007/s10562-021-03739-w

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